Jay A Labinger

Summary

Affiliation: California Institute of Technology
Country: USA

Publications

  1. ncbi request reprint Alfred Werner's Role in the mid-20th Century Flourishing of American Inorganic Chemistry
    Jay A Labinger
    California Institute of Technology, Beckman Institute, Pasadena, CA 90025, USA
    Chimia (Aarau) 68:292-6. 2014
  2. ncbi request reprint Understanding and exploiting C-H bond activation
    Jay A Labinger
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA
    Nature 417:507-14. 2002
  3. doi request reprint Upgrading light hydrocarbons via tandem catalysis: a dual homogeneous Ta/Ir system for alkane/alkene coupling
    David C Leitch
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, United States
    J Am Chem Soc 135:10302-5. 2013
  4. doi request reprint C-H bond activation by air-stable [(diimine)M(II)(mu2-OH)]2(2+) dimers (M = Pd, Pt)
    TRAVIS J WILLIAMS
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA
    J Am Chem Soc 130:2418-9. 2008
  5. doi request reprint Activator-free olefin oligomerization and isomerization reactions catalyzed by an air- and water-tolerant Wacker oxidation intermediate
    Matthew S Winston
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, CA 91125, USA
    Angew Chem Int Ed Engl 51:9822-4. 2012
  6. ncbi request reprint Kinetic and thermodynamic preferences in aryl vs benzylic C-H bond activation with cationic Pt(II) complexes
    Alan F Heyduk
    The Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA
    J Am Chem Soc 126:15034-5. 2004
  7. ncbi request reprint Thermodynamic studies of [H(2)Rh(diphosphine)(2)](+) and [HRh(diphosphine)(2)(CH(3)CN)](2+) complexes in acetonitrile
    Aaron D Wilson
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA
    Inorg Chem 49:3918-26. 2010
  8. ncbi request reprint Electronic Structures of Pd(II) Dimers
    John E Bercaw
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125
    Inorg Chem 49:1801-10. 2010
  9. ncbi request reprint A Versatile Ligand Platform that Supports Lewis Acid Promoted Migratory Insertion
    Amaruka Hazari
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, CA 91125 USA
    Angew Chem Int Ed Engl 51:8268-71. 2012
  10. ncbi request reprint Highly regioirregular polypropylene from asymmetric group 4 anilide(pyridine)phenoxide complexes
    Rachel C Klet
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA
    Chem Commun (Camb) 48:6657-9. 2012

Collaborators

  • Harry B Gray
  • John E Bercaw
  • Alexander J M Miller
  • Alan F Heyduk
  • David C Leitch
  • Rachel C Klet
  • Matthew S Winston
  • Amaruka Hazari
  • Aaron D Wilson
  • Paul F Oblad
  • Nilay Hazari
  • TRAVIS J WILLIAMS
  • Yan Choi Lam
  • David G VanderVelde
  • Jennifer C Green
  • Daniel L DuBois
  • Alec C Durrell
  • Jay R Winkler
  • Andrew J M Caffyn
  • Tom G Driver

Detail Information

Publications12

  1. ncbi request reprint Alfred Werner's Role in the mid-20th Century Flourishing of American Inorganic Chemistry
    Jay A Labinger
    California Institute of Technology, Beckman Institute, Pasadena, CA 90025, USA
    Chimia (Aarau) 68:292-6. 2014
    ..This paper explores the extent to which Werner's heritage - both direct, in the form of academic descendants, and indirect - contributed to those advances. ..
  2. ncbi request reprint Understanding and exploiting C-H bond activation
    Jay A Labinger
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA
    Nature 417:507-14. 2002
    ....
  3. doi request reprint Upgrading light hydrocarbons via tandem catalysis: a dual homogeneous Ta/Ir system for alkane/alkene coupling
    David C Leitch
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, United States
    J Am Chem Soc 135:10302-5. 2013
    ..This dual system can also effect the catalytic dimerization of n-heptane (neohexene as the H2 acceptor) with cooperative turnover numbers of 22/3 (Ir/Ta). ..
  4. doi request reprint C-H bond activation by air-stable [(diimine)M(II)(mu2-OH)]2(2+) dimers (M = Pd, Pt)
    TRAVIS J WILLIAMS
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA
    J Am Chem Soc 130:2418-9. 2008
  5. doi request reprint Activator-free olefin oligomerization and isomerization reactions catalyzed by an air- and water-tolerant Wacker oxidation intermediate
    Matthew S Winston
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, CA 91125, USA
    Angew Chem Int Ed Engl 51:9822-4. 2012
    ..A cationic Pd-hydride is generated principally through a Wacker oxidation of olefin to ketone, and with C(4+) olefins, lesser amounts of allylic C-H activation, β-H transfer, and release of diene products are observed...
  6. ncbi request reprint Kinetic and thermodynamic preferences in aryl vs benzylic C-H bond activation with cationic Pt(II) complexes
    Alan F Heyduk
    The Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA
    J Am Chem Soc 126:15034-5. 2004
    ..This unusual trend is attributed to formation of eta3-benzyl structures, which can be observed spectroscopically for 1,4-diethylbenzene activation...
  7. ncbi request reprint Thermodynamic studies of [H(2)Rh(diphosphine)(2)](+) and [HRh(diphosphine)(2)(CH(3)CN)](2+) complexes in acetonitrile
    Aaron D Wilson
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA
    Inorg Chem 49:3918-26. 2010
    ....
  8. ncbi request reprint Electronic Structures of Pd(II) Dimers
    John E Bercaw
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125
    Inorg Chem 49:1801-10. 2010
    ....
  9. ncbi request reprint A Versatile Ligand Platform that Supports Lewis Acid Promoted Migratory Insertion
    Amaruka Hazari
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, CA 91125 USA
    Angew Chem Int Ed Engl 51:8268-71. 2012
    ..These Lewis acids form relatively weak MO bonds, thereby enabling release of organic products from the metal center...
  10. ncbi request reprint Highly regioirregular polypropylene from asymmetric group 4 anilide(pyridine)phenoxide complexes
    Rachel C Klet
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA
    Chem Commun (Camb) 48:6657-9. 2012
    ..Group 4 complexes containing an anilide(pyridine)phenoxide ligand and activated with methylaluminoxane (MAO) catalyze the formation of highly regioirregular polypropylene...
  11. ncbi request reprint Catalytic alcoholysis of tetramethylsilane via Pt-mediated C-H bond activation
    Alan F Heyduk
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125
    J Am Chem Soc 125:6366-7. 2003
    ..Preliminary experiments suggest that a rate-determining C-H bond activation precedes rapid attack by solvent at silicon to yield the silyl ether product and regenerate the active platinum methyl cation...
  12. ncbi request reprint Homogeneous CO Hydrogenation: Dihydrogen Activation Involves a Frustrated Lewis Pair Instead of a Platinum Complex
    Alexander J M Miller
    Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125
    J Am Chem Soc 132:3301-3. 2010
    ..Treatment of the FLP with dihydrogen cleanly affords multiple hydride transfers and C-C bond formation...