Stergios Piligkos

Summary

Affiliation: University of Copenhagen
Country: Denmark

Publications

  1. doi request reprint A ligand-field study of the ground spin-state magnetic anisotropy in a family of hexanuclear Mn(III) single-molecule magnets
    Stergios Piligkos
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100, Denmark
    Dalton Trans . 2008
  2. doi request reprint Magnetic and magnetocaloric properties of an unusual family of carbonate-panelled [Ln(III)(6)Zn(III)(2)] cages
    Waqas Sethi
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100, Denmark
    Dalton Trans 44:10315-20. 2015
  3. ncbi request reprint Importance of the anisotropic exchange interaction for the magnetic anisotropy of polymetallic systems
    Stergios Piligkos
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100, Denmark Max Plank Institut für Bioanorganische Chemie, Stiftstrasse 34 36, 45470 Mulheim, Germany
    J Am Chem Soc 129:760-1. 2007
  4. doi request reprint EPR spectroscopy of a family of Cr(III) 7M(II) (M = Cd, Zn, Mn, Ni) "wheels": studies of isostructural compounds with different spin ground states
    Stergios Piligkos
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen, Denmark
    Chemistry 15:3152-67. 2009
  5. doi request reprint Fluoride bridges as structure-directing motifs in 3d-4f cluster chemistry
    Torben Birk
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100 Copenhagen, Denmark
    Inorg Chem 51:5435-43. 2012
  6. ncbi request reprint Fluoride-bridged {Gd(III)3M(III)2} (M = Cr, Fe, Ga) molecular magnetic refrigerants
    Kasper S Pedersen
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen Denmark
    Angew Chem Int Ed Engl 53:2394-7. 2014
  7. doi request reprint Fluoride-bridged {Ln2Cr2} polynuclear complexes from semi-labile mer-[CrF3(py)3] and [Ln(hfac)3(H2O)2]
    Christian Aa Thuesen
    Department of Chemistry, University of Copenhagen, Universitets parken 5, DK 2100 Copenhagen, Denmark
    Dalton Trans 41:11284-92. 2012
  8. doi request reprint [ReF(6)](2-) : a robust module for the design of molecule-based magnetic materials
    Kasper S Pedersen
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen Denmark CNRS, CRPP, UPR 8641, 33600 Pessac France Univ Bordeaux, CRPP, UPR 8641, 33600 Pessac France
    Angew Chem Int Ed Engl 53:1351-4. 2014
  9. ncbi request reprint In-Depth Magnetic Characterization of a [2 × 2] Mn(III) Square Grid Using SQUID Magnetometry, Inelastic Neutron Scattering, and High-Field Electron Paramagnetic Resonance Spectroscopy
    Andreas Konstantatos
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100 Copenhagen, Denmark
    Inorg Chem 55:10377-10382. 2016
  10. doi request reprint A linear single-molecule magnet based on [Ru(III)(CN)6]3-
    Kasper S Pedersen
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100, Copenhagen, Denmark
    Chem Commun (Camb) 47:6918-20. 2011

Collaborators

  • Frank Neese
  • Robert Bittl
  • Magnus Schau-Magnussen
  • Kasper S Pedersen
  • Jesper Bendix
  • Høgni Weihe
  • Christian Aa Thuesen
  • Marco Evangelisti
  • Magnus Schau-Magnussen
  • Torben Birk
  • Thomas Weyhermüller
  • Andreas Konstantatos
  • Waqas Sethi
  • Anne Laure Barra
  • Giulia Lorusso
  • Mikkel A Sørensen
  • Högni Weihe
  • Christian Aagaard Thuesen
  • Po Chi Lin
  • Robert Bewley
  • Sergio Sanz
  • Euan K Brechin
  • Gary S Nichol
  • Saurabh Kumar Singh
  • Gopalan Rajaraman
  • Dennis Larsen
  • Marc Sigrist
  • Rodolphe Clérac
  • Hannu Mutka
  • Morten G Vinum
  • Juan José Morales
  • Susanne Mossin
  • Johan Vibenholt
  • Maren Gysler
  • Philip Tregenna-Piggott
  • Jan Dreiser
  • Oliver Waldmann
  • Joscha Nehrkorn
  • Karsten Holldack
  • Alexander Schnegg
  • Ole Mønsted
  • Karin Türk
  • Andrea Puhar
  • Julia Steuber
  • Eckhard Bill

Detail Information

Publications13

  1. doi request reprint A ligand-field study of the ground spin-state magnetic anisotropy in a family of hexanuclear Mn(III) single-molecule magnets
    Stergios Piligkos
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100, Denmark
    Dalton Trans . 2008
    ....
  2. doi request reprint Magnetic and magnetocaloric properties of an unusual family of carbonate-panelled [Ln(III)(6)Zn(III)(2)] cages
    Waqas Sethi
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100, Denmark
    Dalton Trans 44:10315-20. 2015
    ..6 J kg(-1) K(-1) at T = 1.7 K, close to the maximum entropy value per mole expected from six Gd(III) spins (SGd = 7/2), 23.7 J kg(-1) K(-1). ..
  3. ncbi request reprint Importance of the anisotropic exchange interaction for the magnetic anisotropy of polymetallic systems
    Stergios Piligkos
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100, Denmark Max Plank Institut für Bioanorganische Chemie, Stiftstrasse 34 36, 45470 Mulheim, Germany
    J Am Chem Soc 129:760-1. 2007
  4. doi request reprint EPR spectroscopy of a family of Cr(III) 7M(II) (M = Cd, Zn, Mn, Ni) "wheels": studies of isostructural compounds with different spin ground states
    Stergios Piligkos
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen, Denmark
    Chemistry 15:3152-67. 2009
    ....
  5. doi request reprint Fluoride bridges as structure-directing motifs in 3d-4f cluster chemistry
    Torben Birk
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100 Copenhagen, Denmark
    Inorg Chem 51:5435-43. 2012
    ..06(0) cm(-1). The large spin and small anisotropy together with weak exchange interactions in the {Gd(3)Cr(2)} (11) cluster give rise to a very large magneto-caloric effect of -ΔS(m) = 28.7 J kg(-1) K(-1) (μ(0)H = 90 to 0 kOe)...
  6. ncbi request reprint Fluoride-bridged {Gd(III)3M(III)2} (M = Cr, Fe, Ga) molecular magnetic refrigerants
    Kasper S Pedersen
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen Denmark
    Angew Chem Int Ed Engl 53:2394-7. 2014
    ..This observation underlines the necessity of controlling not only the ground state but also close-lying excited states for successful design of molecular refrigerants...
  7. doi request reprint Fluoride-bridged {Ln2Cr2} polynuclear complexes from semi-labile mer-[CrF3(py)3] and [Ln(hfac)3(H2O)2]
    Christian Aa Thuesen
    Department of Chemistry, University of Copenhagen, Universitets parken 5, DK 2100 Copenhagen, Denmark
    Dalton Trans 41:11284-92. 2012
    ..4 J kg(-1) K(-1) for ΔB(0) = 9 T → 0 T at T = 4.1 K. Out-of-phase alternating-current susceptibility (χ'') signals are observed for 1Dy, 2Dy and 2Tb, demonstrating slow relaxation of the magnetization...
  8. doi request reprint [ReF(6)](2-) : a robust module for the design of molecule-based magnetic materials
    Kasper S Pedersen
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen Denmark CNRS, CRPP, UPR 8641, 33600 Pessac France Univ Bordeaux, CRPP, UPR 8641, 33600 Pessac France
    Angew Chem Int Ed Engl 53:1351-4. 2014
    ..8 cm(-1) ) dwarfs the coupling present in related cyanide-bridged systems. These results reveal [ReF6 ](2-) to be an unique new module for the design of molecule-based magnetic materials. ..
  9. ncbi request reprint In-Depth Magnetic Characterization of a [2 × 2] Mn(III) Square Grid Using SQUID Magnetometry, Inelastic Neutron Scattering, and High-Field Electron Paramagnetic Resonance Spectroscopy
    Andreas Konstantatos
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100 Copenhagen, Denmark
    Inorg Chem 55:10377-10382. 2016
    ..The resulting model takes into account both the magnitude and the relative orientations of the single-ion anisotropy tensors...
  10. doi request reprint A linear single-molecule magnet based on [Ru(III)(CN)6]3-
    Kasper S Pedersen
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100, Copenhagen, Denmark
    Chem Commun (Camb) 47:6918-20. 2011
    ..Frequency-domain Fourier-transform THz-EPR (FDFT THz-EPR) and magnetic susceptibility measurements indicate strongly anisotropic Mn-Ru exchange interactions...
  11. ncbi request reprint Magnetic properties of a manganese(III) Chain with monoatomic bridges: catena-MnF(salen)
    Torben Birk
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100 Copenhagen, Denmark
    Inorg Chem 50:5312-4. 2011
    ..In solution, electron paramagnetic resonance shows the chains to be symmetrically cleaved to monomeric MnF(salen)...
  12. ncbi request reprint Computationally inexpensive interpretation of magnetic data for finite spin clusters
    Christian Aagaard Thuesen
    Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100, Copenhagen, Denmark
    Dalton Trans 39:4882-5. 2010
    ..Excellent agreement with experiments as well as with results from computationally more elaborate methods is achieved...
  13. ncbi request reprint A vertebrate-type ferredoxin domain in the Na+-translocating NADH dehydrogenase from Vibrio cholerae
    Po Chi Lin
    Mikrobiologisches Institut der Eidgenössischen Technischen Hochschule, ETH Honggerberg, Zurich, Switzerland
    J Biol Chem 280:22560-3. 2005
    ..This study reveals a novel function for vertebrate-type [2Fe-2S] clusters as redox cofactors in respiratory dehydrogenases...