Pavel Matousek

Summary

Affiliation: Rutherford Appleton Laboratory
Country: UK

Publications

  1. ncbi request reprint Depth profiling in diffusely scattering media using Raman spectroscopy and picosecond Kerr gating
    P Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK
    Appl Spectrosc 59:200-5. 2005
  2. ncbi request reprint Noninvasive Raman spectroscopy of human tissue in vivo
    Pavel Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK
    Appl Spectrosc 60:758-63. 2006
  3. ncbi request reprint Inverse spatially offset Raman spectroscopy for deep noninvasive probing of turbid media
    Pavel Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK
    Appl Spectrosc 60:1341-7. 2006
  4. ncbi request reprint Bulk Raman analysis of pharmaceutical tablets
    P Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK
    Appl Spectrosc 60:1353-7. 2006
  5. ncbi request reprint Numerical simulations of subsurface probing in diffusely scattering media using spatially offset Raman spectroscopy
    P Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK
    Appl Spectrosc 59:1485-92. 2005
  6. ncbi request reprint Prospects for the diagnosis of breast cancer by noninvasive probing of calcifications using transmission Raman spectroscopy
    Pavel Matousek
    Council for the Central Laboratory of the Research Councils, Rutherford Appleton Laboratory, Central Laser Facility, Oxfordshire OX11 0QX, United Kingdom
    J Biomed Opt 12:024008. 2007
  7. ncbi request reprint Deep non-invasive Raman spectroscopy of living tissue and powders
    Pavel Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, UK OX11 0QX
    Chem Soc Rev 36:1292-304. 2007
  8. ncbi request reprint A high-sensitivity femtosecond to microsecond time-resolved infrared vibrational spectrometer
    Michael Towrie
    Central Laser Facility, CCLRC, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX, United Kingdom
    Appl Spectrosc 59:467-73. 2005
  9. doi request reprint Technique for enhancing signal in conventional backscattering fluorescence and Raman spectroscopy of turbid media
    Kevin Buckley
    Central Laser Facility, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire, OX11 0QX, United Kingdom
    Anal Chem 80:6006-9. 2008
  10. doi request reprint Recent advances in the development of Raman spectroscopy for deep non-invasive medical diagnosis
    Pavel Matousek
    Central Laser Facility, Research Complex at Harwell, STFC Rutherford Appleton Laboratory, Harwell Oxford, UK
    J Biophotonics 6:7-19. 2013

Collaborators

Detail Information

Publications52

  1. ncbi request reprint Depth profiling in diffusely scattering media using Raman spectroscopy and picosecond Kerr gating
    P Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK
    Appl Spectrosc 59:200-5. 2005
    ..The experiments were performed in back-scattering geometry using 400 nm excitation wavelength. The experimental technique should be well suited to biomedical applications such as disease diagnosis...
  2. ncbi request reprint Noninvasive Raman spectroscopy of human tissue in vivo
    Pavel Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK
    Appl Spectrosc 60:758-63. 2006
    ..As a generic analytical tool this approach paves the way for a range of uses including disease diagnosis, noninvasive probing of pharmaceutical products, biofilms, catalysts, paints, and in dermatological applications...
  3. ncbi request reprint Inverse spatially offset Raman spectroscopy for deep noninvasive probing of turbid media
    Pavel Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK
    Appl Spectrosc 60:1341-7. 2006
    ..Potential applications include disease diagnosis, noninvasive probing of pharmaceutical products and chemicals through packaging, probing of polymers, biofilms or paints, and homeland security screening...
  4. ncbi request reprint Bulk Raman analysis of pharmaceutical tablets
    P Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK
    Appl Spectrosc 60:1353-7. 2006
    ..Given its properties and instrumental simplicity, the transmission method is particularly well suited to the on-line analysis of bulk content of tablets in pharmaceutical applications...
  5. ncbi request reprint Numerical simulations of subsurface probing in diffusely scattering media using spatially offset Raman spectroscopy
    P Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK
    Appl Spectrosc 59:1485-92. 2005
    ..The model also clearly indicates that an annular geometry, rather than a point-collection geometry, which was used in the earlier experiments, would yield much improved data...
  6. ncbi request reprint Prospects for the diagnosis of breast cancer by noninvasive probing of calcifications using transmission Raman spectroscopy
    Pavel Matousek
    Council for the Central Laboratory of the Research Councils, Rutherford Appleton Laboratory, Central Laser Facility, Oxfordshire OX11 0QX, United Kingdom
    J Biomed Opt 12:024008. 2007
    ....
  7. ncbi request reprint Deep non-invasive Raman spectroscopy of living tissue and powders
    Pavel Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, UK OX11 0QX
    Chem Soc Rev 36:1292-304. 2007
    ..As generic analytical tools, the methods pave the way for a range of new applications for Raman spectroscopy, including disease diagnosis, non-invasive probing of pharmaceutical products in quality control and security screening...
  8. ncbi request reprint A high-sensitivity femtosecond to microsecond time-resolved infrared vibrational spectrometer
    Michael Towrie
    Central Laser Facility, CCLRC, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX, United Kingdom
    Appl Spectrosc 59:467-73. 2005
    ..The results are compared to conventional nanosecond Fourier transform infrared (FT-IR) and laser based flash photolysis time-resolved infrared technology...
  9. doi request reprint Technique for enhancing signal in conventional backscattering fluorescence and Raman spectroscopy of turbid media
    Kevin Buckley
    Central Laser Facility, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire, OX11 0QX, United Kingdom
    Anal Chem 80:6006-9. 2008
    ..Potential applications of this simple device include improving quality control of pharmaceutical products, disease diagnosis of biological tissue, forensics, and security screening...
  10. doi request reprint Recent advances in the development of Raman spectroscopy for deep non-invasive medical diagnosis
    Pavel Matousek
    Central Laser Facility, Research Complex at Harwell, STFC Rutherford Appleton Laboratory, Harwell Oxford, UK
    J Biophotonics 6:7-19. 2013
    ..Examples of emerging applications include non-invasive diagnosis of bone disease, cancer and monitoring of glucose levels. This article reviews this fast moving field focusing on recent developments within the medical area...
  11. doi request reprint Emerging non-invasive Raman methods in process control and forensic applications
    Neil A MacLeod
    Central Laser Facility, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire, OX11 0QX, UK
    Pharm Res 25:2205-15. 2008
    ....
  12. doi request reprint Characterisation of transmission Raman spectroscopy for rapid quantitative analysis of intact multi-component pharmaceutical capsules
    Michael D Hargreaves
    Cobalt Light Systems Ltd, Start Electron, Fermi Avenue, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QR, UK
    J Pharm Biomed Anal 54:463-8. 2011
    ..Ultimately, this technique has significant promise as a Process Analytical Technology (PAT) tool for online production application...
  13. doi request reprint Recent advances in the application of transmission Raman spectroscopy to pharmaceutical analysis
    Kevin Buckley
    Central Laser Facility, Research Complex at Harwell, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Didcot, Oxfordshire OX110QX, UK
    J Pharm Biomed Anal 55:645-52. 2011
    ....
  14. ncbi request reprint Subsurface probing in diffusely scattering media using spatially offset Raman spectroscopy
    P Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, United Kingdom
    Appl Spectrosc 59:393-400. 2005
    ....
  15. ncbi request reprint Functional adaptation of long bone extremities involves the localized "tuning" of the cortical bone composition; evidence from Raman spectroscopy
    Kevin Buckley
    Central Laser Facility, Research Complex at Harwell, STFC Rutherford Appleton Laboratory, Harwell Oxford, OX11 0FA, United KingdombUniversity College London, Institute of Orthopaedics and Musculoskeletal Science, Stanmore, HA7 4LP, United Kingdom
    J Biomed Opt 19:111602. 2014
    ....
  16. doi request reprint Non-invasive analysis of turbid samples using deep Raman spectroscopy
    Kevin Buckley
    Central Laser Facility, Research Complex at Harwell, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Didcot, Oxfordshire OX11 0QX, UK
    Analyst 136:3039-50. 2011
    ..This article reviews this field focusing on recent developments with high societal relevance...
  17. doi request reprint Non-invasive quantitative assessment of the content of pharmaceutical capsules using transmission Raman spectroscopy
    Charlotte Eliasson
    Central Laser Facility, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire, UK
    J Pharm Biomed Anal 47:221-9. 2008
    ..The measured relative root mean square error of prediction (RMSEP) of the concentration of the active pharmaceutical ingredient (API) was 1.2 and 1.8% with 5 and 1s acquisition times, respectively...
  18. ncbi request reprint Simple reconstruction algorithm for shifted excitation Raman difference spectroscopy
    P Matousek
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, United Kingdom
    Appl Spectrosc 59:848-51. 2005
  19. doi request reprint Prediction of sublayer depth in turbid media using spatially offset Raman spectroscopy
    N A MacLeod
    Central Laser Facility, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire, OX11 0QX, United Kingdom
    Anal Chem 80:8146-52. 2008
    ....
  20. ncbi request reprint Millimeter-scale mapping of cortical bone reveals organ-scale heterogeneity
    Kevin Buckley
    Central Laser Facility, Research Complex at Harwell, STFC Rutherford Appleton Laboratory, Harwell Oxford OX11 0FA, UK
    Appl Spectrosc 68:510-4. 2014
    ....
  21. doi request reprint The early picosecond photophysics of Ru(II) polypyridyl complexes: a tale of two timescales
    William Henry
    National Centre for Sensors Research, Dublin City University, Dublin 9, Ireland
    J Phys Chem A 112:4537-44. 2008
    ....
  22. doi request reprint Emerging concepts in deep Raman spectroscopy of biological tissue
    Pavel Matousek
    Central Laser Facility, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire, UK OX11 0QX
    Analyst 134:1058-66. 2009
    ....
  23. ncbi request reprint Deep subsurface Raman spectroscopy of turbid media by a defocused collection system
    C Eliasson
    Central Laser Facility, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire, OX11 0QX, United Kingdom
    Appl Spectrosc 61:1123-7. 2007
    ..Demonstration of the effect is performed using a standard SORS device and a commercial Raman instrument on the noninvasive measurement of paracetamol tablets held within a nontransparent white plastic bottle...
  24. ncbi request reprint ULTRA: A Unique Instrument for Time-Resolved Spectroscopy
    Gregory M Greetham
    Central Laser Facility, Research Complex at Harwell, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire, OX11 0QX, UK
    Appl Spectrosc 64:1311-9. 2010
    ....
  25. ncbi request reprint Noninvasive authentication of pharmaceutical products through packaging using spatially offset Raman spectroscopy
    Charlotte Eliasson
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0QX, UK
    Anal Chem 79:1696-701. 2007
    ..It is demonstrated that such interfering signals can be effectively suppressed by SORS...
  26. doi request reprint Dependence of signal on depth in transmission Raman spectroscopy
    Pavel Matousek
    Central Laser Facility, Research Complex at Harwell, STFC Rutherford Appleton Laboratory, Harwell Oxford, Didcot, UK
    Appl Spectrosc 65:724-33. 2011
    ..The absorption was also shown to produce a depth profile with the photon diode similar to that without it, although with a reduced absolute intensity of Raman signals and diminished enhancement effect...
  27. ncbi request reprint Development of a broadband picosecond infrared spectrometer and its incorporation into an existing ultrafast time-resolved resonance Raman, UV/visible, and fluorescence spectroscopic apparatus
    Michael Towrie
    Central Laser Facility, CCLRC Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX, United Kingdom
    Appl Spectrosc 57:367-80. 2003
    ..We present preliminary picosecond TRIR studies using this spectrometer and also demonstrate how a combination of TRIR and TR3 spectroscopy can provide key information for the full elucidation of a photochemical process...
  28. ncbi request reprint Prospects of Deep Raman Spectroscopy for Noninvasive Detection of Conjugated Surface Enhanced Resonance Raman Scattering Nanoparticles Buried within 25 mm of Mammalian Tissue
    Nicholas Stone
    Biophotonics Research Unit, Gloucestershire Hospitals NHS Foundation Trust, Great Western Road, Gloucester, GL1 3NN, Centre for Molecular Nanometrology, WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, and Central Laser Facility, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Oxfordshire, OX11 0QX
    Anal Chem 82:3969-73. 2010
    ..This permits noninvasive measurement of Raman signatures from conjugated SERRS nanoparticles at clinically relevant concentrations through tissues of between 15 and 25 mm thick...
  29. ncbi request reprint Non-invasive detection of cocaine dissolved in beverages using displaced Raman spectroscopy
    C Eliasson
    Central Laser Facility, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX, United Kingdom
    Anal Chim Acta 607:50-3. 2008
    ..The technique holds great promise for the fast, non-invasive, detection of concealed illicit compounds inside beverages using portable Raman instruments, thus permitting drug trafficking to be combated more effectively...
  30. ncbi request reprint Subsurface probing of calcifications with spatially offset Raman spectroscopy (SORS): future possibilities for the diagnosis of breast cancer
    Nicholas Stone
    Biophotonics Research Group, Gloucestershire Royal Hospital, Great Western Road, Gloucester, UKGL1 3NN
    Analyst 132:899-905. 2007
    ..Non-invasive elucidation of calcification composition, and hence type, associated with benign or malignant lesions, could eliminate the requirement for biopsy in many patients...
  31. ncbi request reprint Depth profiling of calcifications in breast tissue using picosecond Kerr-gated Raman spectroscopy
    Rebecca Baker
    Biophotonics Research Group, Gloucestershire Royal Hospital, Great Western Road, Gloucester, UK
    Analyst 132:48-53. 2007
    ..This presents great potential for the use of Raman spectroscopy as an adjunct to mammography in the early diagnosis of breast cancer...
  32. ncbi request reprint Kerr-gated time-resolved Raman spectroscopy of equine cortical bone tissue
    Michael D Morris
    University of Michigan, Department of Chemistry, Ann Arbor, Michigan 48109, USA
    J Biomed Opt 10:14014. 2005
    ..These novel results demonstrate great promise for in vivo applications for studying diseased bone tissue, and ways to optimize the setup are discussed...
  33. ncbi request reprint Structural features of two distinct molecular complexes of copper(II) cationic porphyrin and deoxyribonucleotides
    Peter Mojzes
    Institute of Physics, Charles University, Ke Karlovu 5, Prague 2, CZ 12116, Czech Republic
    Biopolymers 67:278-81. 2002
    ..dTMP and CuP. (dTMP)2 species to form the exciplex, two types of molecular complexes were suggested and discussed, differing in the orientation of the thymine planes with respect to the porphyrin macrocycle...
  34. doi request reprint Advanced transmission Raman spectroscopy: a promising tool for breast disease diagnosis
    Nicholas Stone
    Biophotonics Research Unit, Gloucestershire Royal Hospital, Gloucester, United Kingdom
    Cancer Res 68:4424-30. 2008
    ..7 cm within a breast phantom made up of porcine tissues. The technique has shown significant potential for probing human breasts to provide complementary data in the early diagnosis of breast cancer...
  35. doi request reprint Ultrafast excited state dynamics controlling photochemical isomerization of N-methyl-4-[trans-2-(4-pyridyl)ethenyl]pyridinium coordinated to a {Re I(CO)3(2,2'-bipyridine)} chromophore
    Michael Busby
    School of Biological and Chemical Sciences, Queen Mary, University of London, Mile End Road, London, UK
    Chemistry 14:6912-23. 2008
    ..The complex [Re(MeDpe(+))(CO)(3)(bpy)](2+) emerges as a prototypical, multifunctional species with complementary redox and photonic behavior...
  36. ncbi request reprint Photooxidation of guanine by a ruthenium dipyridophenazine complex intercalated in a double-stranded polynucleotide monitored directly by picosecond visible and infrared transient absorption spectroscopy
    Benjamin Elias
    Service de Chimie Organique et Photochimie, CP 160 08, Universite Libre de Bruxelles, 50 Avenue F D Roosevelt, 1050 Bruxelles, Belgium
    Chemistry 14:369-75. 2008
    ....
  37. ncbi request reprint Fluorescence kinetics of aqueous solutions of tetracycline and its complexes with Mg2+ and Ca2+
    Siegfried Schneider
    Institut fur Physikalische und Theoretische Chemie, Friedrich Alexander Universitat Erlangen Nurnberg, D 91058 Erlangen, Germany
    Photochem Photobiol Sci 2:1107-17. 2003
    ..The ESIPT process yields primary photoproducts that should emit at much longer wavelengths, thereby explaining the unusually large fluorescence Stokes shift...
  38. ncbi request reprint Raman spectroscopy of street samples of cocaine obtained using Kerr gated fluorescence rejection
    Rachael E Littleford
    Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, UKG1 1XL
    Analyst 129:505-6. 2004
    ..The first use of Kerr gated fluorescence rejection Raman spectroscopy for the analysis of street samples of cocaine in a fluorescing matrix is reported...
  39. ncbi request reprint Excited-state dynamics of fac-[ReI(L)(CO)3(phen)]+ and fac-[ReI(L)(CO)3(5-NO2-phen)]+ (L = imidazole, 4-ethylpyridine; phen = 1,10-phenanthroline) complexes
    Michael Busby
    Department of Chemistry and Centre for Materials Research, Queen Mary, University of London, Mile End Road, London E1 4NS, United Kingdom
    Inorg Chem 43:4994-5002. 2004
    ..ligand occurs, producing a long-lived species, [Re(I)(im.)(CO)(3)(5-NO(2)-phen).-]+...
  40. ncbi request reprint Observation of excited-state proton transfer in green fluorescent protein using ultrafast vibrational spectroscopy
    Deborah Stoner-Ma
    Department of Chemistry, Stony Brook University, Stony Brook, New York 11794 3400, USA
    J Am Chem Soc 127:2864-5. 2005
    ..The TIR data show that the rate-limiting step in the proton relay is deprotonation of the chromophore...
  41. ncbi request reprint Structural analysis of lignin by resonance Raman spectroscopy
    Søren Barsberg
    Forest and Landscape, The Royal Veterinary and Agricultural University, Højbakkegård Allé 1, DK 2630 Taastrup, Denmark
    Macromol Biosci 5:743-52. 2005
    ..New possibilities for basic and selective structural information on fluorescent natural materials, such as lignin, have thus appeared...
  42. ncbi request reprint Use of picosecond Kerr-gated Raman spectroscopy to suppress signals from both surface and deep layers in bladder and prostate tissue
    Maria Consuelo Hart Prieto
    Gloucestershire Royal Hospital, Biophotonics Research Group, Pullman Court, Great Western Road, Gloucester GL 1 3NN, United Kingdom
    J Biomed Opt 10:44006. 2005
    ....
  43. ncbi request reprint Novel assessment of bone using time-resolved transcutaneous Raman spectroscopy
    Edward R C Draper
    Royal Veterinary College, Hatfield, Hertfordshire, United Kingdom
    J Bone Miner Res 20:1968-72. 2005
    ..We recorded Raman spectra of both the mineral and organic phases of bone transcutaneously, a technology with potential to enhance bone quality and fracture risk assessment...
  44. ncbi request reprint Picosecond time-resolved infrared spectroscopic investigation into electron localisation in the excited states of Re(i) polypyridyl complexes with bridging ligands
    Marina K Kuimova
    School of Chemistry, University of Nottingham, University Park, Nottingham, UK
    Photochem Photobiol Sci 5:82-7. 2006
    ..The nu(CO) bands of the adjacent Re centre are affected by the reduction of the bridging ligand. On the IR timescale the excited state structure is best formulated as [Cl(CO)3Re(II)(micro-ppbMe2 *-)Re(I)(CO)3Cl]...
  45. pmc Lignin radicals in the plant cell wall probed by Kerr-gated resonance Raman spectroscopy
    Søren Barsberg
    Danish Centre for Forest, Landscape and Planning, The Royal Veterinary and Agricultural University, DK 2630 Taastrup, Denmark
    Biophys J 90:2978-86. 2006
    ..These observations can be crucial for an understanding of the factors that control cell wall structure during biosynthesis of vascular plants and demonstrate the unique potential of RR spectroscopy of lignin radicals...
  46. pmc Monitoring the direct and indirect damage of DNA bases and polynucleotides by using time-resolved infrared spectroscopy
    Marina K Kuimova
    School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, United Kingdom
    Proc Natl Acad Sci U S A 103:2150-3. 2006
    ..The ability to use time-resolved infrared spectroscopy in this way paves the way for developing solution-phase studies to investigate both direct and indirect radiation chemistry of DNA...
  47. ncbi request reprint Excited-state dynamics of structurally characterized [ReI(CO)3(phen)(HisX)]+ (X = 83, 109) Pseudomonas aeruginosa azurins in aqueous solution
    Ana Maria Blanco-Rodriguez
    School of Biological and Chemical Sciences, Queen Mary, University of London, UK
    J Am Chem Soc 128:4365-70. 2006
    ..5 ps); the 250-ps relaxation is attributable to reorientation of D(2)O molecules as well as structural reorganization of the rhenium chromophore and nearby polar amino acids in each of the modified proteins...
  48. ncbi request reprint Ligand-to-diimine/metal-to-diimine charge-transfer excited states of [Re(NCS)(CO)3(alpha-diimine)] (alpha-diimine = 2,2'-bipyridine, di-iPr-N,N-1,4-diazabutadiene). A spectroscopic and computational study
    Ana Maria Blanco Rodriguez
    Department of Chemistry and Centre for Materials Research, Queen Mary, University of London, Mile End Road, London E1 4NS, United Kingdom
    J Phys Chem A 109:5016-25. 2005
    ..Resonant enhancement of both nu(CO) and nu(NC) Raman bands indicates that the same LLCT/MLCT character mixing occurs in the lowest allowed electronic transition...
  49. ncbi request reprint Ultrafast excited-state dynamics preceding a ligand trans-cis isomerization of fac-[Re(Cl)(CO)3(t-4-styrylpyridine)2] and fac-[Re(t-4-styrylpyridine)(CO)3(2,2'-bipyridine)]+
    Michael Busby
    Department of Chemistry and Centre for Materials Research, Queen Mary, University of London, Mile End Road, London E1 4NS, United Kingdom
    J Phys Chem A 109:3000-8. 2005
    ....
  50. ncbi request reprint Picosecond time-resolved infrared study of 2-aminopurine ionisation in solution
    Marina K Kuimova
    School of Chemistry, University of Nottingham, University Park, Nottingham, UK
    Photochem Photobiol Sci 6:949-55. 2007
    ..DFT calculations (EDF1/6-31+G*) were used to support the assignment of the intermediates observed in these spectroscopic experiments...
  51. ncbi request reprint Characterization of genuine and fake artesunate anti-malarial tablets using Fourier transform infrared imaging and spatially offset Raman spectroscopy through blister packs
    Camilla Ricci
    Department of Chemical Engineering, Imperial College London, London SW7 2AZ, UK
    Anal Bioanal Chem 389:1525-32. 2007
    ..The advantages provided by a combination of SORS and ATR-FTIR imaging in this context confirm its potential for inclusion in the analytical protocol for forensic investigation of counterfeit medicines...
  52. ncbi request reprint Picosecond Kerr-gated time-resolved resonance Raman spectroscopy of the [Ru(phen)(2)dppz](2+) interaction with DNA
    Johan Olofsson
    Department of Physical Chemistry, Chalmers University of Technology, SE 412 96, Goteborg, Sweden
    J Inorg Biochem 91:286-97. 2002
    ..However, the early (4 ps) water spectrum resembles the spectrum in DNA. This interesting observation suggests that the DNA-bound excited state of the complex can be thought of as a model for the initial, poorly solvated state in water...