Enric Brillas

Summary

Affiliation: Universitat de Barcelona
Country: Spain

Publications

  1. ncbi Aniline degradation by Electro-Fenton and peroxi-coagulation processes using a flow reactor for wastewater treatment
    Enric Brillas
    Laboratori de Ciència i Tecnologia Electroquímica de Materials, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Spain
    Chemosphere 47:241-8. 2002
  2. ncbi Electrochemical degradation of chlorophenoxy and chlorobenzoic herbicides in acidic aqueous medium by the peroxi-coagulation method
    Enric Brillas
    Laboratori de Ciència i Tecnologia Electroquímica de Materials LCTEM, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 51:227-35. 2003
  3. doi Degradation of pharmaceutical beta-blockers by electrochemical advanced oxidation processes using a flow plant with a solar compound parabolic collector
    Eloy Isarain-Chávez
    Laboratori d Electroquímica de Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Water Res 45:4119-30. 2011
  4. doi Mineralization of sulfanilamide by electro-Fenton and solar photoelectro-Fenton in a pre-pilot plant with a Pt/air-diffusion cell
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 91:1324-31. 2013
  5. doi Mineralization of metoprolol by electro-Fenton and photoelectro-Fenton processes
    Eloy Isarain-Chávez
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Phys Chem A 115:1234-42. 2011
  6. doi Electro-fenton and photoelectro-fenton degradation of sulfanilic acid using a boron-doped diamond anode and an air diffusion cathode
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Universitat de Barcelona, Spain
    J Phys Chem A 116:3404-12. 2012
  7. ncbi Mineralization of salicylic acid in acidic aqueous medium by electrochemical advanced oxidation processes using platinum and boron-doped diamond as anode and cathodically generated hydrogen peroxide
    Elena Guinea
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Water Res 42:499-511. 2008
  8. doi Electrochemical incineration of diclofenac in neutral aqueous medium by anodic oxidation using Pt and boron-doped diamond anodes
    Enric Brillas
    Laboratori d Electroquímica de Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 79:605-12. 2010
  9. ncbi Degradation of clofibric acid in acidic aqueous medium by electro-Fenton and photoelectro-Fenton
    Ignasi Sirés
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 66:1660-9. 2007
  10. ncbi Electrochemical combustion of herbicide mecoprop in aqueous medium using a flow reactor with a boron-doped diamond anode
    Cristina Flox
    Laboratori de Ciència i Tecnologia Electroquímica de Materials LCTEM, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 64:892-902. 2006

Collaborators

  • Juan Casado
  • Manuel A Rodrigo
  • Luis Julia
  • Marco Panizza
  • Carlos A Martínez-Huitle
  • Onofrio Scialdone
  • Rosa Maria Rodriguez
  • Conchita Arias
  • Francesc Centellas
  • Abdellatif El-Ghenymy
  • José Antonio Garrido
  • Pere Lluís Cabot
  • Ignasi Sirés
  • Sergi Garcia-Segura
  • Eloy Isarain-Chávez
  • Elena Guinea
  • Cristina Flox
  • Sonia Castellanos
  • Dolores Velasco
  • Mehmet A Oturan
  • Angelo R F Pipi
  • Serena Randazzo
  • Marcel Skoumal
  • Francisco López-Calahorra
  • Birame Boye
  • Adalgisa R de Andrade
  • Nihal Oturan
  • Pere L Cabot
  • Mohamed Soussi El Begrani
  • Rosa M Rodríguez
  • Ben Ali Abdelouahid
  • Jose A Garrido
  • Lucio Cesar Almeida
  • Nerilso Bocchi
  • Pablo Cañizares
  • André Savall
  • Karine Groenen-Serrano
  • Cristina Sáez
  • Marc Lopez
  • Momar M Dieng

Detail Information

Publications30

  1. ncbi Aniline degradation by Electro-Fenton and peroxi-coagulation processes using a flow reactor for wastewater treatment
    Enric Brillas
    Laboratori de Ciència i Tecnologia Electroquímica de Materials, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Spain
    Chemosphere 47:241-8. 2002
    ..Both advanced electrochemical oxidation processes (AEOPs) show moderate energy costs, which increase with increasing electrolysis time and applied current...
  2. ncbi Electrochemical degradation of chlorophenoxy and chlorobenzoic herbicides in acidic aqueous medium by the peroxi-coagulation method
    Enric Brillas
    Laboratori de Ciència i Tecnologia Electroquímica de Materials LCTEM, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 51:227-35. 2003
    ..The decay of all herbicides follows a pseudo-first-order reaction, with a similar constant rate for 4-CPA, MCPA, 2,4-D and 2,4,5-T, and a higher value for dicamba...
  3. doi Degradation of pharmaceutical beta-blockers by electrochemical advanced oxidation processes using a flow plant with a solar compound parabolic collector
    Eloy Isarain-Chávez
    Laboratori d Electroquímica de Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Water Res 45:4119-30. 2011
    ..NO₃⁻ was the predominant inorganic ion lost in EF, whereas the SPEF process favored the production of NH₄⁺ ion and volatile N-derivatives...
  4. doi Mineralization of sulfanilamide by electro-Fenton and solar photoelectro-Fenton in a pre-pilot plant with a Pt/air-diffusion cell
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 91:1324-31. 2013
    ..The N content of sulfanilamide was mainly mineralized as NH₄⁺ ion and in much lesser extent as NO₃⁻ ion, whereas most of its initial S was converted into SO₄²⁻ ion...
  5. doi Mineralization of metoprolol by electro-Fenton and photoelectro-Fenton processes
    Eloy Isarain-Chávez
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Phys Chem A 115:1234-42. 2011
    ..NH(4)(+) ion and to a lesser extent NO(3)(-) ion were released in all treatments, being quantified by ionic chromatography...
  6. doi Electro-fenton and photoelectro-fenton degradation of sulfanilic acid using a boron-doped diamond anode and an air diffusion cathode
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Universitat de Barcelona, Spain
    J Phys Chem A 116:3404-12. 2012
    ..NH(4)(+) ion was preferentially released in both treatments, along with NO(3)(-) ion in smaller proportion...
  7. ncbi Mineralization of salicylic acid in acidic aqueous medium by electrochemical advanced oxidation processes using platinum and boron-doped diamond as anode and cathodically generated hydrogen peroxide
    Elena Guinea
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Water Res 42:499-511. 2008
    ..A general reaction sequence for salicylic acid mineralization considering all these intermediates is proposed...
  8. doi Electrochemical incineration of diclofenac in neutral aqueous medium by anodic oxidation using Pt and boron-doped diamond anodes
    Enric Brillas
    Laboratori d Electroquímica de Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 79:605-12. 2010
    ..The process involves the formation of different N-derivatives that slowly release NH4+ and NO3(-) ions. Chloride ion is lost in all cases...
  9. ncbi Degradation of clofibric acid in acidic aqueous medium by electro-Fenton and photoelectro-Fenton
    Ignasi Sirés
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 66:1660-9. 2007
    ..The ultimate product is oxalic acid, which forms very stable Fe(3+)-oxalato complexes under electro-Fenton conditions. These complexes are efficiently photodecarboxylated in photoelectro-Fenton under the action of UVA light...
  10. ncbi Electrochemical combustion of herbicide mecoprop in aqueous medium using a flow reactor with a boron-doped diamond anode
    Cristina Flox
    Laboratori de Ciència i Tecnologia Electroquímica de Materials LCTEM, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 64:892-902. 2006
    ..The initial chlorine is completely released in the form of chloride ion, which is slowly oxidized to Cl2 at the BDD anode. A reaction pathway for MCPP mineralization involving all products detected is proposed...
  11. ncbi Degradation of the herbicide 2,4-DP by anodic oxidation, electro-Fenton and photoelectro-Fenton using platinum and boron-doped diamond anodes
    Enric Brillas
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 68:199-209. 2007
    ..A general sequence accounting for by the reaction of all these intermediates with the different oxidizing agents is proposed...
  12. doi Mineralization of flumequine in acidic medium by electro-Fenton and photoelectro-Fenton processes
    Sergi Garcia-Segura
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Water Res 46:2067-76. 2012
    ..The release of inorganic ions such as F(-), NO(3)(-) and in lesser extent NH(4)(+) was followed by ionic chromatography...
  13. doi Electro-Fenton and photoelectro-Fenton degradations of the drug beta-blocker propranolol using a Pt anode: identification and evolution of oxidation products
    Eloy Isarain-Chávez
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Hazard Mater 185:1228-35. 2011
    ..While chloride ion remains stable, NH(4)(+) and NO(3)(-) ions are released to the medium. A reaction sequence for propranolol hydrochloride mineralization is proposed...
  14. doi Taking advantage of the radical character of tris(2,4,6-trichlorophenyl)methyl to synthesize new paramagnetic glassy molecular materials
    Sonia Castellanos
    Departament de Quimica Organica, Institut de Nanociències I Nanotecnologia, Universitat de Barcelona, Barcelona, Spain
    J Org Chem 73:3759-67. 2008
    ..These radical adducts have luminescent properties covering the red spectral band of the emission with high intensities...
  15. doi Mineralization of the biocide chloroxylenol by electrochemical advanced oxidation processes
    Marcel Skoumal
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 71:1718-29. 2008
    ..A general pathway for chloroxylenol mineralization by all EAOPs including the above by-products is proposed...
  16. doi Electrochemical incineration of sulfanilic acid at a boron-doped diamond anode
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 87:1126-33. 2012
    ..Ionic chromatographic analysis of electrolyzed solutions revealed that the N content of sulfanilic acid was mainly released as NH(4)(+) ion and in much smaller proportion as NO(3)(-) ion...
  17. doi Oxidation of enrofloxacin with conductive-diamond electrochemical oxidation, ozonation and Fenton oxidation: a comparison
    Elena Guinea
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Barcelona, Spain
    Water Res 43:2131-8. 2009
    ..Ammonium ions were the primary product species in CDEO and nitrate ions in ozonation, whereas Fenton effluents contained similar amounts of both nitrogen ionic species...
  18. doi Optimization of the electro-Fenton and solar photoelectro-Fenton treatments of sulfanilic acid solutions using a pre-pilot flow plant by response surface methodology
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Hazard Mater 221:288-97. 2012
    ..The quick photolysis of these complexes by UV light of sunlight explains the higher oxidation power of SPEF. NH(4)(+) was the main inorganic nitrogen ion released in both processes...
  19. doi Electrochemical incineration of cresols: a comparative study between PbO2 and boron-doped diamond anodes
    Cristina Flox
    Departament de Quimica Fisica, Facultat de Quimica, Laboratori d Electroquímica dels Materials i del Medi Ambient, Universitat de Barcelona, Marti i Franques 1 11, Barcelona, Spain
    Chemosphere 74:1340-7. 2009
    ..From these oxidation by-products, a plausible reaction sequence for m-cresol mineralization on both anodes is proposed. The energy consumption for the corresponding electrochemical process is also calculated...
  20. doi Mineralization of the recalcitrant oxalic and oxamic acids by electrochemical advanced oxidation processes using a boron-doped diamond anode
    Sergi Garcia-Segura
    Laboratori d Electroquímica de Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Barcelona, Spain
    Water Res 45:2975-84. 2011
    ..Low current densities and Fe(2+) contents are preferable to remove more efficiently these acids by the most potent AO-BDD-Fe(2+)-UVA method...
  21. doi Solar photoelectro-Fenton degradation of the herbicide 4-chloro-2-methylphenoxyacetic acid optimized by response surface methodology
    Sergi Garcia-Segura
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Hazard Mater 194:109-18. 2011
    ..A reaction sequence for the SPEF degradation of MCPA was proposed...
  22. doi Remediation of water pollution caused by pharmaceutical residues based on electrochemical separation and degradation technologies: a review
    Ignasi Sirés
    Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Barcelona, Spain
    Environ Int 40:212-29. 2012
    ..The routes for the degradation of the some pharmaceuticals are also presented...
  23. ncbi Mineralization of paracetamol in aqueous medium by anodic oxidation with a boron-doped diamond electrode
    Enric Brillas
    Laboratori de Ciència i Tecnologia Electroquímica de Materials, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    Chemosphere 58:399-406. 2005
    ..Paracetamol can be completely destroyed with Pt and its kinetics follows a pseudo-first-order reaction with a constant rate independent of pH...
  24. ncbi Degradation of herbicide 4-chlorophenoxyacetic acid by advanced electrochemical oxidation methods
    Birame Boye
    Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Spain
    Environ Sci Technol 36:3030-5. 2002
    ..The highest mineralization rate found for photoelectro-Fenton is accounted for by the fast photodecomposition of complexes of Fe3+ with such short-chain acids, mainly oxalic acid, under the action of UV light...
  25. doi Comparative electrochemical treatments of two chlorinated aliphatic hydrocarbons. Time course of the main reaction by-products
    Serena Randazzo
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Hazard Mater 192:1555-64. 2011
    ..Chlorine was released as Cl(-), being further oxidized to ClO(3)(-) and, mostly, to ClO(4)(-), due to the action of the largely generated BDD(OH) and OH...
  26. ncbi Electrochemical advanced oxidation processes: today and tomorrow. A review
    Ignasi Sirés
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028, Barcelona, Spain
    Environ Sci Pollut Res Int 21:8336-67. 2014
    ..A global perspective on the fundamentals and experimental setups is offered, and laboratory-scale and pilot-scale experiments are examined and discussed. ..
  27. ncbi Electro-Fenton degradation of the antibiotic sulfanilamide with Pt/carbon-felt and BDD/carbon-felt cells. Kinetics, reaction intermediates, and toxicity assessment
    Abdellatif El-Ghenymy
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028, Barcelona, Spain
    Environ Sci Pollut Res Int 21:8368-78. 2014
    ..Although it acquired its maximum value at short electrolysis time, the solution was completely detoxified at the end of the electro-Fenton treatment, regardless of the anode used. ..
  28. ncbi Application of electrochemical advanced oxidation processes to the mineralization of the herbicide diuron
    Angelo R F Pipi
    Laboratori d Electroquímica dels Materials i del Medi Ambient, Departament de Quimica Fisica, Facultat de Quimica, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain Departamento de Química, Laboratório de Eletrocatálise e Eletroquímica Ambiental, Faculdade de Filosofia, Ciencias e Letras de Ribeirao Preto, Universidade de São Paulo FFCLRP, USP, Av Bandeirantes 3900, 14040 901 Ribeirao Preto, SP, Brazil
    Chemosphere 109:49-55. 2014
    ..Oxalic and oxamic acids were detected as final carboxylic acids. Ammonium and chloride ions were also released, the latter ion being partially converted into chlorate and perchlorate ions at the BDD surface...
  29. ncbi Red organic light-emitting radical adducts of carbazole and tris(2,4,6-trichlorotriphenyl)methyl radical that exhibit high thermal stability and electrochemical amphotericity
    Dolores Velasco
    Departament de Quimica Organica, Institut de Nanociències I Nanotecnologia, Universitat de Barcelona, Marti i Franques 1 11, 08028 Barcelona, Spain
    J Org Chem 72:7523-32. 2007
    ..On the other hand, the EPR parameters of these radical adducts show an imperceptible variation with the substituents in the carbazole...
  30. doi Electrochemical alternatives for drinking water disinfection
    Carlos A Martínez-Huitle
    DISTAM, Università degli Studi di Milano via Celoria 2, CAP 20133 Milan, Italy
    Angew Chem Int Ed Engl 47:1998-2005. 2008
    ..This article reviews electrochemical systems that can contribute to drinking water disinfection and underscores the efficiency of recently developed diamond films in chlorine-free electrochemical systems...