Jeffrey R Long

Summary

Affiliation: University of California
Country: USA

Publications

  1. ncbi request reprint Hydrogen storage in metal-organic frameworks
    Leslie J Murray
    Department of Chemistry, University of California, Berkeley, CA, 94720 1460, USA
    Chem Soc Rev 38:1294-314. 2009
  2. ncbi request reprint Hydrogen storage properties and neutron scattering studies of Mg(2)(dobdc)-a metal-organic framework with open Mg(2+) adsorption sites
    Kenji Sumida
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    Chem Commun (Camb) 47:1157-9. 2011
  3. ncbi request reprint Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions
    V Sara Thoi
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    Chem Soc Rev 42:2388-400. 2013
  4. ncbi request reprint Oxidation of ethane to ethanol by N2O in a metal-organic framework with coordinatively unsaturated iron(II) sites
    Dianne J Xiao
    Department of Chemistry, University of California, Berkeley, California 94720 1460, USA
    Nat Chem 6:590-5. 2014
  5. doi request reprint The mechanism of carbon dioxide adsorption in an alkylamine-functionalized metal-organic framework
    Nora Planas
    Department of Chemistry, Supercomputing Institute, and Chemical Theory Center, University of Minnesota, Minneapolis, Minnesota 55455, USA
    J Am Chem Soc 135:7402-5. 2013
  6. doi request reprint Impact of metal and anion substitutions on the hydrogen storage properties of M-BTT metal-organic frameworks
    Kenji Sumida
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    J Am Chem Soc 135:1083-91. 2013
  7. ncbi request reprint Electrodeposited cobalt-sulfide catalyst for electrochemical and photoelectrochemical hydrogen generation from water
    Yujie Sun
    Departments of Chemistry and Molecular and Cell Biology and the Howard Hughes Medical Institute, University of California, Berkeley, California 94720, United States
    J Am Chem Soc 135:17699-702. 2013
  8. doi request reprint Computational and experimental study of the mechanism of hydrogen generation from water by a molecular molybdenum-oxo electrocatalyst
    Eric J Sundstrom
    Department of Chemistry, University of California, Berkeley, California 94720, United States
    J Am Chem Soc 134:5233-42. 2012
  9. doi request reprint Mössbauer spectroscopy as a probe of magnetization dynamics in the linear iron(I) and iron(II) complexes [Fe(C(SiMe3)3)2](1-/0.)
    Joseph M Zadrozny
    Department of Chemistry, University of California, Berkeley, California 94720 1460, United States
    Inorg Chem 52:13123-31. 2013
  10. doi request reprint Slow magnetic relaxation in a pseudotetrahedral cobalt(II) complex with easy-plane anisotropy
    Joseph M Zadrozny
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    Chem Commun (Camb) 48:3927-9. 2012

Collaborators

  • Craig M Brown
  • Berend Smit
  • William J Evans
  • Junko Yano
  • Martin Head-Gordon
  • Frank Neese
  • Mihail Atanasov
  • Chong Liu
  • Wayne W Lukens
  • Jihan Kim
  • Christopher J Cramer
  • Xinzheng Yang
  • Sergey N Maximoff
  • Katie R Meihaus
  • Joseph M Zadrozny
  • Eric D Bloch
  • Jeffrey D Rinehart
  • Yujie Sun
  • Christopher J Chang
  • Leslie J Murray
  • Kenji Sumida
  • Zoey R Herm
  • Silvia Bordiga
  • Dianne J Xiao
  • Li Chiang Lin
  • Thomas M McDonald
  • Xiaowen Feng
  • Ming Fang
  • Rajamani Krishna
  • Sachin Chavan
  • Kyuho Lee
  • Allison L Dzubak
  • Laura Gagliardi
  • Matthew R Hudson
  • Jeffrey B Neaton
  • Nora Planas
  • V Sara Thoi
  • Gary J Long
  • Wendy L Queen
  • Fernande Grandjean
  • Hemamala I Karunadasa
  • Pragya Verma
  • Jeffrey F Van Humbeck
  • Donald G Truhlar
  • Jarad A Mason
  • Brian M Wiers
  • Joseph J Chen
  • Roberta Poloni
  • Xueqian Kong
  • Joseph W Ziller
  • Jeffrey A Reimer
  • Walter S Drisdell
  • Eric J Sundstrom
  • Stephen Hill
  • Nathan A Siladke
  • Selvan Demir
  • Junjie Liu
  • Nicholas A Piro
  • Mircea Dinca
  • Julian P Bigi
  • Pierre Dechambenoit
  • Bettina Bechlars
  • Joshua D Howe
  • Guangshan Zhu
  • Valentina Crocellà
  • Xiaofei Jing
  • David K Shuh
  • Tolek Tyliszczak
  • Jordan F Corbey
  • Douglas A Reed
  • Stefan G Minasian
  • Samuel J Stoneburner
  • Stosh A Kozimor
  • Francesca Bonino
  • Joshua Borycz
  • William C Isley
  • David C Grauer
  • Ie Rang Jeon
  • Lorenzo Mino
  • Corine Mathoniere
  • Olena Zavorotynska
  • Peidong Yang
  • Jeng Da Chai
  • Mathieu Rouzières
  • Norberto Masciocchi
  • Miguel I Gonzalez
  • Michael L Aubrey
  • Mary Anne Manumpil
  • Alison McManus
  • Rodolphe Clérac

Detail Information

Publications36

  1. ncbi request reprint Hydrogen storage in metal-organic frameworks
    Leslie J Murray
    Department of Chemistry, University of California, Berkeley, CA, 94720 1460, USA
    Chem Soc Rev 38:1294-314. 2009
    ....
  2. ncbi request reprint Hydrogen storage properties and neutron scattering studies of Mg(2)(dobdc)-a metal-organic framework with open Mg(2+) adsorption sites
    Kenji Sumida
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    Chem Commun (Camb) 47:1157-9. 2011
    ....
  3. ncbi request reprint Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions
    V Sara Thoi
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    Chem Soc Rev 42:2388-400. 2013
    ..The use of water as a reaction medium has dual benefits of maintaining high substrate concentration as well as minimizing the environmental impact from organic additives and by-products...
  4. ncbi request reprint Oxidation of ethane to ethanol by N2O in a metal-organic framework with coordinatively unsaturated iron(II) sites
    Dianne J Xiao
    Department of Chemistry, University of California, Berkeley, California 94720 1460, USA
    Nat Chem 6:590-5. 2014
    ..Electronic structure calculations indicate that the active oxidant is likely to be a high-spin S = 2 iron(IV)-oxo species. ..
  5. doi request reprint The mechanism of carbon dioxide adsorption in an alkylamine-functionalized metal-organic framework
    Nora Planas
    Department of Chemistry, Supercomputing Institute, and Chemical Theory Center, University of Minnesota, Minneapolis, Minnesota 55455, USA
    J Am Chem Soc 135:7402-5. 2013
    ..We explain this behavior in the form of a hydrogen-bonded complex involving two carbamic acid moieties resulting from the adsorption of CO2 onto the secondary amines...
  6. doi request reprint Impact of metal and anion substitutions on the hydrogen storage properties of M-BTT metal-organic frameworks
    Kenji Sumida
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    J Am Chem Soc 135:1083-91. 2013
    ....
  7. ncbi request reprint Electrodeposited cobalt-sulfide catalyst for electrochemical and photoelectrochemical hydrogen generation from water
    Yujie Sun
    Departments of Chemistry and Molecular and Cell Biology and the Howard Hughes Medical Institute, University of California, Berkeley, California 94720, United States
    J Am Chem Soc 135:17699-702. 2013
    ..The facile preparation of this Co-S film, along with its low overpotential, high activity, and long-term aqueous stability, offer promising features for potential use in solar energy applications. ..
  8. doi request reprint Computational and experimental study of the mechanism of hydrogen generation from water by a molecular molybdenum-oxo electrocatalyst
    Eric J Sundstrom
    Department of Chemistry, University of California, Berkeley, California 94720, United States
    J Am Chem Soc 134:5233-42. 2012
    ....
  9. doi request reprint Mössbauer spectroscopy as a probe of magnetization dynamics in the linear iron(I) and iron(II) complexes [Fe(C(SiMe3)3)2](1-/0.)
    Joseph M Zadrozny
    Department of Chemistry, University of California, Berkeley, California 94720 1460, United States
    Inorg Chem 52:13123-31. 2013
    ..The ab initio calculated Mössbauer hyperfine parameters of both 1 and 2 are in excellent agreement with the observed hyperfine parameters...
  10. doi request reprint Slow magnetic relaxation in a pseudotetrahedral cobalt(II) complex with easy-plane anisotropy
    Joseph M Zadrozny
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    Chem Commun (Camb) 48:3927-9. 2012
    ..A pseudotetrahedral cobalt(II) complex with a positive axial zero-field splitting parameter of D = 12.7 cm(-1), as determined by high-field EPR spectroscopy, is shown to exhibit slow magnetic relaxation under an applied dc field...
  11. doi request reprint Magnetic blocking in a linear iron(I) complex
    Joseph M Zadrozny
    Department of Chemistry, University of California, Berkeley, California 94720 1460, USA
    Nat Chem 5:577-81. 2013
    ..This S =  complex exhibits an effective spin-reversal barrier of Ueff = 226(4) cm(-1), the largest yet observed for a single-molecule magnet based on a transition metal, and displays magnetic blocking below 4.5 K. ..
  12. ncbi request reprint Hydrocarbon separations in a metal-organic framework with open iron(II) coordination sites
    Eric D Bloch
    Department of Chemistry, University of California, Berkeley, CA 94720, USA
    Science 335:1606-10. 2012
    ....
  13. ncbi request reprint Microporous magnets
    Pierre Dechambenoit
    Department of Chemistry, University of California, Berkeley, CA 94720 1460, USA
    Chem Soc Rev 40:3249-65. 2011
    ..In this critical review, we give an overview of this emerging class of multifunctional materials, with particular emphasis on synthetic strategies and possible routes to new materials with improved properties (149 references)...
  14. doi request reprint Influence of an inner-sphere K+ ion on the magnetic behavior of N2(3-) radical-bridged dilanthanide complexes isolated using an external magnetic field
    Katie R Meihaus
    Department of Chemistry, University of California, Berkeley, California 94720 1460, United States
    Inorg Chem 53:3099-107. 2014
    ..These differences are also likely to be a result of the competing antiferromagnetic Ln(III)-Ln(III) exchange interactions of the type quantified in 1-Gd. ..
  15. doi request reprint Probing adsorption interactions in metal-organic frameworks using X-ray spectroscopy
    Walter S Drisdell
    Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
    J Am Chem Soc 135:18183-90. 2013
    ..Qualitative agreement between ambient-temperature experimental and 0 K theoretical spectra is good, with minor discrepancies thought to result from framework vibrational motion. ..
  16. doi request reprint Exchange coupling and magnetic blocking in bipyrimidyl radical-bridged dilanthanide complexes
    Selvan Demir
    Department of Chemistry, University of California, Berkeley, 94720, United States
    J Am Chem Soc 134:18546-9. 2012
    ..Significantly, the latter complex exhibits a divergence of the field-cooled and zero-field-cooled dc susceptibility data at 6.5 K and magnetic hysteresis below this temperature...
  17. ncbi request reprint Ex Situ NMR relaxometry of metal-organic frameworks for rapid surface-area screening
    Joseph J Chen
    Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA, 94703 USA
    Angew Chem Int Ed Engl 52:12043-6. 2013
    ..This NMR technique is amenable to automation and can expedite the characterization of microporous materials by identifying any nonporous or low-surface-area structures. ..
  18. ncbi request reprint Design of a metal-organic framework with enhanced back bonding for separation of N₂ and CH₄
    Kyuho Lee
    Department of Chemical and Biomolecular Engineering, University of California, Berkeley, California 94720 1462, United States
    J Am Chem Soc 136:698-704. 2014
    ....
  19. ncbi request reprint Selective binding of O2 over N2 in a redox-active metal-organic framework with open iron(II) coordination sites
    Eric D Bloch
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    J Am Chem Soc 133:14814-22. 2011
    ..Application of ideal adsorbed solution theory in simulating breakthrough curves shows Fe(2)(dobdc) to be a promising material for the separation of O(2) from air at temperatures well above those currently employed in industrial settings...
  20. ncbi request reprint Highly-selective and reversible O2 binding in Cr3(1,3,5-benzenetricarboxylate)2
    Leslie J Murray
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    J Am Chem Soc 132:7856-7. 2010
    ..Neutron powder diffraction data confirm this mechanism of O(2) binding and indicate a lengthening of the Cr-Cr distance within the paddle-wheel units of the framework from 2.06(2) to 2.8(1) A...
  21. doi request reprint Separation of hexane isomers in a metal-organic framework with triangular channels
    Zoey R Herm
    Department of Chemistry, University of California Berkeley, CA 94720, USA
    Science 340:960-4. 2013
    ..Configurational-bias Monte Carlo simulations confirm the origins of the molecular separation...
  22. ncbi request reprint A N2(3-) radical-bridged terbium complex exhibiting magnetic hysteresis at 14 K
    Jeffrey D Rinehart
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    J Am Chem Soc 133:14236-9. 2011
    ....
  23. ncbi request reprint Synthesis, structure, and magnetism of an f element nitrosyl complex, (C5Me4H)3UNO
    Nathan A Siladke
    Department of Chemistry, University of California, Irvine, California 92627 2025, USA
    J Am Chem Soc 134:1243-9. 2012
    ..The complex displays temperature-independent paramagnetism with a magnetic moment of 1.36 μ(B) at room temperature. Complex 2 reacts with Al(2)Me(6) to form the adduct (C(5)Me(4)H)(3)UNO(AlMe(3)), 3...
  24. doi request reprint Ammonia capture in porous organic polymers densely functionalized with Brønsted acid groups
    Jeffrey F Van Humbeck
    Department of Chemistry, University of California, Berkeley, California 94720, United States
    J Am Chem Soc 136:2432-40. 2014
    ..15 mmol/g at 480 ppm). Overall, the data strongly suggest that the spatial arrangement of acidic sites allows for cooperative behavior, which leads to enhanced NH3 adsorption. ..
  25. ncbi request reprint Slow magnetic relaxation induced by a large transverse zero-field splitting in a Mn(II)Re(IV)(CN)2 single-chain magnet
    Xiaowen Feng
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    J Am Chem Soc 134:7521-9. 2012
    ....
  26. doi request reprint Molecular cobalt pentapyridine catalysts for generating hydrogen from water
    Yujie Sun
    Department of Chemistry, University of California, Berkeley, California 94720, USA
    J Am Chem Soc 133:9212-5. 2011
    ....
  27. doi request reprint Strong exchange and magnetic blocking in N₂³⁻-radical-bridged lanthanide complexes
    Jeffrey D Rinehart
    Department of Chemistry, University of California, Berkeley, California 94720 1460, USA
    Nat Chem 3:538-42. 2011
    ..3 K at a sweep rate of 0.08 T s(-1)...
  28. ncbi request reprint A molecular MoS₂ edge site mimic for catalytic hydrogen generation
    Hemamala I Karunadasa
    Department of Chemistry, University of California, Berkeley, CA 94720, USA
    Science 335:698-702. 2012
    ....
  29. ncbi request reprint Influence of pyrazolate vs N-heterocyclic carbene ligands on the slow magnetic relaxation of homoleptic trischelate lanthanide(III) and uranium(III) complexes
    Katie R Meihaus
    Department of Chemistry, University of California, Berkeley, California 94720, United States
    J Am Chem Soc 136:6056-68. 2014
    ..These results show that, like molecular symmetry, ligand-donating ability is a variable that can be controlled to the advantage of the synthetic chemist in the design of single-molecule magnets with enhanced relaxation barriers. ..
  30. doi request reprint Magnetic blocking at 10 K and a dipolar-mediated avalanche in salts of the bis(η8-cyclooctatetraenide) complex [Er(COT)2]-
    Katie R Meihaus
    Department of Chemistry, University of California, Berkeley, California 94720, United States
    J Am Chem Soc 135:17952-7. 2013
    ..Collectively, these results highlight the utility of an equatorial ligand field for facilitating slow magnetic relaxation in the prolate Er(III) ion. ..
  31. doi request reprint Tristability in a light-actuated single-molecule magnet
    Xiaowen Feng
    Department of Chemistry, University of California, Berkeley, California 94720, United States
    J Am Chem Soc 135:15880-4. 2013
    ....
  32. doi request reprint High-spin ground states via electron delocalization in mixed-valence imidazolate-bridged divanadium complexes
    Bettina Bechlars
    Department of Chemistry, University of California, Berkeley, CA 94720 1460, USA
    Nat Chem 2:362-8. 2010
    ..Combined modelling of the magnetic data and spectral analysis leads to an estimate of the double-exchange parameter of B = 220 cm(-1) when vibronic coupling is taken into account...
  33. doi request reprint Slow magnetic relaxation in homoleptic trispyrazolylborate complexes of neodymium(iii) and uranium(iii)
    Jeffrey D Rinehart
    Department of Chemistry, University of Washington, WA 98195, USA
    Dalton Trans 41:13572-4. 2012
    ..Magnetic dilution studies performed with NdTp(3) reveal that, while intermolecular interactions partially account for the faster relaxation dynamics, they are not uniquely responsible...
  34. ncbi request reprint Dilution-induced slow magnetic relaxation and anomalous hysteresis in trigonal prismatic dysprosium(III) and uranium(III) complexes
    Katie R Meihaus
    Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, USA
    Inorg Chem 50:8484-9. 2011
    ....
  35. ncbi request reprint Metal-organic frameworks as adsorbents for hydrogen purification and precombustion carbon dioxide capture
    Zoey R Herm
    Department of Chemistry, University of California, Berkeley, California 94720 1460, United States
    J Am Chem Soc 133:5664-7. 2011
    ....
  36. doi request reprint Understanding CO2 Dynamics in Metal-Organic Frameworks with Open Metal Sites
    Li Chiang Lin
    Department of Chemical and Biomolecular Engineering, University of California, Berkeley, Berkeley, CA 94720 USA
    Angew Chem Int Ed Engl 52:4410-3. 2013
    ..Molecular simulations reveal detailed CO2 dynamics (hops between metal sites and localized fluctuations), which can be used to accurately explain the experimentally measured (13) C NMR chemical shift anisotropy pattern...