Jeremy M Smith

Summary

Affiliation: New Mexico State University
Country: USA

Publications

  1. doi request reprint N-O bond homolysis of an iron(II) TEMPO complex yields an iron(III) oxo intermediate
    Jeremy M Smith
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces New Mexico 88003, USA
    J Am Chem Soc 134:6516-9. 2012
  2. ncbi request reprint The structure and reactivity of iron nitride complexes
    Jeremy M Smith
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, NM 88003, USA
    Dalton Trans 41:1423-9. 2012
  3. doi request reprint Thermodynamics of hydrogen atom transfer to a high-valent iron imido complex
    Ismael Nieto
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces New Mexico 88003, USA
    J Am Chem Soc 130:2716-7. 2008
  4. doi request reprint Synthesis, structure, and reactivity of an iron(V) nitride
    Jeremiah J Scepaniak
    Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Las Cruces, NM 88003, USA
    Science 331:1049-52. 2011
  5. doi request reprint Structural and spectroscopic characterization of an electrophilic iron nitrido complex
    Jeremiah J Scepaniak
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, USA
    J Am Chem Soc 130:10515-7. 2008
  6. pmc Tris(carbene)borate ligands featuring imidazole-2-ylidene, benzimidazol-2-ylidene, and 1,3,4-triazol-2-ylidene donors. Evaluation of donor properties in four-coordinate {NiNO}10 complexes
    Salvador B Muñoz
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, United States
    Inorg Chem 51:12660-8. 2012
  7. ncbi request reprint Spin crossover in a four-coordinate iron(II) complex
    Jeremiah J Scepaniak
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, United States
    J Am Chem Soc 133:3824-7. 2011
  8. doi request reprint Cobalt azide complexes with a tris(carbene)borate ligand scaffold
    Jeremiah J Scepaniak
    Department of Chemistry and Biochemistry, New Mexico State University, MSC 3C, Las Cruces, NM 88003, USA
    Acta Crystallogr C 69:968-71. 2013
  9. doi request reprint First-principles calculation of pKa values for organic acids in nonaqueous solution
    Feizhi Ding
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, USA
    J Org Chem 74:2679-91. 2009
  10. doi request reprint Formation of ammonia from an iron nitrido complex
    Jeremiah J Scepaniak
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces NM 88011 USA, Fax 1 575 646 2649
    Angew Chem Int Ed Engl 48:3158-60. 2009

Collaborators

  • Ranko P Bontchev
  • Timothy A Jackson
  • J Krzystek
  • Jeremy N Harvey
  • Jeremiah J Scepaniak
  • Charles G Margarit
  • Feizhi Ding
  • Haobin Wang
  • Wei Tsung Lee
  • Adam P Forshaw
  • Diane A Dickie
  • Salvador B Muñoz
  • T David Harris
  • Carola S Vogel
  • Karsten Meyer
  • Ismael Nieto
  • Ryan E Cowley
  • S A Zvyagin
  • Dmitry Smirnov
  • Joseph M Zadrozny
  • Alejandro J Metta-Magana
  • Hemamala I Karunadasa
  • Alexander Schnegg
  • Andrew Ozarowski
  • Karsten Holldack
  • Diane M Barnes
  • Joshua Telser
  • Ahmad Alamiri
  • Wallace K Foster
  • Hsiu Jung Lin
  • Jörg Sutter
  • Marat M Khusniyarov
  • Frank W Heinemann
  • Jessica A Young
  • Meita D Fulton
  • Eileen N Duesler
  • Martin L Kirk
  • John Sorrell
  • Orcino Sarracino
  • Yanhua Feng

Detail Information

Publications14

  1. doi request reprint N-O bond homolysis of an iron(II) TEMPO complex yields an iron(III) oxo intermediate
    Jeremy M Smith
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces New Mexico 88003, USA
    J Am Chem Soc 134:6516-9. 2012
    ..The oxo intermediate is active in oxygen atom transfer reactions and can be trapped by the triphenylmethyl radical to give the iron(II) alkoxo complex PhB(MesIm)(3)Fe(OCPh(3))...
  2. ncbi request reprint The structure and reactivity of iron nitride complexes
    Jeremy M Smith
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, NM 88003, USA
    Dalton Trans 41:1423-9. 2012
    ..One-electron oxidation of a tris(carbene)borate iron(IV) nitride leads to an isolable iron(V) complex that is unusually reactive for a metal nitride...
  3. doi request reprint Thermodynamics of hydrogen atom transfer to a high-valent iron imido complex
    Ismael Nieto
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces New Mexico 88003, USA
    J Am Chem Soc 130:2716-7. 2008
    ..Consistent with this value, [LMesFe[triple bond]NAd]OTf reacts with 9,10-dihydroanthracene (C-H BDE = 78(1) kcal/mol) to form anthracene...
  4. doi request reprint Synthesis, structure, and reactivity of an iron(V) nitride
    Jeremiah J Scepaniak
    Department of Chemistry and Biochemistry, MSC 3C, New Mexico State University, Las Cruces, NM 88003, USA
    Science 331:1049-52. 2011
    ..Low-temperature reaction of the iron(V) nitrido complex with water under reducing conditions leads to high yields of ammonia with concomitant formation of an iron(II) species...
  5. doi request reprint Structural and spectroscopic characterization of an electrophilic iron nitrido complex
    Jeremiah J Scepaniak
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, USA
    J Am Chem Soc 130:10515-7. 2008
    ..Reaction with PPh3 results in nitrogen atom transfer to the phosphine, supporting a reaction mechanism involving nucleophilic attack of the triphenylphosphine HOMO at the electrophilic LUMO of the iron nitrido complex...
  6. pmc Tris(carbene)borate ligands featuring imidazole-2-ylidene, benzimidazol-2-ylidene, and 1,3,4-triazol-2-ylidene donors. Evaluation of donor properties in four-coordinate {NiNO}10 complexes
    Salvador B Muñoz
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, United States
    Inorg Chem 51:12660-8. 2012
    ..There is a large variation in ν(NO), suggesting these ligands to have a wide range of donor strengths while maintaining a consistent ligand topology. All ligands are stronger donors than Tp* and Cp*...
  7. ncbi request reprint Spin crossover in a four-coordinate iron(II) complex
    Jeremiah J Scepaniak
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, United States
    J Am Chem Soc 133:3824-7. 2011
    ..These structural changes have been interpreted in terms of electronic structure theory...
  8. doi request reprint Cobalt azide complexes with a tris(carbene)borate ligand scaffold
    Jeremiah J Scepaniak
    Department of Chemistry and Biochemistry, New Mexico State University, MSC 3C, Las Cruces, NM 88003, USA
    Acta Crystallogr C 69:968-71. 2013
    ..Attempts to prepare cobalt nitrides by thermolysis or photolysis of these complexes were unsuccessful. ..
  9. doi request reprint First-principles calculation of pKa values for organic acids in nonaqueous solution
    Feizhi Ding
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, USA
    J Org Chem 74:2679-91. 2009
    ..Furthermore, the correlation between the pK(a) values of these acids in different solutions is investigated theoretically, and excellent agreement is found with the experimental results...
  10. doi request reprint Formation of ammonia from an iron nitrido complex
    Jeremiah J Scepaniak
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces NM 88011 USA, Fax 1 575 646 2649
    Angew Chem Int Ed Engl 48:3158-60. 2009
    ..The mechanism likely involves hydrogen-atom transfer from TEMPO-H to the nitrido complex. Similar reaction with the triphenylmethyl radical yields [PhB(MesIm)(3)Fe[triple chemical bond]N--CPh(3)]...
  11. ncbi request reprint Nitrogen atom transfer from iron(IV) nitrido complexes: a dual-nature transition state for atom transfer
    Jeremiah J Scepaniak
    Department of Chemistry and Biochemistry, New Mexico State University, MSC 3C, Las Cruces New Mexico 88003, United States
    Inorg Chem 50:9508-17. 2011
    ..Compared to analogous atom transfer reactions from a 5d metal, these results show how the electronic plasticity of a 3d metal results in rapid atom transfer from pseudotetrahedral late metal complexes...
  12. doi request reprint A tripodal ligand constructed from mesoionic carbene donors
    Wei Tsung Lee
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, United States
    Inorg Chem 52:12842-6. 2013
    ..The attenuated donor strength is proposed to be due to the collective electron-withdrawing effect of the ligand's aryl substituents. ..
  13. doi request reprint Low-spin hexacoordinate Mn(III): synthesis and spectroscopic investigation of homoleptic tris(pyrazolyl)borate and tris(carbene)borate complexes
    Adam P Forshaw
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico 88003, United States
    Inorg Chem 52:144-59. 2013
    ..The donor properties of the three different scorpionate ligands were further characterized using the LFT model that suggests that the tris(carbene)borate is a strong σ-donor with little or no π-bonding...
  14. pmc Formation of a cobalt(III) imido from a cobalt(II) amido complex. Evidence for proton-coupled electron transfer
    Ryan E Cowley
    Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, NM 88003, USA
    J Am Chem Soc 129:2424-5. 2007