Damien M Murphy

Summary

Affiliation: Cardiff University
Country: UK

Publications

  1. ncbi request reprint Visualizing diastereomeric interactions of chiral amine-chiral copper salen adducts by EPR spectroscopy and DFT
    Damien M Murphy
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United Kingdom
    Inorg Chem 50:6944-55. 2011
  2. doi request reprint A CW-EPR, ENDOR and special TRIPLE resonance study of a novel magnesium ketyl radical
    Damien M Murphy
    School of Chemistry, Cardiff University, Park Place, Cardiff, UK
    Magn Reson Chem 49:159-63. 2011
  3. ncbi request reprint An EPR, ENDOR and EIE study of gamma-irradiated poly (lactide-co-glycolide) polymers
    James A Bushell
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK
    Magn Reson Chem 44:929-35. 2006
  4. doi request reprint An ENDOR and DFT analysis of hindered methyl group rotations in frozen solutions of bis(acetylacetonato)-copper(II)
    Katherine M Sharples
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK
    Phys Chem Chem Phys 15:15214-22. 2013
  5. ncbi request reprint Enantioselective binding of structural epoxide isomers by a chiral vanadyl salen complex: a pulsed EPR, cw-ENDOR and DFT investigation
    Damien M Murphy
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UKCF10 3AT
    Phys Chem Chem Phys 11:6757-69. 2009
  6. doi request reprint Structure determination of bound nitrogen-based adducts with copper(ii) acetylacetonato; an EPR, ENDOR and DFT study
    Emma Carter
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK
    Phys Chem Chem Phys 17:11445-54. 2015
  7. ncbi request reprint Redox non-innocence of thioether crowns: elucidation of the electronic structure of the mononuclear Pd(III) complexes [Pd([9]aneS3)2]3+ and [Pd([18]aneS6)]3+
    Emma Stephen
    School of Chemistry, University of Nottingham, Nottingham, NG7 2RD, UK
    Inorg Chem 51:1450-61. 2012
  8. doi request reprint The benzaldehyde oxidation paradox explained by the interception of peroxy radical by benzyl alcohol
    Meenakshisundaram Sankar
    Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK
    Nat Commun 5:3332. 2014
  9. doi request reprint Structure, EPR/ENDOR and DFT characterisation of a [Cu(II)(en)2](OTf)2 complex
    Emma Carter
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK
    Dalton Trans 42:15088-96. 2013
  10. doi request reprint Aryl azide photochemistry in defined protein environments
    Josephine L Morris
    School of Chemistry, Cardiff University, Cardiff CF10 3AT United Kingdom
    Org Lett 15:728-31. 2013

Collaborators

Detail Information

Publications17

  1. ncbi request reprint Visualizing diastereomeric interactions of chiral amine-chiral copper salen adducts by EPR spectroscopy and DFT
    Damien M Murphy
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United Kingdom
    Inorg Chem 50:6944-55. 2011
    ..A delicate balance of steric repulsion between the α-proton (attached to the asymmetric carbon atom) of MBA and the methine proton (attached to the asymmetric carbon atom) of [Cu(1)] was crucial in the stereoselective binding...
  2. doi request reprint A CW-EPR, ENDOR and special TRIPLE resonance study of a novel magnesium ketyl radical
    Damien M Murphy
    School of Chemistry, Cardiff University, Park Place, Cardiff, UK
    Magn Reson Chem 49:159-63. 2011
    ..At lower temperatures, restricted rotations of the diphenyl rings create an inequivalent spin distribution in the two rings, with o(1)-H = 8.80, o(2)-H = 7.85, m-H = 3.00 and p-H = 10.00 MHz...
  3. ncbi request reprint An EPR, ENDOR and EIE study of gamma-irradiated poly (lactide-co-glycolide) polymers
    James A Bushell
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK
    Magn Reson Chem 44:929-35. 2006
    ..This work demonstrates the utility of the EIE approach to supplement and aid the interpretation of powder EPR spectra of radicals in a polymer matrix...
  4. doi request reprint An ENDOR and DFT analysis of hindered methyl group rotations in frozen solutions of bis(acetylacetonato)-copper(II)
    Katherine M Sharples
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK
    Phys Chem Chem Phys 15:15214-22. 2013
    ..This hindered rotation appears to be caused by weak outer-sphere solvent interactions with the complex...
  5. ncbi request reprint Enantioselective binding of structural epoxide isomers by a chiral vanadyl salen complex: a pulsed EPR, cw-ENDOR and DFT investigation
    Damien M Murphy
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UKCF10 3AT
    Phys Chem Chem Phys 11:6757-69. 2009
    ..These findings reveal the potential importance of weak outer sphere interactions in stereoselectivities of enantioselective homogeneous catalysis...
  6. doi request reprint Structure determination of bound nitrogen-based adducts with copper(ii) acetylacetonato; an EPR, ENDOR and DFT study
    Emma Carter
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK
    Phys Chem Chem Phys 17:11445-54. 2015
    ..These results reveal how important structural information on the coordination geometry of Cu(ii) adducts can be obtained by (1)H ENDOR, but only when the complete angular dependency profile of the ENDOR data is thoroughly considered. ..
  7. ncbi request reprint Redox non-innocence of thioether crowns: elucidation of the electronic structure of the mononuclear Pd(III) complexes [Pd([9]aneS3)2]3+ and [Pd([18]aneS6)]3+
    Emma Stephen
    School of Chemistry, University of Nottingham, Nottingham, NG7 2RD, UK
    Inorg Chem 51:1450-61. 2012
    ..4% and 25% Pd character in [Pd([9]aneS(3))(2)](3+) and [Pd([18]aneS(6))](3+), respectively, consistent with the compositions calculated from scalar relativistic DFT calculations...
  8. doi request reprint The benzaldehyde oxidation paradox explained by the interception of peroxy radical by benzyl alcohol
    Meenakshisundaram Sankar
    Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK
    Nat Commun 5:3332. 2014
    ..A similar inhibition effect has also been observed for the aliphatic octanal/1-octanol system. ..
  9. doi request reprint Structure, EPR/ENDOR and DFT characterisation of a [Cu(II)(en)2](OTf)2 complex
    Emma Carter
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK
    Dalton Trans 42:15088-96. 2013
    ....
  10. doi request reprint Aryl azide photochemistry in defined protein environments
    Josephine L Morris
    School of Chemistry, Cardiff University, Cardiff CF10 3AT United Kingdom
    Org Lett 15:728-31. 2013
    ..Following photolysis of mutant T4 lysozyme or green fluorescent proteins, EPR spectra showed, respectively, the presence of a triplet nitrene and an anilino radical...
  11. doi request reprint Interaction of an endosomolytic polyamidoamine ISA23 with vesicles mimicking intracellular membranes: A SANS/EPR study
    Peter C Griffiths
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK
    Macromol Biosci 10:963-73. 2010
    ..The vesicle-mimetic models used here provide a new and useful tool for studying endosomolytic polymer/membrane interactions...
  12. ncbi request reprint Principles and applications of ENDOR spectroscopy for structure determination in solution and disordered matrices
    Damien M Murphy
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UKCF10 3AT
    Chem Soc Rev 35:249-68. 2006
    ..The theory of orientation selective ENDOR, for structure determination in frozen solutions and powders, is then described. A range of examples, illustrating the type of information obtained from the ENDOR spectrum, is finally presented...
  13. doi request reprint Cyclohexane oxidation using Au/MgO: an investigation of the reaction mechanism
    Marco Conte
    Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff, CF10 3AT, UK
    Phys Chem Chem Phys 14:16279-85. 2012
    ....
  14. doi request reprint Iron(I) in Negishi cross-coupling reactions
    Christopher J Adams
    School of Chemistry, University of Bristol, Cantock s Close, Bristol BS8 1TS, UK
    J Am Chem Soc 134:10333-6. 2012
    ..The complexes are low-spin with no significant spin density on the ligands. While complex 8b shows performance consistent with an on-cycle intermediate, it seems that 7 is an off-cycle species...
  15. doi request reprint Influence of counterions on the structure of bis(oxazoline)copper(II) complexes; an EPR and ENDOR investigation
    Mari Elena Owen
    School of Chemistry, Cardiff University, Cardiff, UK
    Dalton Trans 41:11085-92. 2012
    ..The hyperfine and quadrupole parameters for the surrounding ligand nuclei were determined by ENDOR. Well resolved (19)F and (1)H couplings confirmed the presence of both coordinated water and TfO(-) counterions in [Cu(1a)]...
  16. ncbi request reprint Experimental observation of spin delocalisation onto the aryl-alkynyl ligand in the complexes [Mo(C≡CAr)(Ph2PCH2CH2PPh2)(η-C7H7)]+ (Ar = C6H5, C6H4-4-F; C7H7 = cycloheptatrienyl): an EPR and ENDOR investigation
    Emma Carter
    School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK CF10 3AT
    Dalton Trans 39:11424-31. 2010
    ..7 MHz (±1.3 G) and para, ±3.9 MHz (±1.4 G) positions of the C(6)H(5) substituent of the aryl-alkynyl ligand...
  17. ncbi request reprint An EPR and ENDOR study of gamma- and beta-radiation sterilization in poly (lactide-co-glycolide) polymers and microspheres
    James A Bushell
    School of Chemistry, Cardiff University, UK
    J Control Release 110:49-57. 2005
    ....