Patrick Frank

Summary

Affiliation: Stanford University
Country: USA

Publications

  1. ncbi The solution structure of [Cu(aq)]2+ and its implications for rack-induced bonding in blue copper protein active sites
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 44:1922-33. 2005
  2. ncbi A systematic resolution of sulfur in reticulated vitreous carbon using X-ray absorption spectroscopy
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, USA
    Inorg Chem 45:9864-76. 2006
  3. pmc The uptake and fate of vanadyl ion in ascidian blood cells and a detailed hypothesis for the mechanism and location of biological vanadium reduction. A visible and X-ray absorption spectroscopic study
    Patrick Frank
    Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94025, USA
    J Inorg Biochem 102:809-23. 2008
  4. doi Solution [Cu(amm)]2+ is a strongly solvated square pyramid: a full account of the copper K-edge XAS spectrum within single-electron theory
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 47:4126-39. 2008
  5. ncbi A new structural motif for biological iron: iron K-edge XAS reveals a [Fe4-mu-(OR)5(OR)(9-10)] cluster in the ascidian Perophora annectens
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 45:3920-31. 2006
  6. pmc The X-ray absorption spectroscopic model of the copper(II) imidazole complex ion in liquid aqueous solution: a strongly solvated square pyramid
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, United States
    Inorg Chem 51:2086-96. 2012
  7. ncbi The vanadium environment in blood cells of Ascidia ceratodes is divergent at all organismal levels: an XAS and EPR spectroscopic study
    Patrick Frank
    Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94309, USA
    J Inorg Biochem 94:59-71. 2003
  8. ncbi Cooperativity and intermediates in the equilibrium reactions of Fe(II,III) with ethanethiolate in N-methylformamide solution
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, CA 94305 5080, USA
    J Biol Inorg Chem 10:373-82. 2005
  9. pmc Solvation structure of the halides from x-ray absorption spectroscopy
    Matthew Antalek
    Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, California 94025, USA
    J Chem Phys 145:044318. 2016
  10. doi Spin-Polarization-Induced Preedge Transitions in the Sulfur K-Edge XAS Spectra of Open-Shell Transition-Metal Sulfates: Spectroscopic Validation of σ-Bond Electron Transfer
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, United States
    Inorg Chem . 2017

Collaborators

Detail Information

Publications15

  1. ncbi The solution structure of [Cu(aq)]2+ and its implications for rack-induced bonding in blue copper protein active sites
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 44:1922-33. 2005
    ..Further, previously neglected protein folding thermodynamic consequences of the rack-bonding hypothesis indicate an experimental disconfirmation...
  2. ncbi A systematic resolution of sulfur in reticulated vitreous carbon using X-ray absorption spectroscopy
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, USA
    Inorg Chem 45:9864-76. 2006
    ..15% of the RVC surface, increasing to approximately 0.51% following permanganate/sulfuric acid treatment. The detection of episulfide directly corroborates a proposed mechanism for the migration of elemental sulfur through carbon...
  3. pmc The uptake and fate of vanadyl ion in ascidian blood cells and a detailed hypothesis for the mechanism and location of biological vanadium reduction. A visible and X-ray absorption spectroscopic study
    Patrick Frank
    Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94025, USA
    J Inorg Biochem 102:809-23. 2008
    ..Together these constitute the new field of vanadium redox enzymology...
  4. doi Solution [Cu(amm)]2+ is a strongly solvated square pyramid: a full account of the copper K-edge XAS spectrum within single-electron theory
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 47:4126-39. 2008
    ..Cu(amm)](2+) continues the dissymmetry previously found for the solution structure of [Cu(H2O)5](2+), again contradicting the rack-bonding theory of blue copper proteins...
  5. ncbi A new structural motif for biological iron: iron K-edge XAS reveals a [Fe4-mu-(OR)5(OR)(9-10)] cluster in the ascidian Perophora annectens
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 45:3920-31. 2006
    ..Either of these models represents an entirely new structural motif for biological iron. Vanadium domination of blood-cell metals cannot be a defining trait of Phlebobranch tunicates so long as P. annectens is included among them...
  6. pmc The X-ray absorption spectroscopic model of the copper(II) imidazole complex ion in liquid aqueous solution: a strongly solvated square pyramid
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, United States
    Inorg Chem 51:2086-96. 2012
    ....
  7. ncbi The vanadium environment in blood cells of Ascidia ceratodes is divergent at all organismal levels: an XAS and EPR spectroscopic study
    Patrick Frank
    Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94309, USA
    J Inorg Biochem 94:59-71. 2003
    ..Blood cell vanadium thus noticeably diverges at all organismal levels among A. ceratodes...
  8. ncbi Cooperativity and intermediates in the equilibrium reactions of Fe(II,III) with ethanethiolate in N-methylformamide solution
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, CA 94305 5080, USA
    J Biol Inorg Chem 10:373-82. 2005
    ..These results are related to the chemistry of nitrogenase FeMo cofactor in alkaline NMF solution...
  9. pmc Solvation structure of the halides from x-ray absorption spectroscopy
    Matthew Antalek
    Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, California 94025, USA
    J Chem Phys 145:044318. 2016
    ..12 (-0.04/+0.3) Å, supporting the experimental result. These experiments provide the first fully three-dimensional structures presenting to atomic resolution the aqueous solvation spheres of the larger halide ions. ..
  10. doi Spin-Polarization-Induced Preedge Transitions in the Sulfur K-Edge XAS Spectra of Open-Shell Transition-Metal Sulfates: Spectroscopic Validation of σ-Bond Electron Transfer
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, United States
    Inorg Chem . 2017
    ..This electronic structure feature provides a direct spectroscopic confirmation of the through-bond electron-transfer mechanism of redox-active metalloproteins...
  11. pmc A high-resolution XAS study of aqueous Cu(II) in liquid and frozen solutions: pyramidal, polymorphic, and non-centrosymmetric
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, USA
    J Chem Phys 142:084310. 2015
    ....
  12. pmc XAS spectroscopy, sulfur, and the brew within blood cells from Ascidia ceratodes
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, CA 94305, USA Stanford Synchrotron Radiation Lightsource, SLAC, Stanford University, Stanford, CA 94309, USA Electronic address
    J Inorg Biochem 131:99-108. 2014
    ....
  13. ncbi Cooperative ligation, back-bonding, and possible pyridine-pyridine interactions in tetrapyridine-vanadium(II): a visible and X-ray spectroscopic study
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, USA
    Inorg Chem 41:3269-79. 2002
    ..Cooperativity in the binding of pyridine by V(II) is then assigned by default to V(II)-pyridine back-bonding, which emerges only after the first pyridine is bound...
  14. pmc Ancient wood of the Acqualadrone rostrum: materials history through gas chromatography/mass spectrometry and sulfur X-ray absorption spectroscopy
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, United States
    Anal Chem 84:4419-28. 2012
    ....
  15. ncbi High covalence in CuSO4 and the radicalization of sulfate: an X-ray absorption and density functional study
    Robert K Szilagyi
    Department of Chemistry and Biochemistry, Montana State University, Bozeman, Montana 59717, USA
    Inorg Chem 43:8318-29. 2004
    ....