Nazario Martin

Summary

Affiliation: Universidad Complutense
Country: Spain

Publications

  1. doi request reprint Catalytic stereodivergent functionalization of H2@C60
    Enrique E Maroto
    Departamento de Quimica Organica I, Facultad de Ciencias Quimicas, Ciudad Universitaria, s n 28040 Madrid, Spain
    Chem Commun (Camb) 50:740-2. 2014
  2. doi request reprint Tetrathiafulvalene: the advent of organic metals
    Nazario Martin
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Ciudad Universitaria s n, 28040 Madrid, Spain
    Chem Commun (Camb) 49:7025-7. 2013
  3. doi request reprint Two experiments that impacted the fate of fullerenes
    Nazario Martin
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Ciudad Universitaria s n, 28040, Madrid, Spain
    Chem Commun (Camb) 49:1039-41. 2013
  4. ncbi request reprint Regioselective intramolecular Pauson-Khand reactions of C60: an electrochemical study and theoretical underpinning
    Nazario Martin
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense, 28040 Madrid, Spain
    Chemistry 11:2716-29. 2005
  5. ncbi request reprint Electronic communication in tetrathiafulvalene (TTF)/C60 systems: toward molecular solar energy conversion materials?
    Nazario Martin
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense, E 28040 Madrid, Spain
    Acc Chem Res 40:1015-24. 2007
  6. ncbi request reprint Electron donor-acceptor interactions in regioselectively synthesized exTTF(2)-C(70)(CF(3))(10) dyads
    Yuta Takano
    Departamento de Quimica Organica I, Facultad de Quimica, Universidad Complutense, 28040 Madrid, Spain
    Chemistry 16:5343-53. 2010
  7. ncbi request reprint Electronic interactions in a new pi-extended tetrathiafulvalene dimer
    Marta C Díaz
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense, 28040 Madrid, Spain
    Chemistry 12:2709-21. 2006
  8. ncbi request reprint Anefficient approach to chiral fullerene derivatives by catalytic enantioselective 1,3-dipolar cycloadditions
    Salvatore Filippone
    Departamento de Quimica Organica I, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Spain
    Nat Chem 1:578-82. 2009
  9. doi request reprint Charge transfer-assisted self-limited decyanation reaction of TCNQ-type electron acceptors on Cu(100)
    Christian Urban
    Dep de Física de la Materia Condensada, Universidad Autonoma de Madrid, Madrid, Spain
    Chem Commun (Camb) 50:833-5. 2014
  10. ncbi request reprint Self-assembly of C(60) pi-extended tetrathiafulvalene (exTTF) dyads on gold surfaces
    Maria Sierra
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, E 28040 Madrid, Spain
    Langmuir 22:10619-24. 2006

Collaborators

  • Dirk M Guldi
  • Edmund Leary
  • Yang Wang
  • Roberto Otero
  • Timothy Clark
  • Takeshi Akasaka
  • Lawrence T Scott
  • Francesco Giacalone
  • M Teresa Gonzalez
  • Albert Poater
  • Julius Rebek
  • Maurizio Prato
  • Shunichi Fukuzumi
  • Sheng Zhang
  • Salvatore Filippone
  • Enrique E Maroto
  • M Angeles Herranz
  • Emilio M Pérez
  • Luis Sanchez
  • Laura Rodríguez-Pérez
  • Beatriz M Illescas
  • Raul Garcia
  • Enrique Ortí
  • Jose Santos
  • Margarita Suarez
  • Juan Marco-Martínez
  • Juan Luis Lopez
  • Gustavo Fernandez
  • Carmen Atienza
  • Agustín Molina-Ontoria
  • Yuta Takano
  • Javier López-Andarias
  • Joaquín Calbo
  • Pierre Antoine Bouit
  • Antonio Muñoz
  • Ángel Martín-Domenech
  • Rafael Viruela
  • Roberto Martinez-Alvarez
  • María Gallego
  • Maria Sierra
  • Andrea La Rosa
  • Helena Isla
  • Christian Urban
  • Marta Izquierdo
  • Maria Angeles Herranz
  • Vanesa Marcos
  • Silvia Reboredo
  • Carlos Romero-Nieto
  • Juan Luis Delgado
  • Enrique Maroto
  • David Canevet
  • Mateusz Wielopolski
  • Bruno Grimm
  • Andreas Gouloumis
  • Takahiro Tsuchiya
  • Roberto J Brea
  • Wolfgang Seitz
  • Marta C Díaz
  • Dolores Molero
  • Fulvio G Brunetti
  • Fernando H Liquido
  • Rafael M Krick Calderon
  • Michihisa Murata
  • Manuel Alcamí
  • Abel de Cozar
  • Fernando P Cossio
  • Nicolás Agraït
  • José M Gallego
  • Rodolfo Miranda
  • Juan Aragó
  • Yasujiro Murata
  • Allison K Greene
  • Katalin Gillemot
  • Colin J Lambert
  • Jonathan Rodríguez-Fernández
  • Edward A Jackson
  • Koichi Komatsu
  • Fernando Martin
  • Takahiro Iwamoto
  • Charalambos Evangeli
  • Gabino Rubio-Bollinger
  • Lourdes Infantes
  • Ma Rosario Torres
  • Alberto Insuasty
  • Pedro M Viruela
  • Ma Ángeles Herranz
  • Julian Gebhardt
  • Javier Adrio
  • Macarena Sánchez-Navarro
  • Javier Rojo

Detail Information

Publications45

  1. doi request reprint Catalytic stereodivergent functionalization of H2@C60
    Enrique E Maroto
    Departamento de Quimica Organica I, Facultad de Ciencias Quimicas, Ciudad Universitaria, s n 28040 Madrid, Spain
    Chem Commun (Camb) 50:740-2. 2014
    ..The stereodivergent synthesis of either the cis or the trans endohedral cycloadduct is achieved with excellent diastereo- and enantioselectivities. ..
  2. doi request reprint Tetrathiafulvalene: the advent of organic metals
    Nazario Martin
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Ciudad Universitaria s n, 28040 Madrid, Spain
    Chem Commun (Camb) 49:7025-7. 2013
    ....
  3. doi request reprint Two experiments that impacted the fate of fullerenes
    Nazario Martin
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Ciudad Universitaria s n, 28040, Madrid, Spain
    Chem Commun (Camb) 49:1039-41. 2013
    ....
  4. ncbi request reprint Regioselective intramolecular Pauson-Khand reactions of C60: an electrochemical study and theoretical underpinning
    Nazario Martin
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense, 28040 Madrid, Spain
    Chemistry 11:2716-29. 2005
    ..Cyclic voltammetry reveals that the presence of the cyclopentenone's carbonyl group connected directly to the C60 core results in PK compounds with remarkable electron-accepting ability...
  5. ncbi request reprint Electronic communication in tetrathiafulvalene (TTF)/C60 systems: toward molecular solar energy conversion materials?
    Nazario Martin
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense, E 28040 Madrid, Spain
    Acc Chem Res 40:1015-24. 2007
    ..These long-lived radical pairs are called to play an important role for the conversion of sunlight into chemical or electrical power...
  6. ncbi request reprint Electron donor-acceptor interactions in regioselectively synthesized exTTF(2)-C(70)(CF(3))(10) dyads
    Yuta Takano
    Departamento de Quimica Organica I, Facultad de Quimica, Universidad Complutense, 28040 Madrid, Spain
    Chemistry 16:5343-53. 2010
    ....
  7. ncbi request reprint Electronic interactions in a new pi-extended tetrathiafulvalene dimer
    Marta C Díaz
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense, 28040 Madrid, Spain
    Chemistry 12:2709-21. 2006
    ..Oxidation of 14(2+) forms the tetracation 14(4+) which is constituted by two aromatic anthracene units bearing four aromatic, almost orthogonal 1,3-dithiolium cations...
  8. ncbi request reprint Anefficient approach to chiral fullerene derivatives by catalytic enantioselective 1,3-dipolar cycloadditions
    Salvatore Filippone
    Departamento de Quimica Organica I, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Spain
    Nat Chem 1:578-82. 2009
    ..Furthermore, well-defined chiral carbon atoms linked to the fullerene sphere are able to perturb the inherent symmetry of the fullerene π-system as revealed by circular dichroism measurements...
  9. doi request reprint Charge transfer-assisted self-limited decyanation reaction of TCNQ-type electron acceptors on Cu(100)
    Christian Urban
    Dep de Física de la Materia Condensada, Universidad Autonoma de Madrid, Madrid, Spain
    Chem Commun (Camb) 50:833-5. 2014
    ..Combined Scanning Tunneling Microscopy/X-ray Photoelectron Spectroscopy experiments and Density Functional Theory calculations relate the self-limiting behavior to the transfer of electrons from the metal to the molecule. ..
  10. ncbi request reprint Self-assembly of C(60) pi-extended tetrathiafulvalene (exTTF) dyads on gold surfaces
    Maria Sierra
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, E 28040 Madrid, Spain
    Langmuir 22:10619-24. 2006
    ....
  11. doi request reprint [2,2']paracyclophane-based π-conjugated molecular wires reveal molecular-junction behavior
    Agustín Molina-Ontoria
    Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, Madrid, Spain
    J Am Chem Soc 133:2370-3. 2011
    ..If hole transfer is assumed to be the dominant charge transfer (CT) mechanism, CT is facilitated in one direction (from C(60) to ZnP via pCp) but disfavored in the other direction (from ZnP to C(60) via pCp)...
  12. ncbi request reprint Exceptionally strong electronic communication through hydrogen bonds in porphyrin-C60 pairs
    Luis Sanchez
    Departamento de Quimica Organica, Facultad de Quimica, Universidad Complutense de Madrid, 28040 Madrid, Spain
    Angew Chem Int Ed Engl 45:4637-41. 2006
  13. ncbi request reprint Donor-acceptor conjugates of lanthanum endohedral metallofullerene and pi-extended tetrathiafulvalene
    Yuta Takano
    Departamento de Quimica Organica I, Facultad de Quimica, Universidad Complutense, E 28040 Madrid, Spain
    J Am Chem Soc 132:8048-55. 2010
    ..0 x 10(8) s(-1)) in toluene. Transient absorption spectroscopy experiments confirmed these observations...
  14. pmc Enantioselective cycloaddition of münchnones onto [60]fullerene: organocatalysis versus metal catalysis
    Juan Marco-Martínez
    Departamento de Quimica Organica I, Facultad de Quimica, Universidad Complutense, E 28040 Madrid, Spain
    J Am Chem Soc 136:2897-904. 2014
    ..Further functionalization of the pyrrolinofullerene carboxylic acid derivatives has been carried out by esterification and amidation reactions. ..
  15. doi request reprint Large exTTF-based dendrimers. Self-assembly and peripheral cooperative multiencapsulation of C60
    Gustavo Fernandez
    Departamento de Quimica Organica, Facultad de Quimica, Universidad Complutense, E 28040 Madrid, Spain
    J Am Chem Soc 130:10674-83. 2008
    ..The calculated values for D demonstrate the decrease of this magnitude with increasing dendrimer size...
  16. ncbi request reprint Controlling the crystalline three-dimensional order in bulk materials by single-wall carbon nanotubes
    Javier López-Andarias
    Departamento de Quimica Organica, Facultad de C C Químicas, Universidad Complutense de Madrid, 28040 Madrid and IMDEA Nanociencia, 28049 Madrid, Spain
    Nat Commun 5:3763. 2014
    ....
  17. ncbi request reprint Diastereoselective synthesis of fulleropyrrolidines from suitably functionalized chiral cyclobutanes
    Beatriz M Illescas
    Departamento de Quimica Organica, Facultad de Quimica, Universidad Complutense, E 28040 Madrid, Spain
    J Org Chem 70:6929-32. 2005
    ..The new C(60)-based cyclobutane derivatives 7a,b and 9 are suitably functionalized for further incorporation into peptide surrogates...
  18. ncbi request reprint Hydrogen-bonding motifs in fullerene chemistry
    Luis Sanchez
    Departamento de Quimica Organica I, Facultad de Quimica, Universidad Complutense, 28040 Madrid, Spain
    Angew Chem Int Ed Engl 44:5374-82. 2005
    ....
  19. doi request reprint Efficient light harvesters based on the 10-(1,3-dithiol-2-ylidene)anthracene core
    Pierre Antoine Bouit
    IMDEA Nanociencia, Ciudad Universitaria de Cantoblanco, 28049 Madrid, Spain
    Org Lett 15:4166-9. 2013
    ..Electrochemistry and theoretical calculations allowed the understanding of these singular electronic properties. The molecular structures were unambiguously confirmed by X-ray diffraction. ..
  20. ncbi request reprint Spectroscopic characterization of photolytically generated radical ion pairs in single-wall carbon nanotubes bearing surface-immobilized tetrathiafulvalenes
    M Angeles Herranz
    Departamento de Quimica Organica I, Facultad de Quimica, Universidad Complutense de Madrid, E 28040 Madrid, Spain
    J Am Chem Soc 130:66-73. 2008
    ..New conduction band electrons, injected from photoexcited exTTF, shift the transitions that are associated with the van Hove singularities to lower energies...
  21. pmc Stereodivergent synthesis of chiral fullerenes by [3 + 2] cycloadditions to C₆₀
    Enrique E Maroto
    Departamento de Quimica Organica I, Facultad de Quimica, Universidad Complutense, E 28040 Madrid, Spain
    J Am Chem Soc 136:705-12. 2014
    ..Theoretical DFT calculations are in very good agreement with the experimental data. On the basis of this agreement, a plausible reaction mechanism is proposed. ..
  22. ncbi request reprint Does a cyclopropane ring enhance the electronic communication in dumbbell-type c60 dimers?
    Andrea La Rosa
    Departamento de Quimica Organica, Facultad de Quimica, Universidad Complutense, E 28040 Madrid, Spain
    J Org Chem 79:4871-7. 2014
    ..This strengthens the idea that cyclopropane behaves as a quasi-double bond. ..
  23. doi request reprint Switching the stereoselectivity: (fullero)pyrrolidines "a la carte"
    Enrique E Maroto
    Departamento de Quimica Organica I, Facultad de Quimica, Universidad Complutense, E 28040 Madrid, Spain
    J Am Chem Soc 134:12936-8. 2012
    ..Fullerenes are revealed as a useful benchmark to develop suitable catalysts to control the stereochemical outcome and to shed light on the mechanism involved in the related 1,3-dipolar cycloaddition. ..
  24. doi request reprint A new exTTF-crown ether platform to associate fullerenes: cooperative n-π and π-π effects
    Bruno Grimm
    Institute of Physical and Theoretical Chemistry and Interdisciplinary Center for Molecular Materials, University of Erlangen, 91058 Erlangen, Germany
    J Am Chem Soc 132:17387-9. 2010
    ....
  25. ncbi request reprint Self-association and electron transfer in donor-acceptor dyads connected by meta-substituted oligomers
    Agustín Molina-Ontoria
    Departamento de Quimica Organica, Facultad de Quimica, Universidad Complutense, E 28040 Madrid, Spain
    J Am Chem Soc 131:12218-29. 2009
    ..0 micros...
  26. ncbi request reprint Modified SWCNTs with Amphoteric Redox and Solubilizing Properties
    Laura Rodríguez-Pérez
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, 28040 Madrid Spain, Fax 34 91 394 4103
    Chemistry 20:7278-86. 2014
    ....
  27. ncbi request reprint Modified SWCNTs with Amphoteric Redox and Solubilizing Properties
    Laura Rodríguez-Pérez
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, 28040 Madrid Spain, Fax 34 91 394 4103
    Chemistry 20:7177. 2014
    ..Read the full text of the article at 10.1002/chem.201400183. ..
  28. doi request reprint Effect of substituents and protonation on the mechanism of 1,3-dipolar retro-cycloaddition reaction of pyrrolidino[60]- and [70]fullerenes
    Enrique Maroto
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense, Madrid, Spain
    J Mass Spectrom 46:1016-29. 2011
    ..The protonation of the NH group inhibits the cycloreversion process, and therefore different fragmentations take place. The detailed mechanisms of the formation and evolution of the intermediate fragments are described...
  29. ncbi request reprint 1H and 13C spectral assignment of 2(1H)-pyridone derivatives
    Dolores Molero
    CAI RMN, Universidad Complutense, E 28040 Madrid, Spain
    Magn Reson Chem 42:704-8. 2004
    ..1H and 13C NMR spectroscopic data for 4-aryl-3,4-dihydro-6-methyl-2(1H)pyridone derivatives were fully assigned by a combination of one- and two- dimensional experiments (DEPT, HMBC, HMQC, COSY, NOE)...
  30. doi request reprint Tetrafullerene conjugates for all-organic photovoltaics
    Gustavo Fernandez
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Ciudad Universitaria s n, 28040 Madrid, Spain
    J Org Chem 73:3189-96. 2008
    ....
  31. pmc Electron transfer in Me-blocked heterodimeric alpha,gamma-peptide nanotubular donor-acceptor hybrids
    Roberto J Brea
    Departamento de Quimica Organica, Facultad de Quimica, Universidad de Santiago, E 15782 Santiago de Compostela, Spain
    Proc Natl Acad Sci U S A 104:5291-4. 2007
    ....
  32. doi request reprint Linear and hyperbranched electron-acceptor supramolecular oligomers
    Jose Santos
    Departamento de Quimica Organica, Facultad de C C Químicas, Universidad Complutense de Madrid, Av Complutense S N, 28040, Madrid, Spain
    Chem Asian J 6:1848-53. 2011
    ..These polymers constitute two of the first examples of n-type supramolecular polymers reported to date...
  33. doi request reprint Unambiguous one-molecule conductance measurements under ambient conditions
    Edmund Leary
    Instituto Madrileño de Estudios Avanzados, Facultad de Ciencias Módulo 9, 3a planta Avda Fco Tomás y Valiente, 7 Ciudad Universitaria de Cantoblanco, 28049, Madrid, Spain
    Nano Lett 11:2236-41. 2011
    ..By characterizing and controlling the junction, we can draw stronger conclusions about the observed variation in molecular conductance than was previously possible...
  34. doi request reprint Nanorods versus nanovesicles from amphiphilic dendrofullerenes
    Antonio Muñoz
    Departamento de Quimica Organica, Facultad de Quimica, Universidad Complutense, 28040 Madrid, Spain
    J Am Chem Soc 133:16758-61. 2011
    ..These amphiphilic fullerene derivatives aggregate forming micelles, nanorods, or hollow vesicles depending on the concentration and on the solid substrate...
  35. ncbi request reprint Electron transfer in a supramolecular associate of a fullerene fragment
    María Gallego
    Departamento de Quimica Organica, Fac C C Químicas, Universidad Complutense de Madrid, Av Complutense S N, 28040 Madrid Spain http www ucm es info fullerene
    Angew Chem Int Ed Engl 53:2170-5. 2014
    ....
  36. ncbi request reprint Concave versus planar geometries for the hierarchical organization of mesoscopic 3D helical fibers
    Juan Luis Lopez
    Departamento de Quimica Organica, Facultad de C C Químicas, Universidad Complutense de Madrid, Spain
    Angew Chem Int Ed Engl 51:3857-61. 2012
    ..Control over the hierarchical growth by H bonding, π-π, and solvophobic interactions made possible the efficient generation of electroactive 3D helical fibers...
  37. doi request reprint Formation of self-assembled chains of tetrathiafulvalene on a Cu(100) surface
    Yang Wang
    Departamento de Química C 13, Universidad Autonoma de Madrid, Cantoblanco, Madrid, Spain
    J Phys Chem A 115:13080-7. 2011
    ....
  38. ncbi request reprint High degree of polymerization in a fullerene-containing supramolecular polymer
    Helena Isla
    Departamento de Quimica Organica, Fac C C Químicas, Universidad Complutense de Madrid, Av Complutense S N, 28040 Madrid Spain http www ucm es info fullerene
    Angew Chem Int Ed Engl 53:5629-33. 2014
    ..A MW above 150 kDa has been found experimentally in solution, while in the solid state the monomer forms extraordinarily long, straight, and uniform fibers with lengths reaching several microns...
  39. ncbi request reprint Synthesis of soluble donor-acceptor double-cable polymers based on polythiophene and tetracyanoanthraquinodimethane (TCAQ)
    Francesco Giacalone
    Departamento de Quimica Organica, Facultad de Quimica, Universidad Complutense, 28040, Madrid, Spain
    Org Lett 5:1669-72. 2003
    ..The absorption and emission data reveal that the optical properties can be finely tuned by modifying the ratio of monomers in the copolymerization process...
  40. doi request reprint The chemistry of pristine graphene
    Laura Rodríguez-Pérez
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Ciudad Universitaria s n, 28040, Madrid, Spain
    Chem Commun (Camb) 49:3721-35. 2013
    ..Current approaches for the preparation of modified pristine graphene are the aim of this review...
  41. doi request reprint Asymmetric Organocatalysis in Fullerenes Chemistry: Enantioselective Phosphine-catalyzed Cycloaddition of Allenoates onto C60
    Juan Marco-Martínez
    Departamento de Quimica Organica I, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Ciudad Universitaria s n, 28040 Madrid Spain http www ucm es info fullerene
    Angew Chem Int Ed Engl 52:5115-9. 2013
    ..Furthermore, the sector rule previously used to assign the chirality in [60]fullerenes has been corrected in the light of these new experimental findings...
  42. doi request reprint Wraparound hosts for fullerenes: tailored macrocycles and cages
    David Canevet
    IMDEA Nanociencia, Facultad de Ciencias, Ciudad Universitaria de Cantoblanco, Madrid, Spain
    Angew Chem Int Ed Engl 50:9248-59. 2011
    ..In this Minireview, we highlight some of the important breakthroughs that this class of fullerene hosts has already produced...
  43. ncbi request reprint Chiral recognition of carbon nanoforms
    Emilio M Pérez
    Facultad de Ciencias Módulo C IX, 3ª planta, Avda Fco Tomás y Valiente, 7 and Ciudad Universitaria de Cantoblanco, 28049, Madrid, Spain
    Org Biomol Chem 10:3577-83. 2012
    ....
  44. doi request reprint A fully conjugated TTF-π-TCAQ system: synthesis, structure, and electronic properties
    Jose Santos
    Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain
    Chemistry 17:2957-64. 2011
    ..0±0.2) ps) charge recombination to reconstitute the electronic ground state. Such ultrafast charge separation and recombination processes come as a consequence of the very short vinyl linkage between the two electroactive units...
  45. doi request reprint Tuning the electronic properties of nonplanar exTTF-based push-pull chromophores by aryl substitution
    Raul Garcia
    Departamento de Quimica Organica, Facultad de Quimica, Universidad Complutense de Madrid, 28040 Madrid, Spain
    J Org Chem 77:10707-17. 2012
    ..The electronic absorption spectra are characterized by low- to medium-intense charge-transfer bands that extend to the near-infrared...