David Cantillo

Summary

Affiliation: University of Extremadura
Country: Spain

Publications

  1. ncbi On the prebiotic synthesis of D-sugars catalyzed by L-peptides: assessments from first-principles calculations
    David Cantillo
    Department of Organic and Inorganic Chemistry, University of Extremadura, Avda de Elvas s n, 06006 Badajoz, Spain
    Chemistry 18:8795-9. 2012
  2. ncbi Thionation of mesoionics with isothiocyanates: evidence supporting a four-step domino process and ruling out a [2 + 2] mechanism
    David Cantillo
    , QUOREX Research Group, Facultad de Ciencias, Universidad de Extremadura, E 06071 Badajoz, Spain
    J Org Chem 74:3698-705. 2009
  3. ncbi Dissecting competitive mechanisms: thionation vs. cycloaddition in the reaction of thioisomunchnones with isothiocyanates under microwave irradiation
    David Cantillo
    Departamento de Quimica Organica e Inorganica, QUOREX Research Group, Facultad de Ciencias, Universidad de Extremadura, E 06071 Badajoz, Spain
    J Org Chem 74:7644-50. 2009
  4. ncbi Push-pull 1,3-thiazolium-5-thiolates. Formation via concerted and stepwise pathways, and theoretical evaluation of NLO properties
    David Cantillo
    Departamento de Quimica Organica e Inorganica, QUOREX Research Group, Facultad de Ciencias, Universidad de Extremadura, E 06006, Badajoz, Spain
    Org Biomol Chem 8:5367-74. 2010
  5. ncbi Assessing the whole range of CuAAC mechanisms by DFT calculations--on the intermediacy of copper acetylides
    David Cantillo
    Departamento de Quimica Organica e Inorganica, QUOREX Research Group, Facultad de Ciencias, Universidad de Extremadura, E 06006, Badajoz, Spain
    Org Biomol Chem 9:2952-8. 2011
  6. ncbi On the enhanced reactivity and selectivity of triazole formation in molecular flasks. A theoretical rationale
    David Cantillo
    Departamento de Quimica Organica e Inorganica, QUOREX Research Group, Facultad de Ciencias, Universidad de Extremadura, E 06006 Badajoz, Spain
    Org Biomol Chem 9:7638-42. 2011

Detail Information

Publications6

  1. ncbi On the prebiotic synthesis of D-sugars catalyzed by L-peptides: assessments from first-principles calculations
    David Cantillo
    Department of Organic and Inorganic Chemistry, University of Extremadura, Avda de Elvas s n, 06006 Badajoz, Spain
    Chemistry 18:8795-9. 2012
    ....
  2. ncbi Thionation of mesoionics with isothiocyanates: evidence supporting a four-step domino process and ruling out a [2 + 2] mechanism
    David Cantillo
    , QUOREX Research Group, Facultad de Ciencias, Universidad de Extremadura, E 06071 Badajoz, Spain
    J Org Chem 74:3698-705. 2009
    ..The mechanistic hypothesis has further been corroborated by an experiment with isotopically (13)C-labeled PhNCS that unambiguously shows the way in which the exchange reaction occurs...
  3. ncbi Dissecting competitive mechanisms: thionation vs. cycloaddition in the reaction of thioisomunchnones with isothiocyanates under microwave irradiation
    David Cantillo
    Departamento de Quimica Organica e Inorganica, QUOREX Research Group, Facultad de Ciencias, Universidad de Extremadura, E 06071 Badajoz, Spain
    J Org Chem 74:7644-50. 2009
    ..The protocol is quite simple and should convince many organic chemists that certain daunting theoretical treatments can be made easy...
  4. ncbi Push-pull 1,3-thiazolium-5-thiolates. Formation via concerted and stepwise pathways, and theoretical evaluation of NLO properties
    David Cantillo
    Departamento de Quimica Organica e Inorganica, QUOREX Research Group, Facultad de Ciencias, Universidad de Extremadura, E 06006, Badajoz, Spain
    Org Biomol Chem 8:5367-74. 2010
    ....
  5. ncbi Assessing the whole range of CuAAC mechanisms by DFT calculations--on the intermediacy of copper acetylides
    David Cantillo
    Departamento de Quimica Organica e Inorganica, QUOREX Research Group, Facultad de Ciencias, Universidad de Extremadura, E 06006, Badajoz, Spain
    Org Biomol Chem 9:2952-8. 2011
    ..The total proton/deuterium exchange in the afforded triazole demonstrates the formation of a copper acetylide intermediate during the transformation...
  6. ncbi On the enhanced reactivity and selectivity of triazole formation in molecular flasks. A theoretical rationale
    David Cantillo
    Departamento de Quimica Organica e Inorganica, QUOREX Research Group, Facultad de Ciencias, Universidad de Extremadura, E 06006 Badajoz, Spain
    Org Biomol Chem 9:7638-42. 2011
    ....