Patrick Frank

Summary

Affiliation: Stanford University
Country: USA

Publications

  1. ncbi The solution structure of [Cu(aq)]2+ and its implications for rack-induced bonding in blue copper protein active sites
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 44:1922-33. 2005
  2. doi Solution [Cu(amm)]2+ is a strongly solvated square pyramid: a full account of the copper K-edge XAS spectrum within single-electron theory
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 47:4126-39. 2008
  3. ncbi A systematic resolution of sulfur in reticulated vitreous carbon using X-ray absorption spectroscopy
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, USA
    Inorg Chem 45:9864-76. 2006
  4. pmc The uptake and fate of vanadyl ion in ascidian blood cells and a detailed hypothesis for the mechanism and location of biological vanadium reduction. A visible and X-ray absorption spectroscopic study
    Patrick Frank
    Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94025, USA
    J Inorg Biochem 102:809-23. 2008
  5. ncbi A new structural motif for biological iron: iron K-edge XAS reveals a [Fe4-mu-(OR)5(OR)(9-10)] cluster in the ascidian Perophora annectens
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 45:3920-31. 2006
  6. pmc The X-ray absorption spectroscopic model of the copper(II) imidazole complex ion in liquid aqueous solution: a strongly solvated square pyramid
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, United States
    Inorg Chem 51:2086-96. 2012
  7. ncbi The vanadium environment in blood cells of Ascidia ceratodes is divergent at all organismal levels: an XAS and EPR spectroscopic study
    Patrick Frank
    Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94309, USA
    J Inorg Biochem 94:59-71. 2003
  8. ncbi Cooperativity and intermediates in the equilibrium reactions of Fe(II,III) with ethanethiolate in N-methylformamide solution
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, CA 94305 5080, USA
    J Biol Inorg Chem 10:373-82. 2005
  9. ncbi Cooperative ligation, back-bonding, and possible pyridine-pyridine interactions in tetrapyridine-vanadium(II): a visible and X-ray spectroscopic study
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, USA
    Inorg Chem 41:3269-79. 2002
  10. pmc Ancient wood of the Acqualadrone rostrum: materials history through gas chromatography/mass spectrometry and sulfur X-ray absorption spectroscopy
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, United States
    Anal Chem 84:4419-28. 2012

Detail Information

Publications11

  1. ncbi The solution structure of [Cu(aq)]2+ and its implications for rack-induced bonding in blue copper protein active sites
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 44:1922-33. 2005
    ..Further, previously neglected protein folding thermodynamic consequences of the rack-bonding hypothesis indicate an experimental disconfirmation...
  2. doi Solution [Cu(amm)]2+ is a strongly solvated square pyramid: a full account of the copper K-edge XAS spectrum within single-electron theory
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 47:4126-39. 2008
    ..Cu(amm)](2+) continues the dissymmetry previously found for the solution structure of [Cu(H2O)5](2+), again contradicting the rack-bonding theory of blue copper proteins...
  3. ncbi A systematic resolution of sulfur in reticulated vitreous carbon using X-ray absorption spectroscopy
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, USA
    Inorg Chem 45:9864-76. 2006
    ..15% of the RVC surface, increasing to approximately 0.51% following permanganate/sulfuric acid treatment. The detection of episulfide directly corroborates a proposed mechanism for the migration of elemental sulfur through carbon...
  4. pmc The uptake and fate of vanadyl ion in ascidian blood cells and a detailed hypothesis for the mechanism and location of biological vanadium reduction. A visible and X-ray absorption spectroscopic study
    Patrick Frank
    Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94025, USA
    J Inorg Biochem 102:809-23. 2008
    ..Together these constitute the new field of vanadium redox enzymology...
  5. ncbi A new structural motif for biological iron: iron K-edge XAS reveals a [Fe4-mu-(OR)5(OR)(9-10)] cluster in the ascidian Perophora annectens
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, USA
    Inorg Chem 45:3920-31. 2006
    ..Either of these models represents an entirely new structural motif for biological iron. Vanadium domination of blood-cell metals cannot be a defining trait of Phlebobranch tunicates so long as P. annectens is included among them...
  6. pmc The X-ray absorption spectroscopic model of the copper(II) imidazole complex ion in liquid aqueous solution: a strongly solvated square pyramid
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305 5080, United States
    Inorg Chem 51:2086-96. 2012
    ....
  7. ncbi The vanadium environment in blood cells of Ascidia ceratodes is divergent at all organismal levels: an XAS and EPR spectroscopic study
    Patrick Frank
    Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94309, USA
    J Inorg Biochem 94:59-71. 2003
    ..Blood cell vanadium thus noticeably diverges at all organismal levels among A. ceratodes...
  8. ncbi Cooperativity and intermediates in the equilibrium reactions of Fe(II,III) with ethanethiolate in N-methylformamide solution
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, CA 94305 5080, USA
    J Biol Inorg Chem 10:373-82. 2005
    ..These results are related to the chemistry of nitrogenase FeMo cofactor in alkaline NMF solution...
  9. ncbi Cooperative ligation, back-bonding, and possible pyridine-pyridine interactions in tetrapyridine-vanadium(II): a visible and X-ray spectroscopic study
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, USA
    Inorg Chem 41:3269-79. 2002
    ..Cooperativity in the binding of pyridine by V(II) is then assigned by default to V(II)-pyridine back-bonding, which emerges only after the first pyridine is bound...
  10. pmc Ancient wood of the Acqualadrone rostrum: materials history through gas chromatography/mass spectrometry and sulfur X-ray absorption spectroscopy
    Patrick Frank
    Department of Chemistry, Stanford University, Stanford, California 94305, United States
    Anal Chem 84:4419-28. 2012
    ....
  11. ncbi High covalence in CuSO4 and the radicalization of sulfate: an X-ray absorption and density functional study
    Robert K Szilagyi
    Department of Chemistry and Biochemistry, Montana State University, Bozeman, Montana 59717, USA
    Inorg Chem 43:8318-29. 2004
    ....