Stephen Faulkner

Summary

Affiliation: University of Oxford
Country: UK

Publications

  1. doi request reprint Substituent effects on fluoride binding by lanthanide complexes of DOTA-tetraamides
    Octavia A Blackburn
    University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford OX1 3TA, UK
    Dalton Trans 45:3070-7. 2016
  2. doi request reprint Axial fluoride binding by lanthanide DTMA complexes alters the local crystal field, resulting in dramatic spectroscopic changes
    Octavia A Blackburn
    University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford OX1 3TA, UK
    Dalton Trans 44:19509-17. 2015
  3. doi request reprint Ratiometric oxygen sensing using lanthanide luminescent emitting interfaces
    Joshua Lehr
    University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford OX1 3TA, UK
    Chem Commun (Camb) 51:15944-7. 2015
  4. doi request reprint Controlling energy transfer in ytterbium complexes: oxygen dependent lanthanide luminescence and singlet oxygen formation
    Andrew Watkis
    Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, UK
    Chem Commun (Camb) 51:15633-6. 2015
  5. doi request reprint Ternary self-assemblies in water: forming a pentanuclear ReLn4 assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)3(dinicotinate)2Cl
    Leila R Hill
    University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, UK
    Dalton Trans 42:16255-8. 2013
  6. doi request reprint Preparation and study of an f,f,f',f'' covalently linked tetranuclear hetero-trimetallic complex - a europium, terbium, dysprosium triad
    Thomas Just Sørensen
    Chemical Research Laboratory, Oxford University, England, UK
    Chem Commun (Camb) 49:783-5. 2013
  7. pmc Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers
    Leila R Hill
    Chemistry Research Laboratory and University of Oxford, Mansfield Road, Oxford, OX1 3TA, UK
    Dalton Trans 42:67-70. 2013
  8. doi request reprint Ligation driven (19)F relaxation enhancement in self-assembled Ln(III) complexes
    Gemma Louise Davies
    Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK
    Chem Commun (Camb) 51:2918-20. 2015
  9. pmc Nitrite-templated synthesis of lanthanide-containing [2]rotaxanes for anion sensing
    Matthew J Langton
    Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, OX1 3TA UK
    Angew Chem Int Ed Engl 53:11463-6. 2014
  10. pmc Anion sensing by solution- and surface-assembled osmium(II) bipyridyl rotaxanes
    Joshua Lehr
    Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QZ UK
    Chemistry 19:15898-906. 2013

Collaborators

  • Paul D Beer
  • David Parker
  • Benjamin P Burton-Pye
  • Manuel Tropiano
  • Octavia A Blackburn
  • Joshua Lehr
  • Jason J Davis
  • Thomas Just Sørensen
  • Alan M Kenwright
  • Leila R Hill
  • Jack D Routledge
  • Matthew J Langton
  • James A Tilney
  • Andrew Watkis
  • Gemma Louise Davies
  • Michael W Jones
  • Asha Brown
  • Thomas Lang
  • Fabiola Zapata
  • Nicholas H Rees
  • Laura B Jennings
  • Rebekka Hueting
  • Octavia Blackburn
  • Thomas J Sørensen
  • Timothy A Barendt
  • Jamie Bennett
  • Andrew Beeby
  • Louise S Natrajan
  • Lisa M Bushby
  • James Thom
  • Michael Morten
  • Habibur Rahman
  • Nathan L Kilah

Detail Information

Publications20

  1. doi request reprint Substituent effects on fluoride binding by lanthanide complexes of DOTA-tetraamides
    Octavia A Blackburn
    University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford OX1 3TA, UK
    Dalton Trans 45:3070-7. 2016
    ..There are clear differences in the entropic contribution to the free energy of activation between systems with benzylic amides and those with methylamides. ..
  2. doi request reprint Axial fluoride binding by lanthanide DTMA complexes alters the local crystal field, resulting in dramatic spectroscopic changes
    Octavia A Blackburn
    University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford OX1 3TA, UK
    Dalton Trans 44:19509-17. 2015
    ....
  3. doi request reprint Ratiometric oxygen sensing using lanthanide luminescent emitting interfaces
    Joshua Lehr
    University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford OX1 3TA, UK
    Chem Commun (Camb) 51:15944-7. 2015
    ..The resulting interfaces demonstrated a ratiometric oxygen response between 0 and 0.2 atm partial oxygen pressure. ..
  4. doi request reprint Controlling energy transfer in ytterbium complexes: oxygen dependent lanthanide luminescence and singlet oxygen formation
    Andrew Watkis
    Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, UK
    Chem Commun (Camb) 51:15633-6. 2015
    ..Formation of the ytterbium(iii) excited state is sensitised via both the singlet and triplet excited states of the chromophore. Energy transfer from the latter is relatively slow, and gives rise to oxygen-dependent luminescence. ..
  5. doi request reprint Ternary self-assemblies in water: forming a pentanuclear ReLn4 assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)3(dinicotinate)2Cl
    Leila R Hill
    University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, UK
    Dalton Trans 42:16255-8. 2013
    ..Two dinicotinate binding sites are placed at a right-angle in a rhenium complex, which is shown to form a 1 : 2 complex with α,α'-bis(Eu·DO3A)-5-amino-m-xylene...
  6. doi request reprint Preparation and study of an f,f,f',f'' covalently linked tetranuclear hetero-trimetallic complex - a europium, terbium, dysprosium triad
    Thomas Just Sørensen
    Chemical Research Laboratory, Oxford University, England, UK
    Chem Commun (Camb) 49:783-5. 2013
    ..The covalently linked trimetallic system exhibits luminescence from all the different lanthanide centres...
  7. pmc Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers
    Leila R Hill
    Chemistry Research Laboratory and University of Oxford, Mansfield Road, Oxford, OX1 3TA, UK
    Dalton Trans 42:67-70. 2013
    ..The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated...
  8. doi request reprint Ligation driven (19)F relaxation enhancement in self-assembled Ln(III) complexes
    Gemma Louise Davies
    Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK
    Chem Commun (Camb) 51:2918-20. 2015
    ..Strong bidentate ligation between a fluorinated isophthalate and binuclear lanthanide-DO3A species yields a new class of (19)F NMR agent with very high nuclear relaxation rates at physiologically-relevant pH. ..
  9. pmc Nitrite-templated synthesis of lanthanide-containing [2]rotaxanes for anion sensing
    Matthew J Langton
    Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, OX1 3TA UK
    Angew Chem Int Ed Engl 53:11463-6. 2014
    ..Following removal of the nitrite anion template, the europium [2]rotaxane host is demonstrated to recognize and sense fluoride selectively. ..
  10. pmc Anion sensing by solution- and surface-assembled osmium(II) bipyridyl rotaxanes
    Joshua Lehr
    Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QZ UK
    Chemistry 19:15898-906. 2013
    ....
  11. doi request reprint Reversible recruitment and emission of DO3A-derived lanthanide complexes at ligating molecular films on gold
    Joshua Lehr
    Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3TA, United Kingdom
    Langmuir 29:1475-82. 2013
    ..The switchable catechol oxidation state provides a means of electrochemically triggering the release of prior ligated complexes...
  12. doi request reprint Reversible redox modulation of a lanthanide emissive molecular film
    Joshua Lehr
    Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3TA, United Kingdom
    Chem Commun (Camb) 51:6515-7. 2015
    ..Electrochemical modulation of europium emission upon switching the ferrocene moiety's redox state is ascribed to the reversible generation of a quenching ferrocenium species. ..
  13. doi request reprint Kinetically Stable Lanthanide Complexes Displaying Exceptionally High Quantum Yields upon Long-Wavelength Excitation: Synthesis, Photophysical Properties, and Solution Speciation
    Jack D Routledge
    University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford OX1 3TA, United Kingdom
    Inorg Chem 54:3337-45. 2015
    ..Knowledge of the molecular speciation in solution is therefore critical when assessing the luminescence properties of such complexes. ..
  14. doi request reprint Luminescence and upconversion from thulium(III) species in solution
    Octavia A Blackburn
    Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, OX1 3TA, UK
    Phys Chem Chem Phys 14:13378-84. 2012
    ....
  15. doi request reprint Self-assembly between dicarboxylate ions and a binuclear europium complex: formation of stable adducts and heterometallic lanthanide complexes
    James A Tilney
    University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford, UK OX1 3TA
    Dalton Trans 40:12063-6. 2011
    ..The complex with isophthalate derivatives is particularly stable...
  16. doi request reprint Exploiting lanthanide luminescence in supramolecular assemblies
    Joshua Lehr
    Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3TA, UK
    Chem Commun (Camb) 50:5678-87. 2014
    ..In this feature article we discuss the current and potential applications for lanthanide luminescence in supramolecular, switchable and surface bound architectures. ..
  17. doi request reprint Lanthanide complexes of azidophenacyl-DO3A as new synthons for click chemistry and the synthesis of heterometallic lanthanide arrays
    Manuel Tropiano
    Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA UK
    Chemistry 21:5697-9. 2015
    ..They also undergo click chemistry with propargylDO3A derivatives, giving rise to heterometallic complexes. ..
  18. doi request reprint Reversible luminescence switching of a redox-active ferrocene-europium dyad
    Manuel Tropiano
    Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA, UK
    J Am Chem Soc 133:11847-9. 2011
    ....
  19. doi request reprint Lanthanide cation-templated synthesis of rotaxanes
    Fabiola Zapata
    Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, OX1 3TA, UK
    Chem Commun (Camb) 49:8157-9. 2013
    ..Stoppering of the pseudo-rotaxane assembly allows for preparation of the [2]rotaxane. ..
  20. doi request reprint A lanthanide based sensor for the time-gated detection of hydrogen sulfide
    Manuel Tropiano
    University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford OX1 3TA, UK
    Chem Commun (Camb) 50:4696-8. 2014
    ..The probe shows excellent selectivity and fast reaction time. Its long-lived luminescence makes this the first probe for the time-gated detection of sulfide in complex biological samples...