Enric Brillas

Summary

Affiliation: Universitat de Barcelona
Country: Spain

Publications

  1. ncbi request reprint Aniline degradation by Electro-Fenton and peroxi-coagulation processes using a flow reactor for wastewater treatment
    Enric Brillas
    Laboratori de Ciència i Tecnologia Electroquímica de Materials, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Spain
    Chemosphere 47:241-8. 2002
  2. ncbi request reprint Electrochemical degradation of chlorophenoxy and chlorobenzoic herbicides in acidic aqueous medium by the peroxi-coagulation method
    Enric Brillas
    Laboratori de Ciència i Tecnologia Electroquímica de Materials LCTEM, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 51:227-35. 2003
  3. doi request reprint Degradation of pharmaceutical beta-blockers by electrochemical advanced oxidation processes using a flow plant with a solar compound parabolic collector
    Eloy Isarain-Chávez
    Laboratori d Electroquímica de Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Water Res 45:4119-30. 2011
  4. doi request reprint Mineralization of metoprolol by electro-Fenton and photoelectro-Fenton processes
    Eloy Isarain-Chávez
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Phys Chem A 115:1234-42. 2011
  5. doi request reprint Electro-fenton and photoelectro-fenton degradation of sulfanilic acid using a boron-doped diamond anode and an air diffusion cathode
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Universitat de Barcelona, Spain
    J Phys Chem A 116:3404-12. 2012
  6. ncbi request reprint Mineralization of salicylic acid in acidic aqueous medium by electrochemical advanced oxidation processes using platinum and boron-doped diamond as anode and cathodically generated hydrogen peroxide
    Elena Guinea
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Water Res 42:499-511. 2008
  7. doi request reprint Electrochemical incineration of diclofenac in neutral aqueous medium by anodic oxidation using Pt and boron-doped diamond anodes
    Enric Brillas
    Laboratori d Electroquímica de Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 79:605-12. 2010
  8. ncbi request reprint Degradation of clofibric acid in acidic aqueous medium by electro-Fenton and photoelectro-Fenton
    Ignasi Sirés
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 66:1660-9. 2007
  9. ncbi request reprint Degradation of the herbicide 2,4-DP by anodic oxidation, electro-Fenton and photoelectro-Fenton using platinum and boron-doped diamond anodes
    Enric Brillas
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 68:199-209. 2007
  10. doi request reprint Mineralization of flumequine in acidic medium by electro-Fenton and photoelectro-Fenton processes
    Sergi Garcia-Segura
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Water Res 46:2067-76. 2012

Collaborators

  • Juan Casado
  • Luis Julia
  • Manuel A Rodrigo
  • Carlos A Martínez-Huitle
  • Onofrio Scialdone
  • Conchita Arias
  • Francesc Centellas
  • Rosa Maria Rodriguez
  • José Antonio Garrido
  • Pere Lluís Cabot
  • Abdellatif El-Ghenymy
  • Sergi Garcia-Segura
  • Eloy Isarain-Chávez
  • Ignasi Sirés
  • Elena Guinea
  • Cristina Flox
  • Sonia Castellanos
  • Dolores Velasco
  • Serena Randazzo
  • Marcel Skoumal
  • Francisco López-Calahorra
  • Birame Boye
  • Rosa M Rodríguez
  • Ben Ali Abdelouahid
  • Jose A Garrido
  • Pere L Cabot
  • Mohamed Soussi El Begrani
  • Nerilso Bocchi
  • Lucio Cesar Almeida
  • Pablo Cañizares
  • André Savall
  • Karine Groenen-Serrano
  • Cristina Sáez
  • Marc Lopez
  • Momar M Dieng

Detail Information

Publications27

  1. ncbi request reprint Aniline degradation by Electro-Fenton and peroxi-coagulation processes using a flow reactor for wastewater treatment
    Enric Brillas
    Laboratori de Ciència i Tecnologia Electroquímica de Materials, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Spain
    Chemosphere 47:241-8. 2002
    ..Both advanced electrochemical oxidation processes (AEOPs) show moderate energy costs, which increase with increasing electrolysis time and applied current...
  2. ncbi request reprint Electrochemical degradation of chlorophenoxy and chlorobenzoic herbicides in acidic aqueous medium by the peroxi-coagulation method
    Enric Brillas
    Laboratori de Ciència i Tecnologia Electroquímica de Materials LCTEM, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 51:227-35. 2003
    ..The decay of all herbicides follows a pseudo-first-order reaction, with a similar constant rate for 4-CPA, MCPA, 2,4-D and 2,4,5-T, and a higher value for dicamba...
  3. doi request reprint Degradation of pharmaceutical beta-blockers by electrochemical advanced oxidation processes using a flow plant with a solar compound parabolic collector
    Eloy Isarain-Chávez
    Laboratori d Electroquímica de Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Water Res 45:4119-30. 2011
    ..NO₃⁻ was the predominant inorganic ion lost in EF, whereas the SPEF process favored the production of NH₄⁺ ion and volatile N-derivatives...
  4. doi request reprint Mineralization of metoprolol by electro-Fenton and photoelectro-Fenton processes
    Eloy Isarain-Chávez
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Phys Chem A 115:1234-42. 2011
    ..NH(4)(+) ion and to a lesser extent NO(3)(-) ion were released in all treatments, being quantified by ionic chromatography...
  5. doi request reprint Electro-fenton and photoelectro-fenton degradation of sulfanilic acid using a boron-doped diamond anode and an air diffusion cathode
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Universitat de Barcelona, Spain
    J Phys Chem A 116:3404-12. 2012
    ..NH(4)(+) ion was preferentially released in both treatments, along with NO(3)(-) ion in smaller proportion...
  6. ncbi request reprint Mineralization of salicylic acid in acidic aqueous medium by electrochemical advanced oxidation processes using platinum and boron-doped diamond as anode and cathodically generated hydrogen peroxide
    Elena Guinea
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Water Res 42:499-511. 2008
    ..A general reaction sequence for salicylic acid mineralization considering all these intermediates is proposed...
  7. doi request reprint Electrochemical incineration of diclofenac in neutral aqueous medium by anodic oxidation using Pt and boron-doped diamond anodes
    Enric Brillas
    Laboratori d Electroquímica de Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 79:605-12. 2010
    ..The process involves the formation of different N-derivatives that slowly release NH4+ and NO3(-) ions. Chloride ion is lost in all cases...
  8. ncbi request reprint Degradation of clofibric acid in acidic aqueous medium by electro-Fenton and photoelectro-Fenton
    Ignasi Sirés
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 66:1660-9. 2007
    ..The ultimate product is oxalic acid, which forms very stable Fe(3+)-oxalato complexes under electro-Fenton conditions. These complexes are efficiently photodecarboxylated in photoelectro-Fenton under the action of UVA light...
  9. ncbi request reprint Degradation of the herbicide 2,4-DP by anodic oxidation, electro-Fenton and photoelectro-Fenton using platinum and boron-doped diamond anodes
    Enric Brillas
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 68:199-209. 2007
    ..A general sequence accounting for by the reaction of all these intermediates with the different oxidizing agents is proposed...
  10. doi request reprint Mineralization of flumequine in acidic medium by electro-Fenton and photoelectro-Fenton processes
    Sergi Garcia-Segura
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Water Res 46:2067-76. 2012
    ..The release of inorganic ions such as F(-), NO(3)(-) and in lesser extent NH(4)(+) was followed by ionic chromatography...
  11. doi request reprint Mineralization of the biocide chloroxylenol by electrochemical advanced oxidation processes
    Marcel Skoumal
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 71:1718-29. 2008
    ..A general pathway for chloroxylenol mineralization by all EAOPs including the above by-products is proposed...
  12. doi request reprint Taking advantage of the radical character of tris(2,4,6-trichlorophenyl)methyl to synthesize new paramagnetic glassy molecular materials
    Sonia Castellanos
    Departament de Quimica Organica, Institut de Nanociències I Nanotecnologia, Universitat de Barcelona, Barcelona, Spain
    J Org Chem 73:3759-67. 2008
    ..These radical adducts have luminescent properties covering the red spectral band of the emission with high intensities...
  13. doi request reprint Electro-Fenton and photoelectro-Fenton degradations of the drug beta-blocker propranolol using a Pt anode: identification and evolution of oxidation products
    Eloy Isarain-Chávez
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Hazard Mater 185:1228-35. 2011
    ..While chloride ion remains stable, NH(4)(+) and NO(3)(-) ions are released to the medium. A reaction sequence for propranolol hydrochloride mineralization is proposed...
  14. doi request reprint Electrochemical incineration of sulfanilic acid at a boron-doped diamond anode
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 87:1126-33. 2012
    ..Ionic chromatographic analysis of electrolyzed solutions revealed that the N content of sulfanilic acid was mainly released as NH(4)(+) ion and in much smaller proportion as NO(3)(-) ion...
  15. doi request reprint Oxidation of enrofloxacin with conductive-diamond electrochemical oxidation, ozonation and Fenton oxidation: a comparison
    Elena Guinea
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Barcelona, Spain
    Water Res 43:2131-8. 2009
    ..Ammonium ions were the primary product species in CDEO and nitrate ions in ozonation, whereas Fenton effluents contained similar amounts of both nitrogen ionic species...
  16. ncbi request reprint Electrochemical combustion of herbicide mecoprop in aqueous medium using a flow reactor with a boron-doped diamond anode
    Cristina Flox
    Laboratori de Ciència i Tecnologia Electroquímica de Materials LCTEM, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 64:892-902. 2006
    ..The initial chlorine is completely released in the form of chloride ion, which is slowly oxidized to Cl2 at the BDD anode. A reaction pathway for MCPP mineralization involving all products detected is proposed...
  17. doi request reprint Optimization of the electro-Fenton and solar photoelectro-Fenton treatments of sulfanilic acid solutions using a pre-pilot flow plant by response surface methodology
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Hazard Mater 221:288-97. 2012
    ..The quick photolysis of these complexes by UV light of sunlight explains the higher oxidation power of SPEF. NH(4)(+) was the main inorganic nitrogen ion released in both processes...
  18. doi request reprint Electrochemical incineration of cresols: a comparative study between PbO2 and boron-doped diamond anodes
    Cristina Flox
    Departament de Quimica Fisica, Facultat de Quimica, Laboratori d Electroquímica dels Materials i del Medi Ambient, Universitat de Barcelona, Marti i Franques 1 11, Barcelona, Spain
    Chemosphere 74:1340-7. 2009
    ..From these oxidation by-products, a plausible reaction sequence for m-cresol mineralization on both anodes is proposed. The energy consumption for the corresponding electrochemical process is also calculated...
  19. doi request reprint Mineralization of sulfanilamide by electro-Fenton and solar photoelectro-Fenton in a pre-pilot plant with a Pt/air-diffusion cell
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 91:1324-31. 2013
    ..The N content of sulfanilamide was mainly mineralized as NH₄⁺ ion and in much lesser extent as NO₃⁻ ion, whereas most of its initial S was converted into SO₄²⁻ ion...
  20. doi request reprint Mineralization of the recalcitrant oxalic and oxamic acids by electrochemical advanced oxidation processes using a boron-doped diamond anode
    Sergi Garcia-Segura
    Laboratori d Electroquímica de Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Barcelona, Spain
    Water Res 45:2975-84. 2011
    ..Low current densities and Fe(2+) contents are preferable to remove more efficiently these acids by the most potent AO-BDD-Fe(2+)-UVA method...
  21. doi request reprint Solar photoelectro-Fenton degradation of the herbicide 4-chloro-2-methylphenoxyacetic acid optimized by response surface methodology
    Sergi Garcia-Segura
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Hazard Mater 194:109-18. 2011
    ..A reaction sequence for the SPEF degradation of MCPA was proposed...
  22. doi request reprint Remediation of water pollution caused by pharmaceutical residues based on electrochemical separation and degradation technologies: a review
    Ignasi Sirés
    Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Barcelona, Spain
    Environ Int 40:212-29. 2012
    ..The routes for the degradation of the some pharmaceuticals are also presented...
  23. ncbi request reprint Mineralization of paracetamol in aqueous medium by anodic oxidation with a boron-doped diamond electrode
    Enric Brillas
    Laboratori de Ciència i Tecnologia Electroquímica de Materials, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 58:399-406. 2005
    ..Paracetamol can be completely destroyed with Pt and its kinetics follows a pseudo-first-order reaction with a constant rate independent of pH...
  24. ncbi request reprint Degradation of herbicide 4-chlorophenoxyacetic acid by advanced electrochemical oxidation methods
    Birame Boye
    Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Spain
    Environ Sci Technol 36:3030-5. 2002
    ..The highest mineralization rate found for photoelectro-Fenton is accounted for by the fast photodecomposition of complexes of Fe3+ with such short-chain acids, mainly oxalic acid, under the action of UV light...
  25. doi request reprint Comparative electrochemical treatments of two chlorinated aliphatic hydrocarbons. Time course of the main reaction by-products
    Serena Randazzo
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Hazard Mater 192:1555-64. 2011
    ..Chlorine was released as Cl(-), being further oxidized to ClO(3)(-) and, mostly, to ClO(4)(-), due to the action of the largely generated BDD(OH) and OH...
  26. ncbi request reprint Red organic light-emitting radical adducts of carbazole and tris(2,4,6-trichlorotriphenyl)methyl radical that exhibit high thermal stability and electrochemical amphotericity
    Dolores Velasco
    Departament de Quimica Organica, Institut de Nanociències I Nanotecnologia, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Org Chem 72:7523-32. 2007
    ..On the other hand, the EPR parameters of these radical adducts show an imperceptible variation with the substituents in the carbazole...
  27. doi request reprint Electrochemical alternatives for drinking water disinfection
    Carlos A Martínez-Huitle
    DISTAM, Università degli Studi di Milano via Celoria 2, CAP 20133 Milan, Italy
    Angew Chem Int Ed Engl 47:1998-2005. 2008
    ..This article reviews electrochemical systems that can contribute to drinking water disinfection and underscores the efficiency of recently developed diamond films in chlorine-free electrochemical systems...