Bernard P Binks

Summary

Affiliation: University of Hull
Country: UK

Publications

  1. ncbi request reprint Aqueous foams stabilized solely by silica nanoparticles
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Angew Chem Int Ed Engl 44:3722-5. 2005
  2. ncbi request reprint Contact angles in relation to emulsions stabilised solely by silica nanoparticles including systems containing room temperature ionic liquids
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, UK HU6 7RX
    Phys Chem Chem Phys 9:6391-7. 2007
  3. ncbi request reprint Inversion of silica-stabilized emulsions induced by particle concentration
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Langmuir 21:3296-302. 2005
  4. ncbi request reprint Phase inversion of particle-stabilized materials from foams to dry water
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, UK
    Nat Mater 5:865-9. 2006
  5. ncbi request reprint Naturally occurring spore particles at planar fluid interfaces and in emulsions
    B P Binks
    Surfactant and Colloid Group, and Sporomex Ltd, Department of Chemistry, University of Hull, Hull HU6 7RX, United Kingdom
    Langmuir 21:8161-7. 2005
  6. ncbi request reprint Effects of pH and salt concentration on oil-in-water emulsions stabilized solely by nanocomposite microgel particles
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, United Kingdom
    Langmuir 22:2050-7. 2006
  7. doi request reprint Novel stabilization of emulsions via the heteroaggregation of nanoparticles
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Langmuir 24:4443-6. 2008
  8. ncbi request reprint Silica particle-stabilized emulsions of silicone oil and water: aspects of emulsification
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, HU6 7RX, United Kingdom
    Langmuir 20:1130-7. 2004
  9. doi request reprint Effects of temperature on water-in-oil emulsions stabilised solely by wax microparticles
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    J Colloid Interface Sci 335:94-104. 2009
  10. doi request reprint Stabilisation of liquid-air surfaces by particles of low surface energy
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Phys Chem Chem Phys 12:9169-71. 2010

Collaborators

Detail Information

Publications43

  1. ncbi request reprint Aqueous foams stabilized solely by silica nanoparticles
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Angew Chem Int Ed Engl 44:3722-5. 2005
  2. ncbi request reprint Contact angles in relation to emulsions stabilised solely by silica nanoparticles including systems containing room temperature ionic liquids
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, UK HU6 7RX
    Phys Chem Chem Phys 9:6391-7. 2007
    ....
  3. ncbi request reprint Inversion of silica-stabilized emulsions induced by particle concentration
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Langmuir 21:3296-302. 2005
    ..In water, solvation of particle surfaces prevents this from occurring and particles behave as hydrophilic ones at all concentrations. A concentration-induced change in particle wettability is thus advanced...
  4. ncbi request reprint Phase inversion of particle-stabilized materials from foams to dry water
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, UK
    Nat Mater 5:865-9. 2006
    ..The resultant materials in which either air or water become encapsulated have potential applications in the food, pharmaceutical and cosmetics industries...
  5. ncbi request reprint Naturally occurring spore particles at planar fluid interfaces and in emulsions
    B P Binks
    Surfactant and Colloid Group, and Sporomex Ltd, Department of Chemistry, University of Hull, Hull HU6 7RX, United Kingdom
    Langmuir 21:8161-7. 2005
    ..The influence of particle concentration, oil/water ratio, and additives in the aqueous phase is studied...
  6. ncbi request reprint Effects of pH and salt concentration on oil-in-water emulsions stabilized solely by nanocomposite microgel particles
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, United Kingdom
    Langmuir 22:2050-7. 2006
    ..24 mol kg(-1). The degree of ionization of such microgel particles is a critical factor in controlling the coalescence stability of o/w emulsions stabilized by them...
  7. doi request reprint Novel stabilization of emulsions via the heteroaggregation of nanoparticles
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Langmuir 24:4443-6. 2008
    ..The increased viscosity of the continuous phase also contributes to such stability...
  8. ncbi request reprint Silica particle-stabilized emulsions of silicone oil and water: aspects of emulsification
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, HU6 7RX, United Kingdom
    Langmuir 20:1130-7. 2004
    ..For higher phi(o) close to conditions of phase inversion, coalescence becomes more prevalent and the drop size increases with time with stable multiple emulsions forming as a result...
  9. doi request reprint Effects of temperature on water-in-oil emulsions stabilised solely by wax microparticles
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    J Colloid Interface Sci 335:94-104. 2009
    ..Rapid cooling of these latter emulsions enhances their long-term stability as solidification of the molten wax leads to a thickening of the continuous oil phase...
  10. doi request reprint Stabilisation of liquid-air surfaces by particles of low surface energy
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Phys Chem Chem Phys 12:9169-71. 2010
    ..By varying the surface tension of the liquid, various particle-stabilised materials from oil dispersions to air-in-oil foams to dry water can be prepared...
  11. doi request reprint Pickering emulsions stabilized by hydrophilic nanoparticles: in situ surface modification by oil
    Bernard P Binks
    Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Soft Matter 12:6858-67. 2016
    ..Complementary experiments including relevant oil-water-solid contact angles and infra-red analysis of dried particles after contact with oil support the proposed mechanism. ..
  12. ncbi request reprint Enhanced stabilization of emulsions due to surfactant-induced nanoparticle flocculation
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, HU6 7RX, U K
    Langmuir 23:7436-9. 2007
    ..Here, we extend the idea using positively charged silica particles in mixtures with anionic surfactant...
  13. ncbi request reprint Synergistic stabilization of emulsions by a mixture of surface-active nanoparticles and surfactant
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, U K
    Langmuir 23:1098-106. 2007
    ..This results from a competition between the influence of particle hydrophobicity and interfacial tension on the magnitude of E...
  14. ncbi request reprint Effect of pH and salt concentration on the phase inversion of particle-stabilized foams
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, UK
    Langmuir 23:9143-6. 2007
    ..The results are rationalized in terms of changes in the hydrophobicity of the solid surfaces, probed by measurement of the contact angles of water drops on hydrophobized glass slides in air...
  15. ncbi request reprint Novel stabilisation of emulsions by soft particles: polyelectrolyte complexes
    Ana Maria Bago Rodriguez
    Department of Chemistry, University of Hull, Hull, HU6 7RX, UK
    Faraday Discuss 191:255-285. 2016
    ....
  16. doi request reprint Oil-in-oil emulsions stabilised solely by solid particles
    Bernard P Binks
    Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Soft Matter 12:876-87. 2016
    ..Consistent with the above findings, we find that only sufficiently hydrophobic particles (clay, zinc oxide, silicone, calcium carbonate) can act as efficient V/S emulsion stabilisers. ..
  17. doi request reprint Emulsions stabilised by whey protein microgel particles: towards food-grade Pickering emulsions
    Mathieu Destribats
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Soft Matter 10:6941-54. 2014
    ....
  18. doi request reprint Dry oil powders and oil foams stabilised by fluorinated clay platelet particles
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, HU6 7RX, UK
    Soft Matter 10:578-89. 2014
    ..Above the COPR, catastrophic phase inversion occurs yielding an ultra-stable air-in-oil foam. We thus demonstrate the ability to disperse oil drops or air bubbles coated with particles within novel materials. ..
  19. doi request reprint Influence of propylene glycol on aqueous silica dispersions and particle-stabilized emulsions
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, UK
    Langmuir 29:5723-33. 2013
    ....
  20. doi request reprint Direct measurement of contact angles of silica particles in relation to double inversion of pickering emulsions
    Bernard Paul Binks
    Department of Chemistry, University of Hull, Hull, UK
    Langmuir 29:4923-7. 2013
    ..These results unequivocally link the single-particle contact angles to the type of particle-stabilized emulsion, confirming macroscopic emulsion inversion on the microscopic level...
  21. doi request reprint Phase inversion of particle-stabilised perfume oil-water emulsions: experiment and theory
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, HU6 7RX, UK
    Phys Chem Chem Phys 12:11954-66. 2010
    ..Results of the latter two inversion routes are combined to develop an emulsion compositional map allowing a variety of emulsions with different characteristics to be described by varying the relative amounts of the three components...
  22. ncbi request reprint Temperature-induced inversion of nanoparticle-stabilized emulsions
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Angew Chem Int Ed Engl 44:4795-8. 2005
  23. ncbi request reprint Inversion of emulsions stabilized solely by ionizable nanoparticles
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Angew Chem Int Ed Engl 44:441-4. 2005
  24. doi request reprint Selective retardation of perfume oil evaporation from oil-in-water emulsions stabilized by either surfactant or nanoparticles
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, United Kingdom
    Langmuir 26:18024-30. 2010
    ..Surfactant films are less effective than adsorbed films of nanoparticles, and the retardation can be further enhanced by compression of the adsorbed nanoparticle films by preshrinking the emulsion drops...
  25. doi request reprint Membrane permeation of testosterone from either solutions, particle dispersions, or particle-stabilized emulsions
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Langmuir 28:2510-22. 2012
    ....
  26. ncbi request reprint Particle-stabilized emulsions: a bilayer or a bridging monolayer?
    Tommy S Horozov
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, HU6 7RX, UK
    Angew Chem Int Ed Engl 45:773-6. 2006
  27. ncbi request reprint Effect of electrolyte in silicone oil-in-water emulsions stabilised by fumed silica particles
    Tommy S Horozov
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, UK HU6 7RX
    Phys Chem Chem Phys 9:6398-404. 2007
    ..The drastic improvement of the stability to creaming is attributed to the formation of a visco-elastic three-dimensional network of interconnected particles and emulsion droplets...
  28. doi request reprint How membrane permeation is affected by donor delivery solvent
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, HU6 7RX, UK
    Phys Chem Chem Phys 14:15525-38. 2012
    ..These effects include a change in rate-limiting step, permeant solution non-ideality and others...
  29. doi request reprint Evaporation of Sunscreen Films: How the UV Protection Properties Change
    Bernard P Binks
    Department of Chemistry, University of Hull, Hull HU6 7RX, United Kingdom
    ACS Appl Mater Interfaces 8:13270-81. 2016
    ..Overall, it is hoped that the understanding gained about the mechanisms whereby film evaporation affects the SPF will provide useful guidance for the formulation of more effective sunscreens. ..
  30. ncbi request reprint Drop sizes and particle coverage in emulsions stabilised solely by silica nanoparticles of irregular shape
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, UK
    Phys Chem Chem Phys 12:11967-74. 2010
    ..Some particle desorption occurs but this is a secondary effect...
  31. ncbi request reprint Compositional ripening of particle- and surfactant-stabilised emulsions: a comparison
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, UKHU6 7RX
    Phys Chem Chem Phys 12:2219-26. 2010
    ..Addition of excess, non-adsorbed particles to the particle-stabilised emulsions suppresses the swelling-triggered coalescence and causes a switchover from particle to surfactant behaviour...
  32. doi request reprint Evaporation of Particle-Stabilized Emulsion Sunscreen Films
    Bernard P Binks
    Department of Chemistry, University of Hull, Hull HU6 7RX, United Kingdom
    ACS Appl Mater Interfaces 8:21201-13. 2016
    ..Measured UV spectra during evaporation are in reasonable agreement with spectra calculated using models discussed here. ..
  33. doi request reprint Oil powders and gels from particle-stabilized emulsions
    Horst Adelmann
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, United Kingdom
    Langmuir 28:1694-7. 2012
    ..Comparisons are made throughout with a typical surfactant-stabilized emulsion which does not produce oil powders or gels...
  34. ncbi request reprint Novel film-calliper method of measuring the contact angle of colloidal particles at liquid interfaces
    Tommy S Horozov
    Department of Chemistry, University of Hull, Hull HU6 7RX, United Kingdom T S
    Langmuir 24:1678-81. 2008
    ..Its applicability to submicrometer and micrometer latex and silica particles is demonstrated...
  35. ncbi request reprint Structure and stability of silica particle monolayers at horizontal and vertical octane-water interfaces
    Tommy S Horozov
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, HU6 7RX, UK
    Langmuir 21:7405-12. 2005
    ....
  36. doi request reprint Particles at Oil-Air Surfaces: Powdered Oil, Liquid Oil Marbles, and Oil Foam
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, U K
    ACS Appl Mater Interfaces 7:14328-37. 2015
    ..When sheared on a substrate, the dry oil powders containing at least 60 wt % of oil release the encapsulated oil, making these materials attractive formulations in the cosmetic and food industries. ..
  37. ncbi request reprint Stability of suspensions, emulsions, and foams studied by a novel automated analyzer
    Tommy S Horozov
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, U K
    Langmuir 20:9007-13. 2004
    ..The new analyzer differs from the existing instruments by its simplicity and high productivity, allowing 24 samples to be measured simultaneously...
  38. doi request reprint Particle-Stabilized Powdered Water-in-Oil Emulsions
    Bernard P Binks
    Department of Chemistry, University of Hull, Hull HU6 7RX, U K
    Langmuir 32:3110-5. 2016
    ....
  39. doi request reprint Double oil-in-oil-in-oil emulsions stabilised solely by particles
    Andrew T Tyowua
    Department of Chemistry, University of Hull, Hull HU6 7RX, UK Applied Colloid Science and Catalysis Group, Department of Chemistry, Benue State University, PMB 102119 Makurdi, Nigeria Electronic address
    J Colloid Interface Sci 488:127-134. 2017
    ..Values of oil-oil-solid particle contact angles θoo, measured on microscope glass slides composed of the particles, are in good agreement with the type of simple emulsions and hence double emulsions formed by the particles...
  40. doi request reprint How polymer additives reduce the pour point of hydrocarbon solvents containing wax crystals
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull, HU6 7RX, UK
    Phys Chem Chem Phys 17:4107-17. 2015
    ..This finding and the mechanistic insight gained here provide the basis for a simple and rapid screening test to identify candidate species likely to be effective PPDs for particular wax systems. ..
  41. ncbi request reprint Quantitative Prediction of the Reduction of Corrosion Inhibitor Effectiveness Due to Parasitic Adsorption onto a Competitor Surface
    Bernard P Binks
    Surfactant and Colloid Group, Department of Chemistry, University of Hull, Hull HU6 7RX, U K
    Langmuir 27:469-73. 2011
    ..This methodology demonstrates how the optimization of a corrosion inhibitor formulation for specific application conditions should take into account the parasitic adsorption of the inhibitor onto the competitor surfaces present...
  42. ncbi request reprint Steric stabilization of core-shell nanoparticles in liquid carbon dioxide at the vapor pressure
    Jasper L Dickson
    Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712, USA
    Langmuir 20:9380-7. 2004
    ..Compared to polymeric chains, the perfluorodecane side chains are more easily solvated and thus stabilize nanoparticle dispersions in CO2 at much lower pressures, even down to the vapor pressure...
  43. ncbi request reprint Stabilization of carbon dioxide-in-water emulsions with silica nanoparticles
    Jasper L Dickson
    Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712, USA
    Langmuir 20:7976-83. 2004
    ..739 g/mL is particularly relevant in practical applications, given the difficulty in stabilizing these emulsions with surfactants, because of the unusually weak solvation of the surfactant tails by CO(2)...