Armando Córdova

Summary

Affiliation: Stockholm University
Country: Sweden

Publications

  1. ncbi request reprint Direct asymmetric intermolecular aldol reactions catalyzed by amino acids and small peptides
    Armando Córdova
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 12:5383-97. 2006
  2. ncbi request reprint Sugar-assisted kinetic resolution of amino acids and amplification of enantiomeric excess of organic molecules
    Armando Córdova
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 12:5446-51. 2006
  3. ncbi request reprint The direct catalytic asymmetric alpha-aminooxylation reaction: development of stereoselective routes to 1,2-diols and 1,2-amino alcohols and density functional calculations
    Armando Córdova
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 10:3673-84. 2004
  4. ncbi request reprint Direct amino acid catalyzed asymmetric synthesis of polyketide sugars
    JESUS CASAS
    Department of Organic Chemistry, Stockholm University, 10691 Stockholm, Sweden
    Angew Chem Int Ed Engl 44:1343-5. 2005
  5. ncbi request reprint Direct catalytic enantioselective aza-Diels-Alder reactions
    Henrik Sundén
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Angew Chem Int Ed Engl 44:4877-80. 2005
  6. ncbi request reprint Direct amino acid catalyzed asymmetric alpha oxidation of ketones with molecular oxygen
    Henrik Sundén
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, Stockholm, Sweden
    Angew Chem Int Ed Engl 43:6532-5. 2004
  7. doi request reprint One-pot catalytic asymmetric cascade synthesis of cycloheptane derivatives
    Jan Vesely
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm Sweden
    Chemistry 14:2693-8. 2008
  8. doi request reprint Dynamic kinetic asymmetric transformation (DYKAT) by combined amine- and transition-metal-catalyzed enantioselective cycloisomerization
    Gui Ling Zhao
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 16:1585-91. 2010
  9. ncbi request reprint (S)-selective kinetic resolution and chemoenzymatic dynamic kinetic resolution of secondary alcohols
    Linnéa Borén
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 12:225-32. 2005
  10. ncbi request reprint Catalytic enantioselective domino oxa-michael/aldol condensations: asymmetric synthesis of benzopyran derivatives
    Henrik Sundén
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden
    Chemistry 13:574-81. 2007

Collaborators

  • Barbara Nozière
  • Ramon Rios
  • Jan E Bäckvall
  • Fahmi Himo
  • Arianna Bassan
  • Ismail Ibrahem
  • Gui Ling Zhao
  • Luca Deiana
  • Henrik Sundén
  • Pawel Dziedzic
  • Jan Vesely
  • Lars Eriksson
  • Magnus Engqvist
  • JESUS CASAS
  • Junliang Sun
  • Jonas Hafrén
  • Weibiao Zou
  • Linnéa Borén
  • Yongmei Xu
  • Carlos Palo-Nieto
  • Oscar Verho
  • Eric V Johnston
  • Samson Afewerki
  • Qiong Zhang
  • Farman Ullah
  • Shuangzheng Lin
  • Belén Martín-Matute
  • Betul Kaynak

Detail Information

Publications22

  1. ncbi request reprint Direct asymmetric intermolecular aldol reactions catalyzed by amino acids and small peptides
    Armando Córdova
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 12:5383-97. 2006
    ..These results suggest that the prebiotic oligomerization of amino acids to peptides may plausibly have been a link in the evolution of the homochirality of sugars. The mechanism and stereochemistry of the reactions are also discussed...
  2. ncbi request reprint Sugar-assisted kinetic resolution of amino acids and amplification of enantiomeric excess of organic molecules
    Armando Córdova
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 12:5446-51. 2006
    ..This process provides a mechanism in which a racemic mixture of an amino acid can catalyze the formation of an optically active organic molecule in the presence of a sugar product of low enantiomeric excess...
  3. ncbi request reprint The direct catalytic asymmetric alpha-aminooxylation reaction: development of stereoselective routes to 1,2-diols and 1,2-amino alcohols and density functional calculations
    Armando Córdova
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 10:3673-84. 2004
    ..The direct catalytic alpha-oxidation is also a novel route for the stereoselective preparation of beta-adrenoreceptor antagonists...
  4. ncbi request reprint Direct amino acid catalyzed asymmetric synthesis of polyketide sugars
    JESUS CASAS
    Department of Organic Chemistry, Stockholm University, 10691 Stockholm, Sweden
    Angew Chem Int Ed Engl 44:1343-5. 2005
  5. ncbi request reprint Direct catalytic enantioselective aza-Diels-Alder reactions
    Henrik Sundén
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Angew Chem Int Ed Engl 44:4877-80. 2005
  6. ncbi request reprint Direct amino acid catalyzed asymmetric alpha oxidation of ketones with molecular oxygen
    Henrik Sundén
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, Stockholm, Sweden
    Angew Chem Int Ed Engl 43:6532-5. 2004
  7. doi request reprint One-pot catalytic asymmetric cascade synthesis of cycloheptane derivatives
    Jan Vesely
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm Sweden
    Chemistry 14:2693-8. 2008
    ..In this chiral-amine-catalyzed asymmetric process, six new bonds and five new stereocenters were formed with excellent stereocontrol (>25:1 d.r. and 98- >99 ee)...
  8. doi request reprint Dynamic kinetic asymmetric transformation (DYKAT) by combined amine- and transition-metal-catalyzed enantioselective cycloisomerization
    Gui Ling Zhao
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 16:1585-91. 2010
    ....
  9. ncbi request reprint (S)-selective kinetic resolution and chemoenzymatic dynamic kinetic resolution of secondary alcohols
    Linnéa Borén
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 12:225-32. 2005
    ..The DKR process works under very mild reaction conditions to give the corresponding esters in high yields and with excellent enantioselectivities...
  10. ncbi request reprint Catalytic enantioselective domino oxa-michael/aldol condensations: asymmetric synthesis of benzopyran derivatives
    Henrik Sundén
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden
    Chemistry 13:574-81. 2007
    ....
  11. ncbi request reprint The direct catalytic asymmetric mannich reaction
    Armando Córdova
    Arrhenius Laboratory, Department of Organic Chemistry, Stockholm University, SE 10691 Stockholm, Sweden
    Acc Chem Res 37:102-12. 2004
    ..They also complement each other in syn or anti selectivity of the direct asymmetric Mannich reaction. In this Account, we highlight the recent developments in and contributions to this research...
  12. doi request reprint Catalytic asymmetric aziridination of α,β-unsaturated aldehydes
    Luca Deiana
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden
    Chemistry 17:7904-17. 2011
    ..The mechanisms and stereochemistry of all these catalytic transformations are also discussed...
  13. doi request reprint A kinetic and mechanistic study of the amino acid catalyzed aldol condensation of acetaldehyde in aqueous and salt solutions
    Barbara Nozière
    Department of Meteorology, Stockholm University, SE 106 91 Stockholm, Sweden
    J Phys Chem A 112:2827-37. 2008
    ..Notably, kinetic investigations of the C-C bond-forming addition step would only be possible with high concentrations of amino acids...
  14. doi request reprint Products and kinetics of the liquid-phase reaction of glyoxal catalyzed by ammonium ions (NH4(+))
    Barbara Nozière
    Department of Applied Environmental Sciences, Stockholm University, SE 106 91 Stockholm, Sweden
    J Phys Chem A 113:231-7. 2009
    ..With these results the reactive uptake of glyoxal on ammonium-containing aerosols was estimated and shown to be a possible explanation for depletion of this compound in Mexico City...
  15. ncbi request reprint Amino acid catalyzed neogenesis of carbohydrates: a plausible ancient transformation
    Armando Córdova
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, Sweden
    Chemistry 11:4772-84. 2005
    ..The one-pot asymmetric de novo syntheses of deoxy and polyketide carbohydrates involved a novel dynamic kinetic asymmetric transformation (DYKAT) mediated by an amino acid...
  16. ncbi request reprint Examples of catalytic asymmetric amine synthesis using organic catalysts
    Ramon Rios
    Stockholm University, Department of Organic Chemistry, Arrhenius Laboratory, SE 10691 Stockholm, Sweden
    Curr Opin Drug Discov Devel 12:824-47. 2009
    ....
  17. ncbi request reprint The origin of stereoselectivity in primary amino acid catalyzed intermolecular aldol reactions
    Arianna Bassan
    Stockholm University, Department of Physics, AlbaNova, 106 91 Stockholm, Sweden
    Angew Chem Int Ed Engl 44:7028-32. 2005
  18. ncbi request reprint Acyclic chiral amines and amino acids as inexpensive and readily tunable catalysts for the direct asymmetric three-component Mannich reaction
    Ismail Ibrahem
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden
    Chemistry 11:7024-9. 2005
    ....
  19. ncbi request reprint The small peptide-catalyzed direct asymmetric aldol reaction in water
    Pawel Dziedzic
    Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Sweden
    Org Biomol Chem 4:38-40. 2006
    ....
  20. ncbi request reprint Inorganic ammonium salts and carbonate salts are efficient catalysts for aldol condensation in atmospheric aerosols
    Barbara Nozière
    Department of Applied Environmental Science, Svante Arrhenius väg 8C, 106 91 Stockholm, Sweden
    Phys Chem Chem Phys 12:3864-72. 2010
    ....
  21. doi request reprint Heterogeneous "Organoclick" Derivatization of Polysaccharides: Photochemical Thiol-ene Click Modification of Solid Cellulose
    Gui Ling Zhao
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, SE 10691 Stockholm, Sweden
    Macromol Rapid Commun 31:740-4. 2010
    ..The solid cellulose was "organoclick" modified with aryl, alkyl and polyester groups, respectively. The modification allows for a highly modular and metal free surface modification of solid polysaccharides...
  22. pmc Highly enantioselective cascade transformations by merging heterogeneous transition metal catalysis with asymmetric aminocatalysis
    Luca Deiana
    Department of Organic Chemistry, The Arrhenius Laboratory, Stockholm University, Stockholm, Sweden
    Sci Rep 2:851. 2012
    ....