A Corma

Summary

Country: Spain

Publications

  1. ncbi request reprint A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Nature 418:514-7. 2002
  2. ncbi request reprint Preparation of substituted anilines from nitro compounds by using supported gold catalysts
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Av los Naranjos, S N, Valencia 46022, Spain
    Nat Protoc 1:2590-5. 2006
  3. ncbi request reprint Integrating chemists preferences for shape-similarity clustering of series
    Laurent A Baumes
    Instituto de Tecnologia Quimica, UPV CSIC, Valencia, Spain
    Comb Chem High Throughput Screen 11:266-82. 2008
  4. ncbi request reprint Cluster and periodic calculations of the ethene protonation reaction catalyzed by theta-1 zeolite: influence of method, model size, and structural constraints
    M Boronat
    Instituto de Tecnología Química UPV CSIC Universidad Politécnica de Valencia, Spain
    Chemistry 7:1295-303. 2001
  5. ncbi request reprint Gold supported on a mesoporous CeO2 matrix as an efficient catalyst in the selective aerobic oxidation of aldehydes in the liquid phase
    Avelino Corma
    Instituto de Tecnologia Quimica CSIC UPV, Universidad Politecnica de Valencia, Avda Los Naranjos s n, 46022, Valencia, Spain
    Chem Commun (Camb) . 2005
  6. ncbi request reprint Single-site homogeneous and heterogeneized gold(III) hydrogenation catalysts: mechanistic implications
    Aleix Comas-Vives
    Instituto de Quimica Organica General, CSIC, C Juan de la Cierva 3, 28006 Madrid, Spain
    J Am Chem Soc 128:4756-65. 2006
  7. doi request reprint Cu and Au metal-organic frameworks bridge the gap between homogeneous and heterogeneous catalysts for alkene cyclopropanation reactions
    Avelino Corma
    Inst Tecnología Química, UPV CSIC, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones Cientificas, Avda los Naranjos, S N, 46022 Valencia, Spain
    Chemistry 16:9789-95. 2010
  8. ncbi request reprint Synthesis of micro- and mesoporous molecular sieves at room temperature and neutral pH catalyzed by functional analogues of silicatein
    Avelino Corma
    Instituto de Tecnologia Quimica CSIC UPV, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022, Valencia, Spain
    Chem Commun (Camb) . 2006
  9. ncbi request reprint Replacing HCl by solid acids in industrial processes: synthesis of diamino diphenyl methane (DADPM) for producing polyurethanes
    Avelino Corma
    Instituto Tecnología Química, UPV CSIC, Avda Los Naranjos s n, 46022 Valencia, Spain
    Chem Commun (Camb) . 2004
  10. ncbi request reprint Hierarchically mesostructured doped CeO2 with potential for solar-cell use
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Nat Mater 3:394-7. 2004

Collaborators

  • Jihong Yu
  • Aleix Comas-Vives
  • Pablo Botella
  • Mark E Davis
  • German Sastre
  • J Jiang
  • D L Dorset
  • Antonio Leyva
  • Fei Gao
  • Laurent A Baumes
  • Manuel Moliner
  • Mercedes Boronat
  • Nuria Martin
  • Hermenegildo Garcia
  • Maria J Climent
  • Urbano Díaz
  • Patricia Concepción
  • Sara Iborra
  • Zhibin Li
  • Susana Valencia
  • M Boronat
  • George W Huber
  • Angel Cantín
  • Pedro Atienzar
  • Mercedes Alvaro
  • Teresa Blasco
  • Joaquín Martínez-Triguero
  • P V Escrig
  • Judit Oliver-Meseguer
  • F G Cirujano
  • Miguel Palomino
  • Enrica Gianotti
  • Ana Primo
  • Amarajothi Dhakshinamoorthy
  • Abdessamad Grirrane
  • Nicolas Villandier
  • Ana Belen Fernandez
  • Onofre Casanova
  • Mercè Boronat
  • Jose L Jorda
  • Fernando Rey
  • Carmela Aprile
  • Pedro Montes-Navajas
  • David Law
  • J Primo
  • Jose Manuel Serra
  • Maria J Diaz-Cabanas
  • Jean Yves Chane-Ching
  • Simon R Bare
  • Cristian R Boruntea
  • A Pulido
  • Laura Martí
  • P Concepción
  • E Primo-Millo
  • Antonio Leyva-Pérez
  • Saud I Al-Resayes
  • Yolanda Perez
  • N Cabedo
  • Mariano Fajardo
  • J C Hernandez-Garrido
  • D J Iglesias
  • J J Calvino
  • Daniel Brunel
  • Marie Grill
  • Cristina Franch
  • F X Llabrés I Xamena
  • Eduardo Palomares
  • J Muñoz-Pallares
  • Salvatore Coluccia
  • Cristina Martinez
  • Ines Lezcano-Gonzalez
  • Francesc Illas
  • Laura L Santos
  • Michael Renz
  • Cristina Martínez-Sánchez
  • David Fabuel
  • Jose Alejandro Vidal-Moya
  • Encarna Peris
  • Jose F Cabeza
  • Pedro Serna
  • Frederic Cobo
  • Wharton Sinkler
  • Shelly D Kelly
  • Daniel Aubert
  • John J Low
  • Marc Airiau
  • Laszlo T Nemeth
  • Jordi Rius
  • Frank S Modica
  • Sandra Leiva

Detail Information

Publications87

  1. ncbi request reprint A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Nature 418:514-7. 2002
    ..74-nm-wide windows. As expected for a zeolite with this structure, ITQ-21 exhibits high catalytic activity and selectivity for valuable products in preliminary oil refining tests...
  2. ncbi request reprint Preparation of substituted anilines from nitro compounds by using supported gold catalysts
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Av los Naranjos, S N, Valencia 46022, Spain
    Nat Protoc 1:2590-5. 2006
    ..The total time to carry out this protocol strongly depends on the reaction step, which is a function of the activity of the catalyst and the nature of the substrate...
  3. ncbi request reprint Integrating chemists preferences for shape-similarity clustering of series
    Laurent A Baumes
    Instituto de Tecnologia Quimica, UPV CSIC, Valencia, Spain
    Comb Chem High Throughput Screen 11:266-82. 2008
    ....
  4. ncbi request reprint Cluster and periodic calculations of the ethene protonation reaction catalyzed by theta-1 zeolite: influence of method, model size, and structural constraints
    M Boronat
    Instituto de Tecnología Química UPV CSIC Universidad Politécnica de Valencia, Spain
    Chemistry 7:1295-303. 2001
    ....
  5. ncbi request reprint Gold supported on a mesoporous CeO2 matrix as an efficient catalyst in the selective aerobic oxidation of aldehydes in the liquid phase
    Avelino Corma
    Instituto de Tecnologia Quimica CSIC UPV, Universidad Politecnica de Valencia, Avda Los Naranjos s n, 46022, Valencia, Spain
    Chem Commun (Camb) . 2005
    ..Gold supported on CeO2 catalyses the selective aerobic oxidation of aliphatic and aromatic aldehydes better than other reported catalysts such as Pt/C/Bi materials; the activity is due to the nanometric particle size of Au and CeO2...
  6. ncbi request reprint Single-site homogeneous and heterogeneized gold(III) hydrogenation catalysts: mechanistic implications
    Aleix Comas-Vives
    Instituto de Quimica Organica General, CSIC, C Juan de la Cierva 3, 28006 Madrid, Spain
    J Am Chem Soc 128:4756-65. 2006
    ....
  7. doi request reprint Cu and Au metal-organic frameworks bridge the gap between homogeneous and heterogeneous catalysts for alkene cyclopropanation reactions
    Avelino Corma
    Inst Tecnología Química, UPV CSIC, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones Cientificas, Avda los Naranjos, S N, 46022 Valencia, Spain
    Chemistry 16:9789-95. 2010
    ..This type of material gives better results than previous solid catalysts while working together with the homogeneous catalysts. These MOFs can help to bridge the gap between homogeneous and heterogeneous catalysis...
  8. ncbi request reprint Synthesis of micro- and mesoporous molecular sieves at room temperature and neutral pH catalyzed by functional analogues of silicatein
    Avelino Corma
    Instituto de Tecnologia Quimica CSIC UPV, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022, Valencia, Spain
    Chem Commun (Camb) . 2006
    ..By using functional mimics of the protein silicatein alpha together with organic structure directing agents, it was possible to produce different mesoporous and microporous molecular sieves at room temperature and neutral pH...
  9. ncbi request reprint Replacing HCl by solid acids in industrial processes: synthesis of diamino diphenyl methane (DADPM) for producing polyurethanes
    Avelino Corma
    Instituto Tecnología Química, UPV CSIC, Avda Los Naranjos s n, 46022 Valencia, Spain
    Chem Commun (Camb) . 2004
    ..Delaminated zeolite catalysts allow replacement of HCl in the production of DADPM: they offer higher activity and catalyst life than conventional zeolites, and their structured external surface controls product selectivity...
  10. ncbi request reprint Hierarchically mesostructured doped CeO2 with potential for solar-cell use
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Nat Mater 3:394-7. 2004
    ..We have constructed operational organic-dye-free solar cells using nanometric ceria particles (in both mesostructured or amorphous forms) as the active component, and find efficiencies that depend on the illuminating power...
  11. ncbi request reprint Issues in the synthesis of crystalline molecular sieves: towards the crystallization of low framework-density structures
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Chemphyschem 5:305-13. 2004
    ..Synthesis mechanisms and the parameters that can direct the crystal assembly pathway and the ultimate product formed are discussed and rationalized...
  12. ncbi request reprint Sn-Beta zeolite as diastereoselective water-resistant heterogeneous Lewis-acid catalyst for carbon-carbon bond formation in the intramolecular carbonyl-ene reaction
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Avda de los naranjos s n, 46022 Valencia, Spain
    Chem Commun (Camb) . 2004
    ..The water-tolerant Lewis acid Sn-Beta isomerises citronellal to isopulegol with high diastereoselectivity working in batch or in fixed bed reactors with very high turnover numbers...
  13. doi request reprint High yield synthesis of high-silica chabazite by combining the role of zeolite precursors and tetraethylammonium: SCR of NOx
    Nuria Martin
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones Cientificas, Valencia, 46022, Spain
    Chem Commun (Camb) 51:9965-8. 2015
    ..Moreover, Cu-CHA materials prepared by post-synthetic and "one-pot" methodologies show high activity and stability for SCR of NOx. ..
  14. ncbi request reprint Synthesis of ITQ-21 in OH- media
    A Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Chem Commun (Camb) . 2003
    ....
  15. doi request reprint Heterogeneous Catalysis: Understanding for Designing, and Designing for Applications
    Avelino Corma
    UPV CSIC, Universidad Politecnica de Valencia, Instituto de Tecnologia Quimica, Avda de los naranjos s n, Valencia, 46022, Spain
    Angew Chem Int Ed Engl 55:6112-3. 2016
    ....
  16. ncbi request reprint Al-free Sn-Beta zeolite as a catalyst for the selective reduction of carbonyl compounds (Meerwein-Ponndorf-Verley reaction)
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avenida de los Naranjos s n, 46022 Valencia, Spain
    J Am Chem Soc 124:3194-5. 2002
    ..This heterogeneous catalyst exhibits activities and selectivities not observed before with other Me-zeolites...
  17. ncbi request reprint Sn-MCM-41--a heterogeneous selective catalyst for the Baeyer-Villiger oxidation with hydrogen peroxide
    A Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Avda de los naranjos s n, 46022 Valencia, Spain
    Chem Commun (Camb) . 2001
    ....
  18. ncbi request reprint ITQ-16, a new zeolite family of the beta group with different proportions of polymorphs A, B and C
    A Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Chem Commun (Camb) . 2001
    ....
  19. ncbi request reprint High-throughput synthesis and catalytic properties of a molecular sieve with 18- and 10-member rings
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Nature 443:842-5. 2006
    ..The conditions for synthesis are easily accessible, but are not typical, and were identified using high-throughput techniques...
  20. doi request reprint Spiers Memorial Lecture. Heterogeneous catalysis: understanding the fundamentals for catalyst design
    Avelino Corma
    Instituto de Tecnología Química UPV CSIC, Universitat Politècnica de València Consejo Superior de Investigaciones Científicas, Valencia, 46022, Spain
    Faraday Discuss 188:9-20. 2016
    ..Then, materials synthesis methods can be applied to prepare catalysts with the desired surface active sites and their selective interaction with the reactants. ..
  21. ncbi request reprint Chemoselective hydrogenation of nitro compounds with supported gold catalysts
    Avelino Corma
    Instituto de Tecnologia Quimica, Universidad Politecnica de Valencia Consejo Superior de Investigaciones Cientificas, Avenida Los Naranjos, S N, 46022 Valencia, Spain
    Science 313:332-4. 2006
    ..These chemoselective hydrogenation gold catalysts also provide a previously unknown route for the synthesis of the industrially relevant cyclohexanone oxime from 1-nitro-1-cyclohexene...
  22. doi request reprint Direct synthesis of a photoactive inorganic-organic mesostructured hybrid material and its application as a photocatalyst
    Avelino Corma
    Instituto de Tecnología Química UPV CSIC, Avenida Los Naranjos s n, 46022, Valencia, Spain
    Chemphyschem 10:1084-9. 2009
    ..The material is stable and can be recycled without loss of the photochemical activity...
  23. doi request reprint Synthesis of bifunctional Au-Sn organic-inorganic catalysts for acid-free hydroamination reactions
    Avelino Corma
    Instituto Universitario Mixto de Tecnología Química, UPV CSIC, Avda de los naranjos s n, 46022, Valencia, Spain
    Chem Commun (Camb) . 2008
    ..Gold(III) complexes heterogenized on the surface of a Sn-containing MCM-41 are efficient recyclable catalysts for hydroamination reactions, without requiring any acid promoters...
  24. doi request reprint Transforming nonselective into chemoselective metal catalysts for the hydrogenation of substituted nitroaromatics
    Avelino Corma
    Instituto de Tecnología Química UPV CSIC, Av De Los Naranjos s n, 46022 Valencia, Spain
    J Am Chem Soc 130:8748-53. 2008
    ..By doing this, it has been possible to change the relative rate for hydrogenating competitive groups present in the molecule by almost 2 orders of magnitude, increasing the chemoselectivity from less than 1% to more than 95%...
  25. ncbi request reprint On the activation of molecular hydrogen by gold: a theoretical approximation to the nature of potential active sites
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Av los Naranjos, S N, E 46022 Valencia, Spain
    Chem Commun (Camb) . 2007
    ....
  26. doi request reprint Nanocrystalline SSZ-39 zeolite as an efficient catalyst for the methanol-to-olefin (MTO) process
    Nuria Martin
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones Cientificas, Valencia, 46022, Spain
    Chem Commun (Camb) 52:6072-5. 2016
    ..The obtained SSZ-39 material shows a remarkably high catalyst lifetime compared to conventional SSZ-13 and SSZ-39 materials. ..
  27. doi request reprint Efficient synthesis of the Cu-SSZ-39 catalyst for DeNOx applications
    Nuria Martin
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones, Cientificas, Valencia, 46022, Spain
    Chem Commun (Camb) 51:11030-3. 2015
    ....
  28. ncbi request reprint Application of artificial neural networks to combinatorial catalysis: modeling and predicting ODHE catalysts
    Avelino Corma
    Instituto de Technología Química UPV CSIC av Los naranjos s n, 46022 Valencia, Spain
    Chemphyschem 3:939-45. 2002
    ....
  29. ncbi request reprint ITQ-15: the first ultralarge pore zeolite with a bi-directional pore system formed by intersecting 14- and 12-ring channels, and its catalytic implications
    Avelino Corma
    Instituto de Tecnologia Quimica CSIC UPV, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Chem Commun (Camb) . 2004
    ....
  30. ncbi request reprint Zeolite-based photocatalysts
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Av De Los Naranjos s n, 46022 Valencia, Spain
    Chem Commun (Camb) . 2004
    ..This review gives special emphasis to the commercial and potential application of photocatalysts...
  31. ncbi request reprint Supramolecular self-assembled molecules as organic directing agent for synthesis of zeolites
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Nature 431:287-90. 2004
    ..We have also extended the use of our supramolecular structure-directing agents to the synthesis of a range of other zeolites...
  32. doi request reprint Layered zeolitic materials: an approach to designing versatile functional solids
    Urbano Díaz
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avenida de los Naranjos s n, E 46022 Valencia, Spain
    Dalton Trans 43:10292-316. 2014
    ..The catalytic applications of the layered zeolites are also highlighted, pointing out the high accessibility and reactivity of active sites present in the lamellar framework. ..
  33. doi request reprint Solid catalysts for multistep reactions: one-pot synthesis of 2,3-dihydro-1,5-benzothiazepines with solid acid and base catalysts
    Maria J Climent
    Instituto de Tecnología Química UPV CSIC, Universitat Politècnica de València, Avda dels Tarongers s n, 46022, Valencia Spain, Fax 34 963877809
    ChemSusChem 7:1177-85. 2014
    ....
  34. doi request reprint One-pot palladium-catalyzed borrowing hydrogen synthesis of thioethers
    Avelino Corma
    Instituto de Tecnología Química UPV CSIC, Avda Los Naranjos s n, 46022 Valencia Spain, Fax 34 963877809
    Chemistry 19:17464-71. 2013
    ..The latter reacts with a thiol involving most probably the intermediacy of a thionium ion RCH=S(+)R, which can be reduced in situ by the metal hydride to afford thioethers...
  35. doi request reprint Formation and stability of 3-5 atom gold clusters from gold complexes during the catalytic reaction: dependence on ligands and counteranions
    Judit Oliver-Meseguer
    Instituto de Tecnologia Quimica, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones Cientificas, Avenida de los Naranjos s n, 46022 Valencia, Spain
    Chem Commun (Camb) 49:7782-4. 2013
    ..Kinetic and spectroscopic studies show that released ligands and counteranions exert a direct effect on the formation and stability of the clusters. ..
  36. doi request reprint Methanol to olefins: activity and stability of nanosized SAPO-34 molecular sieves and control of selectivity by silicon distribution
    Zhibin Li
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones Cientificas, Av De Los Naranjos s n, 46022 Valencia, Spain
    Phys Chem Chem Phys 15:14670-80. 2013
    ..The effects of equilibrium of olefins and deactivation by coke were isolated, showing that after full formation of the hydrocarbon pool, selectivity is independent of deactivation by coke. ..
  37. doi request reprint The promotional effect of Sn-beta zeolites on platinum for the selective hydrogenation of α,β-unsaturated aldehydes
    Patricia Concepción
    Instituto de Tecnologia Quimica CSIC UPV, Universidad Politecnica de Valencia, 46022 Valencia, Spain
    Phys Chem Chem Phys 15:12048-55. 2013
    ..These Pt(0)-Sn(4+) sites, which are only observed in the Pt/Sn-beta catalyst, have been shown to strongly activate the carbonyl group enhancing the hydrogenation rate of the C=O bond...
  38. doi request reprint Catalysis using multifunctional organosiliceous hybrid materials
    Urbano Díaz
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Avenida de los Naranjos s n, E 46022, Valencia, Spain
    Chem Soc Rev 42:4083-97. 2013
    ..Research on this subject for heterogeneous catalysts is still in the beginning stage and very interesting results can be expected if we are able to successfully combine the properties of organic and inorganic catalysts...
  39. doi request reprint Coupling of two multistep catalytic cycles for the one-pot synthesis of propargylamines from alcohols and primary amines on a nanoparticulated gold catalyst
    Avelino Corma
    Instituto de Tecnología Química UPV CSIC, Valencia, Spain
    Chemistry 18:14150-6. 2012
    ..The secondary amine formed enters into a second A(3)-coupling cycle to give propargylamines. The multistep reaction requires a gold species formed and stabilized on a ceria surface...
  40. doi request reprint Cu-SSZ-39, an active and hydrothermally stable catalyst for the selective catalytic reduction of NOx
    Manuel Moliner
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones Cientificas, Valencia, 46022, Spain
    Chem Commun (Camb) 48:8264-6. 2012
    ..A Cu-exchanged SSZ-39 zeolite has been synthesized and tested for the selective catalytic reduction (SCR) of NOx. This material shows an excellent catalytic activity, and most importantly, an extraordinary hydrothermal stability...
  41. ncbi request reprint MOFs as multifunctional catalysts: One-pot synthesis of menthol from citronellal over a bifunctional MIL-101 catalyst
    F G Cirujano
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones Cientificas, Avda de los Naranjos, S N, 46022 Valencia, Spain
    Dalton Trans 41:4249-54. 2012
    ....
  42. doi request reprint Gold catalyzes the Sonogashira coupling reaction without the requirement of palladium impurities
    Avelino Corma
    Instituto Universitario de Tecnología Química CSIC UPV, Universidad Politecnica de Valencia, Av de los Naranjos, S N, 46022 Valencia, Spain
    Chem Commun (Camb) 47:1446-8. 2011
    ..The presence of Pd impurities is not mandatory for catalyst activity...
  43. ncbi request reprint Reactivity in the confined spaces of zeolites: the interplay between spectroscopy and theory to develop structure-activity relationships for catalysis
    Mercedes Boronat
    , UPV CSIC, Avda de los naranjos s n, 46022, Valencia, Spain
    Phys Chem Chem Phys 11:2876-84. 2009
    ....
  44. pmc Extra-large pore zeolite (ITQ-40) with the lowest framework density containing double four- and double three-rings
    A Corma
    Instituto de Tecnologia Quimica, CSIC Universidad Politecnica de Valencia, Valencia, Spain
    Proc Natl Acad Sci U S A 107:13997-4002. 2010
    ..The results presented here push ahead the possibilities of zeolites for uses in electronics, control delivery of drugs and chemicals, as well as for catalysis...
  45. ncbi request reprint Zeolite Rho: a highly selective adsorbent for CO2/CH4 separation induced by a structural phase modification
    Miguel Palomino
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones Cientificas, Avenida de los Naranjos s n, 46022, Valencia, Spain
    Chem Commun (Camb) 48:215-7. 2012
    ..Zeolite Rho is able to successfully separate CO(2) from CH(4) with the highest selectivity ever observed on the basis of pore diameter and surface polarity. The adsorption of CO(2) provokes structural changes in the zeolite Rho...
  46. doi request reprint A recyclable bifunctional acid-base organocatalyst with ionic liquid character. The role of site separation and spatial configuration on different condensation reactions
    Avelino Corma
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia Consejo Superior de Investigaciones Cientificas, Avenida de los Naranjos s n, 46022 Valencia, Spain
    Phys Chem Chem Phys 13:17255-61. 2011
    ..The combination of the acid-base pairs within the proper geometry and the ionic liquid nature makes this catalyst active, selective and recyclable...
  47. ncbi request reprint Mechanistic differences between methanol and dimethyl ether carbonylation in side pockets and large channels of mordenite
    Mercedes Boronat
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia Consejo Superior de Investigaciones Cientificas, Avenida de los Naranjos s n, 46022 Valencia, Spain
    Phys Chem Chem Phys 13:2603-12. 2011
    ....
  48. doi request reprint Multifunctional hybrid organic-inorganic catalytic materials with a hierarchical system of well-defined micro- and mesopores
    Avelino Corma
    Instituto de Tecnología Química, UPV CSIC, Universidad Politécnica de Valencia, Avenida de los Naranjos s n, E 46022 Valencia, Spain
    J Am Chem Soc 132:15011-21. 2010
    ..The resultant materials can act as bifunctional catalysts for performing a two-step cascade reaction that involves the catalytic conversion of benzaldehyde dimethylacetal into benzylidene malononitrile...
  49. ncbi request reprint Gold catalysts open a new general chemoselective route to synthesize oximes by hydrogenation of alpha,beta-unsaturated nitrocompounds with H2
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Av Los Naranjos s n, Valencia, Spain
    J Am Chem Soc 129:6358-9. 2007
  50. ncbi request reprint A general method for the preparation of ethers using water-resistant solid lewis acids
    Avelino Corma
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Avenida de los Naranjos s n, 46022 Valencia, Spain
    Angew Chem Int Ed Engl 46:298-300. 2007
  51. doi request reprint Coupling fatty acids by ketonic decarboxylation using solid catalysts for the direct production of diesel, lubricants, and chemicals
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Avda Los Naranjos s n, 46022 Valencia, Spain
    ChemSusChem 1:739-41. 2008
  52. ncbi request reprint Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer-Villiger oxidations
    A Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Avda de los naranjos s n, 46022 Valencia, Spain
    Nature 412:423-5. 2001
    ..We ascribe this high selectivity to direct activation of the ketone group, whereas other catalysts first activate hydrogen peroxide, which can then interact with the ketone group as well as other functional groups...
  53. ncbi request reprint A zeolite with interconnected 8-, 10- and 12-ring pores and its unique catalytic selectivity
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Nat Mater 2:493-7. 2003
    ..This thermally and hydrothermally stable zeolite structure, when synthesized in its acidic form by incorporating aluminium in the framework, presents unique catalytic shape-selectivity effects derived from its particular pore topology...
  54. doi request reprint Surfactants from biomass: a two-step cascade reaction for the synthesis of sorbitol fatty acid esters using solid acid catalysts
    Avelino Corma
    Instituto de Technologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    ChemSusChem 1:85-90. 2008
    ....
  55. doi request reprint Boosting theoretical zeolitic framework generation for the determination of new materials structures using GPU programming
    Laurent A Baumes
    Insituto de Tecnologia Quimica, UPV CSIC, Valencia Spain
    Phys Chem Chem Phys 13:4674-8. 2011
    ..Using such hardware, the manuscript shows how an efficiently implemented genetic algorithm with a simple fitness function allows boosting the determination of zeolite structures. A case study is presented...
  56. doi request reprint Active sites for H2 adsorption and activation in Au/TiO2 and the role of the support
    Mercè Boronat
    Instituto de Tecnología Química UPV CSIC, Av De Los Naranjos s n, 46022 Valencia, Spain
    J Phys Chem A 113:3750-7. 2009
    ..The presence of Ovacancy defects in reduced surfaces preferentially stabilizes the most active 2L particles, while less active 1L isomers are the most stable on the stoichiometric surfaces...
  57. doi request reprint Isolable gold(I) complexes having one low-coordinating ligand as catalysts for the selective hydration of substituted alkynes at room temperature without acidic promoters
    Antonio Leyva
    Instituto de Tecnología Química UPV CSIC, Avda de los naranjos s n, 46022, Valencia, Spain
    J Org Chem 74:2067-74. 2009
    ..The described catalytic system should provide an efficient alternative to mercury-based methodologies and be useful in synthetic programs...
  58. doi request reprint Biomass into chemicals: aerobic oxidation of 5-hydroxymethyl-2-furfural into 2,5-furandicarboxylic acid with gold nanoparticle catalysts
    Onofre Casanova
    Instituto de Tecnología Química UPV CSIC, Universitat Politècnica de València, Avda dels Tarongers s n, 46022 Valencia, Spain
    ChemSusChem 2:1138-44. 2009
    ..Substrate degradation is strongly diminished and the catalyst life increased by performing the reaction in two temperature steps...
  59. doi request reprint Design of a full-profile-matching solution for high-throughput analysis of multiphase samples through powder X-ray diffraction
    Laurent A Baumes
    Instituto de Tecnologia Quimica, CSIC Universidad Politecnica de Valencia, UPV, Av de los Naranjos, s n 46022, Spain
    Chemistry 15:4258-69. 2009
    ....
  60. ncbi request reprint Zeolites as pheromone dispensers
    J Muñoz-Pallares
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avenida de los Naranjos s n, 46022 Valencia, Spain
    J Agric Food Chem 49:4801-7. 2001
    ..e., the higher the polarizability and the lower the polarity, the slower the release of attractants...
  61. doi request reprint Euphorbia characias as bioenergy crop: a study of variations in energy value components according to phenology and water status
    P V Escrig
    Instituto de Tecnología Química UPV CSIC, Avenida de los Naranjos s n, 46022 Valencia, Spain
    J Agric Food Chem 61:10096-109. 2013
    ..characias as a potential energy crop. The total water requirements to obtain the maximum yields of hexane- and methanol-extractables were determined for its annual development cycle. ..
  62. doi request reprint Enhancement of the photocatalytic activity of TiO2 through spatial structuring and particle size control: from subnanometric to submillimetric length scale
    Carmela Aprile
    Instituto de Tecnología QuímicaCSIC UPV, Universidad Politecnica de Valencia, Av De Los Naranjos s n, 46022, Valencia, Spain
    Phys Chem Chem Phys 10:769-83. 2008
    ....
  63. ncbi request reprint High-throughput characterisation of materials by photoluminescence spectroscopy
    Pedro Atienzar
    Instituto de Tecnologia Quimica CSIC UPV, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Chemistry 10:6043-7. 2004
    ..Here, we present its application to the optimisation of the ship-in-a-bottle synthesis of a novel electroluminescent polymer (PPV) and a photocatalyst (TP+), both encapsulated in large-pore zeolites...
  64. doi request reprint Study of the Beckmann rearrangement of acetophenone oxime over porous solids by means of solid state NMR spectroscopy
    Ana Belen Fernandez
    Instituto de Tecnologia Quimica, Valencia, Spain
    Phys Chem Chem Phys 11:5134-41. 2009
    ..In the presence of water, the reaction starts at 473 K, still being very selective up to 573 K, and the amide is partially hydrolyzed only above this temperature ...
  65. doi request reprint Enzyme-like specificity in zeolites: a unique site position in mordenite for selective carbonylation of methanol and dimethyl ether with CO
    Mercedes Boronat
    Instituto de Tecnologia Quimica, Universidad Politecnica de Valencia CSIC, Av De Los Naranjos s n, 46022 Valencia, Spain
    J Am Chem Soc 130:16316-23. 2008
    ..The competing effect of water is explained at the molecular level, and the molecular microkinetic reaction model has been established...
  66. ncbi request reprint Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering
    George W Huber
    Instituto de Tecnología Químicia, UPV CSIC, Universidad Politénica de Valencia, Avda de los Naranjos, S N, Valencia, Spain
    Chem Rev 106:4044-98. 2006
  67. doi request reprint Multisite solid catalyst for cascade reactions: the direct synthesis of benzodiazepines from nitro compounds
    Maria J Climent
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Avenida de los Naranjos s n, 46022 Valencia, Spain
    Chemistry 15:8834-41. 2009
    ....
  68. ncbi request reprint Zeolite synthesis modelling with support vector machines: a combinatorial approach
    Jose Manuel Serra
    Instituto de Tecnología Química UPV CSIC, Av De Los Naranjos s n, E 46022 Valencia, Spain
    Comb Chem High Throughput Screen 10:13-24. 2007
    ..They may overcome overfitting problems observed sometimes for neural networks. It is also studied the influence of the type of material descriptors used as model output...
  69. doi request reprint Propene epoxidation with O2 or H2-O2 mixtures over silver catalysts: theoretical insights into the role of the particle size
    M Boronat
    Instituto de Tecnologia Quimica, Universidad Politecnica de Valencia Consejo Superior de Investigaciones Cientificas, Av De Los Naranjos s n, E 46022 Valencia, Spain
    Phys Chem Chem Phys 16:26600-12. 2014
    ..Theoretical findings have been experimentally confirmed by Raman spectroscopy of O2 adsorption and catalytic testing of planar and three dimensional silver clusters. ..
  70. ncbi request reprint Support vector machines for predictive modeling in heterogeneous catalysis: a comprehensive introduction and overfitting investigation based on two real applications
    L A Baumes
    Instituto de Tecnología Química UPV CSIC, Av Naranjos s n, 46022 Valencia, Spain
    J Comb Chem 8:583-96. 2006
    ..Finally, we discuss why SVMs is a strategic method, as compared to other machine learning techniques, such as neural networks or induction trees, and why emphasis is put on the problem of overfitting...
  71. doi request reprint Preparation of symmetric and asymmetric aromatic azo compounds from aromatic amines or nitro compounds using supported gold catalysts
    Abdessamad Grirrane
    Instituto Universitario de Tecnología Química CSIC UPV, Universidad Politecnica de Valencia, Valencia, Spain
    Nat Protoc 5:429-38. 2010
    ..In addition, the catalytic process is efficient for the synthesis of symmetric and a range of asymmetric aromatic azo compounds from the mixtures of two anilines substituted with electron-donor and electron-acceptor substituents...
  72. ncbi request reprint Monomers that form conducting polymers as structure-directing agents: synthesis of microporous molecular sieves encapsulating poly-para-phenylenevinylene
    Pedro Atienzar
    Instituto de Tecnologia Quimica CSIC UPV, Universidad Politecnica de Valencia, Avda de los Naranjos s n 46022 Valencia, Spain
    Chemistry 13:8733-8. 2007
    ..The organic self-assembled organic-inorganic material was extensively characterized and the implication on electrical conductivity is presented...
  73. doi request reprint Complexation and fluorescence of tricyclic basic dyes encapsulated in cucurbiturils
    Pedro Montes-Navajas
    Instituto de Tecnologia Quimica, Universidad Politecnica de Valencia, Av De Los Naranjos s n, 46022, Valencia, Spain
    Chemphyschem 9:713-20. 2008
    ....
  74. doi request reprint One pot catalytic conversion of cellulose into biodegradable surfactants
    Nicolas Villandier
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones Cientificas, Avenida de los Naranjos s n 46022, Valencia, Spain
    Chem Commun (Camb) 46:4408-10. 2010
    ....
  75. doi request reprint Monodispersed mesoporous silica nanoparticles with very large pores for enhanced adsorption and release of DNA
    Fei Gao
    Instituto de Tecnologia Quimica, UPV CSIC, Avenida Los Naranjos s n, 46022 Valencia, Spain
    J Phys Chem B 113:1796-804. 2009
    ..07 microg DNA m(-2), which is the highest content achieved with silica-based materials. Furthermore, plasmid DNA becomes protected from enzymatic degradation when conjugated with the mesostructured nanoparticles...
  76. ncbi request reprint Electrochemiluminescent cells based on zeolite-encapsulated host-guest systems: encapsulated ruthenium tris-bipyridyl
    Mercedes Alvaro
    Instituto de Tecnologia Quimica CSIC UPV, Universidad Politecnica de Valencia, Av De Los Naranjos s n, 46022, Valencia, Spain
    Chemistry 13:3733-8. 2007
    ..Ion exchange of sodium by cesium and vapor deposition of calcium metal inside the zeolite pores enhance the electrochemiluminescent efficiency of the cell by a factor of 4...
  77. ncbi request reprint Carbonylation of methanol on metal-acid zeolites: evidence for a mechanism involving a multisite active center
    Teresa Blasco
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    Angew Chem Int Ed Engl 46:3938-41. 2007
  78. doi request reprint Hybrid organic-inorganic catalytic mesoporous materials with proton sponges as building blocks
    Enrica Gianotti
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Consejo Superior de Investigaciones Cientificas, Avenida de los Naranjos s n, 46022 Valencia, Spain
    Phys Chem Chem Phys 13:11702-9. 2011
    ..These hybrids show high activity as base catalysts and can be recycled...
  79. ncbi request reprint Delineating similarities and dissimilarities in the use of metal organic frameworks and zeolites as heterogeneous catalysts for organic reactions
    Amarajothi Dhakshinamoorthy
    Instituto Universitario de Tecnología Química CSIC UPV Av De los Naranjos s n, 46022, Valencia, Spain
    Dalton Trans 40:6344-60. 2011
    ..Particular attention is paid to provide critical comments on how MOFs could be adapted by design or can be modified by post-synthetic treatments to give well performing catalysts...
  80. doi request reprint Synergy between the metal nanoparticles and the support for the hydrogenation of functionalized carboxylic acids to diols on Ru/TiO2
    Ana Primo
    Instituto de Tecnologia Quimica, Universidad Politecnica de Valencia CSIC, Camino de Vera, 46022 Valencia, Spain
    Chem Commun (Camb) 47:3613-5. 2011
    ..This superior catalytic activity can be due to a combined action of small ruthenium nanoparticles and the titania support...
  81. ncbi request reprint Chemical routes for the transformation of biomass into chemicals
    Avelino Corma
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Avenida de los Naranjos, S N, Valencia, Spain
    Chem Rev 107:2411-502. 2007
  82. ncbi request reprint Rational design and HT techniques allow the synthesis of new IWR zeolite polymorphs
    Angel Cantín
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Spain
    J Am Chem Soc 128:4216-7. 2006
    ..This work opens the possibility to synthesize the Ge-free polymorphs of a large number of new germanosilicate structures reported in the last five years. This certainly will increase their possibilities for industrial application...
  83. doi request reprint Mono- and multisite solid catalysts in cascade reactions for chemical process intensification
    Maria J Climent
    Instituto de Tecnologia Quimica, UPV CSIC, Universidad Politecnica de Valencia, Spain
    ChemSusChem 2:500-6. 2009
    ..It is shown that single- and multisite solid catalysts can be designed to carry out cascade reactions for the synthesis of fine chemicals...
  84. ncbi request reprint Synthesis and structure of the bidimensional zeolite ITQ-32 with small and large pores
    Angel Cantín
    Instituto de Tecnología Química UPV CSIC, Universidad Politecnica de Valencia, Avda de los naranjos s n, 46022 Valencia, Spain
    J Am Chem Soc 127:11560-1. 2005
    ..This zeolite presents a relatively large pore volume (0.16 cm3/g) and pore apertures of 3.5 x 4.3 A and can be prepared as a nearly pure silica zeolite and as aluminosilicate. In the latest case, acidic properties are developed...
  85. ncbi request reprint Synergies between bio- and oil refineries for the production of fuels from biomass
    George W Huber
    Chemical Engineering Department, University of Massachusetts Amherst, Amherst, MA 01003, USA
    Angew Chem Int Ed Engl 46:7184-201. 2007
    ..This Review discusses the chemistry, catalysts, and challenges involved in the production of biofuels...
  86. ncbi request reprint Uniform catalytic site in Sn-beta-zeolite determined using X-ray absorption fine structure
    Simon R Bare
    UOP LLC, Des Plaines, Illinois 60016, EXAFS Analysis, Bolingbrook, Illinois 60440, USA
    J Am Chem Soc 127:12924-32. 2005
    ..This uniform site distribution of the Sn suggests that there is likely a symbiotic relationship between the structure-directing agent in the zeolite synthesis and the Sn heteroatoms during the framework formation...
  87. ncbi request reprint A general method for the synthesis of nanostructured large-surface-area materials through the self-assembly of functionalized nanoparticles
    Jean Yves Chane-Ching
    Rhodia Recherches, 52 rue de la Haie Coq, 93308 Aubervilliers, France
    Chemistry 11:979-87. 2005
    ..Examples of such materials include CeO2, ZrO2, and CeO2-Al(OH)3 composites...