- Metal-catalyzed double migratory cascade reactions of propargylic esters and phosphatesRoohollah Kazem Shiroodi
Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607 7061, USA
Chem Soc Rev 42:4991-5001. 2013..The serendipitous observations, as well as designed approaches involving the double migratory cascade reactions, will be discussed with emphasis placed on the mechanistic aspects and the synthetic utilities of the obtained products...
- Pd-catalyzed cascade carbopalladation-annulation reaction of 3-(2-iodobenzyl)-indoles into fused 6/5/7/6- and 6/5/5/6- heterocyclic systemsNatalia Chernyak
Department of Chemistry, University of Illinois, 845 West Taylor Street, Chicago, IL 60607, USA
Chem Commun (Camb) 46:150-2. 2010..A remarkable base effect on the chemoselectivity of this transformation has been found: switching from Et(3)N to CsOAc completely reverses the reaction path to intramolecular cyclization forming fused five-membered rings...