Research Topics
| T J WallingtonSummaryAffiliation: Ford Motor Company Country: USA Publications
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Detail Information
Publications
Corn ethanol production, food exports, and indirect land use changeT J Wallington
Systems Analytics and Environmental Sciences Department, Ford Motor Company, Mail Drop RIC 2122, Dearborn, Michigan 48121 2053, United States
Environ Sci Technol 46:6379-84. 2012..We highlight the lack of information concerning the magnitude of intensification effects and the associated large uncertainties in assessments of the indirect land use change associated with corn ethanol...- Low-CO(2) electricity and hydrogen: a help or hindrance for electric and hydrogen vehicles?T J Wallington
Systems Analytics and Environmental Sciences Department, Ford Motor Company, Dearborn, Michigan 48121 2053, USA
Environ Sci Technol 44:2702-8. 2010..Connections between the sectors leading to this counterintuitive result need consideration in policy and technology planning... 
Formation of methyl nitrite and methyl nitrate during plasma treatment of diesel exhaustT J Wallington
Ford Motor Company, Mail Drop SRL 3083, Dearborn, Michigan 48121 2053, USA
Environ Sci Technol 37:4242-5. 2003..The linear relationship between the yields of CH3ONO and CH3ONO2 provides a means of estimating the yield of these compounds during nonthermal plasma treatment of diesel exhaust...- Formation of C7F15COOH (PFOA) and other perfluorocarboxylic acids during the atmospheric oxidation of 8:2 fluorotelomer alcoholT J Wallington
Ford Motor Company, SRL 3083, P O Box 2053, Dearborn, Michigan 48121 2053, USA
Environ Sci Technol 40:924-30. 2006..This is the first modeling study of the atmospheric chemistry of a fluorotelomer alcohol... - Atmospheric chemistry of n-butanol: kinetics, mechanisms, and products of Cl atom and OH radical initiated oxidation in the presence and absence of NO(x)M D Hurley
Systems Analytics and Environmental Sciences Department, Ford Motor Company, Mail Drop RIC 2122, Dearborn, Michigan 48121 2053, USA
J Phys Chem A 113:7011-20. 2009..The results are discussed with respect to the atmospheric chemistry of n-butanol... - Comment on "Atmospheric chemistry of linear perfluorinated aldehydes: dissociation kinetics of CnF2n+1CO radicals"T J Wallington
Ford Motor Company, RIC 2122, Dearborn, Michigan 48121-2053, USA
J Phys Chem A 112:576-7; discussion 577-8. 2008 - Atmospheric chemistry of 3-pentanol: kinetics, mechanisms, and products of Cl atom and OH radical initiated oxidation in the presence and absence of NOXM D Hurley
Systems Analytics and Environmental Sciences Department, Ford Motor Company, Mail Drop RIC 2122, Dearborn, Michigan 48121 2053, USA
J Phys Chem A 112:8053-60. 2008..The results are discussed with respect to the literature data and atmospheric chemistry of 3-pentanol... - Atmospheric chemistry of a model biodiesel fuel, CH3C(O)O(CH2)2OC(O)CH3: kinetics, mechanisms, and products of Cl atom and OH radical initiated oxidation in the presence and absence of NOxM D Hurley
Physical and Environmental Sciences Department, Ford Motor Company, Mail Drop SRL 3083, Dearborn, Michigan 48121, USA
J Phys Chem A 111:2547-54. 2007.... - Atmospheric chemistry of n-C(x)F(2)(x)(+1)CHO (x = 1, 2, 3, 4): fate of n-C(x)F(2)(x)(+1)C(O) radicalsM D Hurley
Ford Motor Company, P O Box 2053, Dearborn, Michigan 48121 2053, USA
J Phys Chem A 110:12443-7. 2006..Results are discussed with respect to the atmospheric chemistry of n-C(x)F(2)(x)(+1)C(O) radicals and their possible role in contributing to the formation of perfluorocarboxylic acids in the environment... - CO2 emission benefit of diesel (versus gasoline) powered vehiclesJ L Sullivan
Scientific Research Laboratory, SRL-3083, Ford Motor Company, Dearborn, Michigan 48121-2053, USA
Environ Sci Technol 38:3217-23. 2004..We anticipate that the gap between diesel and gasoline well-to-wheel vehicle CO2 emissions will decrease to approximately 14-27% by the year 2015... - R-134a emissions from vehiclesW O Siegl
Research Laboratory, Ford Motor Company, Dearborn, Michigan 48121, USA
Environ Sci Technol 36:561-6. 2002..The results are discussed with respect to the contribution of vehicle emissions to global climate change... - Organic aerosol formation during the atmospheric degradation of tolueneM D Hurley
Ford Motor Company, Dearborn, Michigan 48121 2053, USA
Environ Sci Technol 35:1358-66. 2001..075 +/- 0.004. In the presence of ozone the aerosol yield is 0.108 +/- 0.004. This work provides experimental evidence and a simple theory confirming the formation of aerosol from secondary reactions... - Products and mechanism of the reaction of chlorine atoms with 3-pentanone in 700-950 torr of N(2)/O(2) diluent at 297-515 KE W Kaiser
Department of Natural Sciences, University of Michigan Dearborn, 4901 Evergreen Road, Dearborn, Michigan 48128, USA
J Phys Chem A 114:343-54. 2010..6) x 10(-11) over the range of 297-460 K], 2,3-pentanedione [1.4 (+/-0.3) x 10(-11) at 297 K], and ethylvinylketone [1.9 (+/-0.4) x 10(-10) over the range of 297-400 K, decreasing rapidly above 400 K] were measured at ambient pressure... - Relative rate study of the kinetics, mechanism, and thermodynamics of the reaction of chlorine atoms with CF3CF═CH2 (HFO-1234yf) in 650-950 Torr of N2 or N2/O2 diluent at 296-462 KE W Kaiser
Department of Natural Sciences, University of Michigan Dearborn, 4901 Evergreen Road, Dearborn, Michigan 48128, United States
J Phys Chem A 116:5958-71. 2012..Rate constants relative to CH(4) for the reactions of Cl with the reference compounds CH(3)Cl, CH(2)Cl(2), and CHCl(3) were measured at 470 K to resolve a literature discrepancy. (R = 1.986 cal K(-1) mol(-1))... - Products and mechanism of the reaction of Cl with butanone in N2/O2 diluent at 297-526 KE W Kaiser
Department of Natural Sciences, University of Michigan Dearborn, 4901 Evergreen Road, Dearborn, Michigan 48128, USA
J Phys Chem A 113:2424-37. 2009..In 700-900 Torr of N(2)/O(2) diluent, the major fate of the alkoxy radicals CH(3)C(O)CH(O)CH(3) and OCH(2)C(O)C(2)H(5) is decomposition to give CH(3)C(O) radicals and CH(3)CHO and HCHO and C(O)C(2)H(5) radicals, respectively... - Methane emissions from vehiclesE K Nam
Research Laboratory MD-3083, Ford Motor Company, P.O. Box 2053, Dearborn, Michigan 48121, USA
Environ Sci Technol 38:2005-10. 2004..3-0.4% of that of CO2 emissions from vehicles. The environmental impact of CH4 emissions from vehicles is negligible and is likely to remain so for the foreseeable future... - Atmospheric chemistry of HFE-7500 in-C3F7CF(OC2H5)CF(CF3)2]: reaction with OH radicals and Cl atoms and atmospheric fate of n-C3F7CF(OCHO*)CF(CF3)2 and n-C3F7CF(OCH2CH2O9)CF(CF3)2 radicalsM Goto
Department of Molecular Engineering, Kyoto University, Japan
Environ Sci Technol 36:2395-402. 2002..The atmospheric oxidation of HFE-7500 gives n-C3F7-CF(OC(O)CH3)CF(CF3)2 and n-C3F7CF(OC(O)H)CF(CF3)2 as oxidation products. The results are discussed with respect to the atmospheric chemistry and environmental impact of HFE-7500... - Atmospheric lifetime of fluorotelomer alcoholsD A Ellis
Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6
Environ Sci Technol 37:3816-20. 2003.... - Experimental and computational investigation of gas-phase reaction of chlorine with n-propanol: observation of chloropropanol conformational isomerization at room temperatureT Yamanaka
Department of Molecular Engineering, Kyoto University, Kyoto 615 8510, Japan
J Phys Chem A 112:2773-81. 2008..As is typical of alpha-halogenated alcohols, CH3CH2CHClOH readily decomposes heterogeneously to propanal and HCl... - Atmospheric chemistry of 2-ethoxy-3,3,4,4,5-pentafluorotetrahydro-2,5-bis[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-furan: kinetics, mechanisms, and products of Cl atom and OH radical initiated oxidationM S Javadi
Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK 2100 Copenhagen, Denmark
Environ Sci Technol 41:7389-95. 2007..RfOC2H5 has a global warming potential of approximately 55 for a 100 year horizon. The results are discussed with respect to the atmospheric chemistry and environmental impact of RfOC2H5... - Kinetics and mechanism of the gas phase reaction of chlorine atoms with i-propanolT Yamanaka
Department of Molecular Engineering, Kyoto University, Kyoto 615 8510, Japan
Phys Chem Chem Phys 9:4211-7. 2007..IR spectra for the chlorides CH(3)CCl(OH)CH(3) and CH(3)CH(OH)CH(2)Cl were inferred experimentally and assignments confirmed via comparison with ab initio computed spectra... - Atmospheric chemistry of CF3CH=CH2 and C4F9CH=CH2: products of the gas-phase reactions with Cl atoms and OH radicalsT Nakayama
Solar Terrestrial Environment Laboratory and Graduate School of Science, Nagoya University, Honohara 3 13, Toyokawa, Aichi, 442 8507 Japan
J Phys Chem A 111:909-15. 2007..The results are discussed with respect to previous literature data and the possibility that the atmospheric oxidation of CxF2x+1CH=CH2 contributes to the observed burden of perfluorocarboxylic acids, CxF2x+1COOH, in remote locations... - Atmospheric chemistry of perfluoroalkanesulfonamides: kinetic and product studies of the OH radical and Cl atom initiated oxidation of N-ethyl perfluorobutanesulfonamideJ W Martin
Department of Chemistry, University of Toronto, 80 St George Street, Toronto, Ontario, Canada
Environ Sci Technol 40:864-72. 2006..Taken together, results suggest a plausible route by which perfluorooctanesulfonamides may serve as atmospheric sources of PFCAs, including perfluorooctanoic acid...