Armando Córdova

Summary

Affiliation: Stockholm University
Country: Sweden

Publications

  1. ncbi Amino acid catalyzed neogenesis of carbohydrates: a plausible ancient transformation
    Armando Córdova
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, Sweden
    Chemistry 11:4772-84. 2005
  2. ncbi Direct amino acid catalyzed asymmetric synthesis of polyketide sugars
    JESUS CASAS
    Department of Organic Chemistry, Stockholm University, 10691 Stockholm, Sweden
    Angew Chem Int Ed Engl 44:1343-5. 2005
  3. ncbi Direct catalytic enantioselective aza-Diels-Alder reactions
    Henrik Sundén
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Angew Chem Int Ed Engl 44:4877-80. 2005
  4. ncbi Direct amino acid catalyzed asymmetric alpha oxidation of ketones with molecular oxygen
    Henrik Sundén
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, Stockholm, Sweden
    Angew Chem Int Ed Engl 43:6532-5. 2004
  5. ncbi Sugar-assisted kinetic resolution of amino acids and amplification of enantiomeric excess of organic molecules
    Armando Córdova
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 12:5446-51. 2006
  6. ncbi One-pot catalytic asymmetric cascade synthesis of cycloheptane derivatives
    Jan Vesely
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm Sweden
    Chemistry 14:2693-8. 2008
  7. ncbi Dynamic kinetic asymmetric transformation (DYKAT) by combined amine- and transition-metal-catalyzed enantioselective cycloisomerization
    Gui Ling Zhao
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 16:1585-91. 2010
  8. ncbi (S)-selective kinetic resolution and chemoenzymatic dynamic kinetic resolution of secondary alcohols
    Linnéa Borén
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 12:225-32. 2005
  9. ncbi Catalytic enantioselective domino oxa-michael/aldol condensations: asymmetric synthesis of benzopyran derivatives
    Henrik Sundén
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden
    Chemistry 13:574-81. 2007
  10. ncbi The direct catalytic asymmetric mannich reaction
    Armando Córdova
    Arrhenius Laboratory, Department of Organic Chemistry, Stockholm University, SE 10691 Stockholm, Sweden
    Acc Chem Res 37:102-12. 2004

Collaborators

  • Ramon Rios
  • Barbara Nozière
  • Jan E Bäckvall
  • Fahmi Himo
  • Gui Ling Zhao
  • Luca Deiana
  • Ismail Ibrahem
  • Henrik Sundén
  • Jan Vesely
  • Lars Eriksson
  • JESUS CASAS
  • Junliang Sun
  • Pawel Dziedzic
  • Gui-Ling Zhao
  • Linnéa Borén
  • Magnus Engqvist
  • Eric V Johnston
  • Oscar Verho
  • Samson Afewerki
  • Carlos Palo-Nieto
  • Qiong Zhang
  • Farman Ullah
  • Shuangzheng Lin
  • Jonas Hafrén
  • Yongmei Xu
  • Betul Kaynak
  • Belén Martín-Matute

Detail Information

Publications18

  1. ncbi Amino acid catalyzed neogenesis of carbohydrates: a plausible ancient transformation
    Armando Córdova
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, Sweden
    Chemistry 11:4772-84. 2005
    ..The one-pot asymmetric de novo syntheses of deoxy and polyketide carbohydrates involved a novel dynamic kinetic asymmetric transformation (DYKAT) mediated by an amino acid...
  2. ncbi Direct amino acid catalyzed asymmetric synthesis of polyketide sugars
    JESUS CASAS
    Department of Organic Chemistry, Stockholm University, 10691 Stockholm, Sweden
    Angew Chem Int Ed Engl 44:1343-5. 2005
  3. ncbi Direct catalytic enantioselective aza-Diels-Alder reactions
    Henrik Sundén
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Angew Chem Int Ed Engl 44:4877-80. 2005
  4. ncbi Direct amino acid catalyzed asymmetric alpha oxidation of ketones with molecular oxygen
    Henrik Sundén
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, Stockholm, Sweden
    Angew Chem Int Ed Engl 43:6532-5. 2004
  5. ncbi Sugar-assisted kinetic resolution of amino acids and amplification of enantiomeric excess of organic molecules
    Armando Córdova
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 12:5446-51. 2006
    ..This process provides a mechanism in which a racemic mixture of an amino acid can catalyze the formation of an optically active organic molecule in the presence of a sugar product of low enantiomeric excess...
  6. ncbi One-pot catalytic asymmetric cascade synthesis of cycloheptane derivatives
    Jan Vesely
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm Sweden
    Chemistry 14:2693-8. 2008
    ..In this chiral-amine-catalyzed asymmetric process, six new bonds and five new stereocenters were formed with excellent stereocontrol (>25:1 d.r. and 98- >99 ee)...
  7. ncbi Dynamic kinetic asymmetric transformation (DYKAT) by combined amine- and transition-metal-catalyzed enantioselective cycloisomerization
    Gui Ling Zhao
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 16:1585-91. 2010
    ....
  8. ncbi (S)-selective kinetic resolution and chemoenzymatic dynamic kinetic resolution of secondary alcohols
    Linnéa Borén
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 12:225-32. 2005
    ..The DKR process works under very mild reaction conditions to give the corresponding esters in high yields and with excellent enantioselectivities...
  9. ncbi Catalytic enantioselective domino oxa-michael/aldol condensations: asymmetric synthesis of benzopyran derivatives
    Henrik Sundén
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden
    Chemistry 13:574-81. 2007
    ....
  10. ncbi The direct catalytic asymmetric mannich reaction
    Armando Córdova
    Arrhenius Laboratory, Department of Organic Chemistry, Stockholm University, SE 10691 Stockholm, Sweden
    Acc Chem Res 37:102-12. 2004
    ..They also complement each other in syn or anti selectivity of the direct asymmetric Mannich reaction. In this Account, we highlight the recent developments in and contributions to this research...
  11. ncbi Catalytic asymmetric aziridination of α,β-unsaturated aldehydes
    Luca Deiana
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden
    Chemistry 17:7904-17. 2011
    ..The mechanisms and stereochemistry of all these catalytic transformations are also discussed...
  12. ncbi Direct asymmetric intermolecular aldol reactions catalyzed by amino acids and small peptides
    Armando Córdova
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 12:5383-97. 2006
    ..These results suggest that the prebiotic oligomerization of amino acids to peptides may plausibly have been a link in the evolution of the homochirality of sugars. The mechanism and stereochemistry of the reactions are also discussed...
  13. ncbi A kinetic and mechanistic study of the amino acid catalyzed aldol condensation of acetaldehyde in aqueous and salt solutions
    Barbara Nozière
    Department of Meteorology, Stockholm University, SE 106 91 Stockholm, Sweden
    J Phys Chem A 112:2827-37. 2008
    ..Notably, kinetic investigations of the C-C bond-forming addition step would only be possible with high concentrations of amino acids...
  14. ncbi Products and kinetics of the liquid-phase reaction of glyoxal catalyzed by ammonium ions (NH4(+))
    Barbara Nozière
    Department of Applied Environmental Sciences, Stockholm University, SE 106 91 Stockholm, Sweden
    J Phys Chem A 113:231-7. 2009
    ..With these results the reactive uptake of glyoxal on ammonium-containing aerosols was estimated and shown to be a possible explanation for depletion of this compound in Mexico City...
  15. ncbi Examples of catalytic asymmetric amine synthesis using organic catalysts
    Ramon Rios
    Stockholm University, Department of Organic Chemistry, Arrhenius Laboratory, SE 10691 Stockholm, Sweden
    Curr Opin Drug Discov Devel 12:824-47. 2009
    ....
  16. ncbi The direct catalytic asymmetric alpha-aminooxylation reaction: development of stereoselective routes to 1,2-diols and 1,2-amino alcohols and density functional calculations
    Armando Córdova
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 10:3673-84. 2004
    ..The direct catalytic alpha-oxidation is also a novel route for the stereoselective preparation of beta-adrenoreceptor antagonists...
  17. ncbi Heterogeneous "Organoclick" Derivatization of Polysaccharides: Photochemical Thiol-ene Click Modification of Solid Cellulose
    Gui Ling Zhao
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, SE 10691 Stockholm, Sweden
    Macromol Rapid Commun 31:740-4. 2010
    ..The solid cellulose was "organoclick" modified with aryl, alkyl and polyester groups, respectively. The modification allows for a highly modular and metal free surface modification of solid polysaccharides...
  18. ncbi Highly enantioselective cascade transformations by merging heterogeneous transition metal catalysis with asymmetric aminocatalysis
    Luca Deiana
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, Stockholm, Sweden
    Sci Rep 2:851. 2012
    ....