Peter W Roesky

Summary

Publications

  1. doi request reprint Zinc-silylene complexes
    Sebastian Schafer
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstraße 15, 76131 Karlsruhe, Germany
    Chem Commun (Camb) 50:11401-3. 2014
  2. doi request reprint Gold(I) complexes with heteroaryl phosphine ligands
    Christian Sarcher
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstr 15, Geb 30 45, 76131 Karlsruhe, Germany
    Dalton Trans 43:2397-405. 2014
  3. doi request reprint Synthesis, structure and reactivity of rare-earth metal complexes containing anionic phosphorus ligands
    Tianshu Li
    Institut fur Anorganische Chemie, Karlsruhe Institute of Technology KIT, Engesserstrasse 15, 76131 Karlsruhe, Germany
    Chem Soc Rev 43:42-57. 2014
  4. doi request reprint Slow magnetic relaxation in four square-based pyramidal dysprosium hydroxo clusters ligated by chiral amino acid anions - a comparative study
    Dominique T Thielemann
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstr 15, Geb 30 45, 76131 Karlsruhe, Germany
    Dalton Trans 42:14794-800. 2013
  5. ncbi request reprint Chiral lutetium benzamidinate complexes
    Paul Benndorf
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology KIT, Engesserstr 15, 76131 Karlsruhe, Germany
    Chem Commun (Camb) 47:2574-6. 2011
  6. ncbi request reprint Salen-based metal-organic frameworks of nickel and the lanthanides
    Peter W Roesky
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstr 15, 76128 Karlsruhe, Germany
    Chem Commun (Camb) 47:2035-7. 2011
  7. doi request reprint Peptoid-ligated pentadecanuclear yttrium and dysprosium hydroxy clusters
    Dominique T Thielemann
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe Germany
    Chemistry 21:2713. 2015
  8. doi request reprint Peptoid-ligated pentadecanuclear yttrium and dysprosium hydroxy clusters
    Dominique T Thielemann
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe Germany
    Chemistry 21:2813-20. 2015
  9. doi request reprint Trinuclear nickel-lanthanide compounds
    Asamanjoy Bhunia
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie, Engesserstr 15, Geb 30 45, 76131 Karlsruhe, Germany
    Dalton Trans 42:2445-50. 2013
  10. doi request reprint Luminescent cell-penetrating pentadecanuclear lanthanide clusters
    Dominique T Thielemann
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany
    J Am Chem Soc 135:7454-7. 2013

Collaborators

  • Annie K Powell
  • Manfred Scheer
  • Christopher Barner-Kowollik
  • Glen B Deacon
  • Birgit Rudat
  • Andreas Eichhöfer
  • Andreas Scheurer
  • Thomas J A Wolf
  • Dominique T Thielemann
  • Michael T Gamer
  • Tianshu Li
  • Yanhua Lan
  • Asamanjoy Bhunia
  • Paul Benndorf
  • Munendra Yadav
  • Jochen Kratsch
  • Pascual Oña-Burgos
  • Anna T Wagner
  • Ignacio Fernandez
  • Sebastian Bestgen
  • Stefan Bräse
  • Dominik K Kölmel
  • Nicholas Arleth
  • Sergey N Konchenko
  • Ralf Köppe
  • Sebastian Marks
  • Jelena Jenter
  • Esther S Rösch
  • Sergei Lebedkin
  • Manfred M Kappes
  • Sebastian Schafer
  • Johannes Willenbacher
  • Svetlana V Klementyeva
  • Christian Sarcher
  • Christoph Kaub
  • Timo Augenstein
  • Valeriu Mereacre
  • Magdalena Kuzdrowska
  • Karsten Meyer
  • Sanjay K Singh
  • Franziska Völcker
  • Gereon Niedner-Schatteburg
  • Christoph Riehn
  • Claus Feldmann
  • Joachim G Heck
  • Fabian Menges
  • Matthias W Löble
  • Laurent Maron
  • Sophie M Guillaume
  • Anja Lühl
  • Leila Taghizadeh Ghoochany
  • Anna Corina Schmidt
  • Carsten Koke
  • Melissa A Denecke
  • Andreas Geist
  • Petra J Panak
  • Lars Esmezjan
  • Werner R Thiel
  • Sabrina Kaercher
  • Thomas O Bauer
  • Elisa Rothe
  • Ozcan Altintas
  • Björn B Beele
  • Yu Sun
  • Volker Schünemann
  • Saeid Farsadpour
  • Meike A Gotthardt
  • Christopher E Anson
  • Marco Neumaier
  • Cédric G Jaffredo
  • Silke Behrens
  • Wolfgang Kleist
  • Fabian Dielmann
  • Matthias Schmid
  • Stefanie Dehnen
  • Esther Rösch
  • Klaus Harms
  • Partha P Jana
  • Radostan Riedel
  • Liana Annunziata
  • Ute Schepers
  • Stephan Schulz
  • Corinna M Preuss
  • Frank Breher
  • María Casimiro
  • Marija H Habicht
  • Liviu Ungur
  • Sophia Schmitt
  • Liviu F Chibotaru
  • Larissa Hartenstein

Detail Information

Publications35

  1. doi request reprint Zinc-silylene complexes
    Sebastian Schafer
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstraße 15, 76131 Karlsruhe, Germany
    Chem Commun (Camb) 50:11401-3. 2014
    ....
  2. doi request reprint Gold(I) complexes with heteroaryl phosphine ligands
    Christian Sarcher
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstr 15, Geb 30 45, 76131 Karlsruhe, Germany
    Dalton Trans 43:2397-405. 2014
    ..The homoleptic complexes show a different behavior...
  3. doi request reprint Synthesis, structure and reactivity of rare-earth metal complexes containing anionic phosphorus ligands
    Tianshu Li
    Institut fur Anorganische Chemie, Karlsruhe Institute of Technology KIT, Engesserstrasse 15, 76131 Karlsruhe, Germany
    Chem Soc Rev 43:42-57. 2014
    ..Particular attention has been paid to the synthesis, structure, and reactivity of the rare-earth metal phosphides. ..
  4. doi request reprint Slow magnetic relaxation in four square-based pyramidal dysprosium hydroxo clusters ligated by chiral amino acid anions - a comparative study
    Dominique T Thielemann
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstr 15, Geb 30 45, 76131 Karlsruhe, Germany
    Dalton Trans 42:14794-800. 2013
    ....
  5. ncbi request reprint Chiral lutetium benzamidinate complexes
    Paul Benndorf
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology KIT, Engesserstr 15, 76131 Karlsruhe, Germany
    Chem Commun (Camb) 47:2574-6. 2011
    ..Enantiomerically pure lutetium complexes were synthesized as the first rare earth metal complexes containing a chiral amidinate ligand. The catalytic activity and the enantioselectivity in hydroamination reactions were studied...
  6. ncbi request reprint Salen-based metal-organic frameworks of nickel and the lanthanides
    Peter W Roesky
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstr 15, 76128 Karlsruhe, Germany
    Chem Commun (Camb) 47:2035-7. 2011
    ..By using this strategy unique structures, in which the salen-nickel unit acts as flexible strut, were obtained. The shape of the network is strongly influenced by the ion radius of the lanthanide element...
  7. doi request reprint Peptoid-ligated pentadecanuclear yttrium and dysprosium hydroxy clusters
    Dominique T Thielemann
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe Germany
    Chemistry 21:2713. 2015
    ..Seals are known to be very skilled at balancing and other tricks, whereas our skills include crystallizing new compounds and further examining their properties. Read the full text of the article at 10.1002/chem.201405569. ..
  8. doi request reprint Peptoid-ligated pentadecanuclear yttrium and dysprosium hydroxy clusters
    Dominique T Thielemann
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe Germany
    Chemistry 21:2813-20. 2015
    ..Furthermore, the χT product as a function of temperature for the dysprosium cluster gave evidence that this is a ferromagnetically coupled compound below 11 K...
  9. doi request reprint Trinuclear nickel-lanthanide compounds
    Asamanjoy Bhunia
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie, Engesserstr 15, Geb 30 45, 76131 Karlsruhe, Germany
    Dalton Trans 42:2445-50. 2013
    ..Hydrogen/deuterium exchange (HDX) experiments in solution support the fragmentation scheme. The magnetic studies on all these compounds suggest the presence of weak antiferromagnetic interactions between neighboring metal centers...
  10. doi request reprint Luminescent cell-penetrating pentadecanuclear lanthanide clusters
    Dominique T Thielemann
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany
    J Am Chem Soc 135:7454-7. 2013
    ..The cytotoxicity of 1 and 2 toward the HeLa cells is moderate...
  11. doi request reprint Mononuclear and tetranuclear compounds of yttrium and dysprosium ligated by a salicylic schiff-base derivative: synthesis, photoluminescence, and magnetism
    Munendra Yadav
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie, Engesserstrasse 15, 76131 Karlsruhe, Germany
    Inorg Chem 54:773-81. 2015
    ..Compound 4 shows single-molecule-magnet behavior with two relaxation processes, one with the effective energy barrier U(eff) = 84 K and the preexponential factor τ(0) = 5.1 × 10(-9) s...
  12. doi request reprint 1H,89Y HMQC and further NMR spectroscopic and X-ray diffraction investigations on yttrium-containing complexes exhibiting various nuclearities
    Matthias W Löble
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany
    Chemistry 18:5325-34. 2012
    ..1)H,(19)F HOESY and (19)F,(19)F EXSY data revealed that the anions are specifically located in particular regions of space, which nicely correlated with the geometries found in the X-ray structures...
  13. doi request reprint Intramolecular phosphorus-phosphorus bond formation within a Co2P4 core
    Tianshu Li
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany
    Inorg Chem 52:14231-6. 2013
    ..The formation of the P-P bond is not a result of the direct reduction of the phosphorus atoms but is induced by a rearrangement of the positive charges between the metal atoms. ..
  14. ncbi request reprint Zinc-zinc bonded decamethyldizincocene Zn2(η(5)-C5Me5)2 as catalyst for the inter- and intramolecular hydroamination reaction
    Anja Lühl
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie, Engesserstr 15, 76131 Karlsruhe, Germany
    Chem Commun (Camb) 47:8280-2. 2011
    ..High reaction rates under mild conditions were observed. This is the first application of a Zn-Zn bonded compound as catalyst...
  15. ncbi request reprint Salen-based coordination polymers of iron and the rare Earth elements
    Asamanjoy Bhunia
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstrasse 15, 76131 Karlsruhe, Germany
    Inorg Chem 50:12697-704. 2011
    ..In addition, an anomalous temperature dependence of both isomer shift and quadrupole splitting has been observed...
  16. doi request reprint P-P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes
    Tianshu Li
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstr 15, Geb 30 45, 76131 Karlsruhe, Germany
    Chem Commun (Camb) 49:2183-5. 2013
    ..They are the first P(10) bridging 3d/4f metal complexes and the first examples of reductive coupling of polyphosphide complexes by divalent lanthanides...
  17. doi request reprint From a Dy(III) single molecule magnet (SMM) to a ferromagnetic [Mn(II)Dy(III)Mn(II)] trinuclear complex
    Asamanjoy Bhunia
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstr 15, 76128 Karlsruhe, Germany
    Inorg Chem 51:9589-97. 2012
    ..Hydrogen/deuterium exchange (HDX) reactions with ND(3) were performed in a FT-ICR Penning-trap mass spectrometer...
  18. doi request reprint Catching gaseous SO2 in cone-type lanthanide complexes: an unexpected coordination mode for SO2 in f-element chemistry
    Paul Benndorf
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie, Germany
    Angew Chem Int Ed Engl 51:5006-10. 2012
    ..Concomitant with the addition and removal of SO(2), the color of the complexes changes reversibly. The structures of the SO(2) compounds could be confirmed in solution and in the solid state...
  19. doi request reprint Activation of SO2 with [(η(5) -C5 Me5 )2 Ln(THF)2 ] (Ln=Eu, Yb) leading to dithionite and sulfinate complexes
    Svetlana V Klementyeva
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstrasse 15, Geb 30 45, 76131 Karlsruhe Germany, Fax 49 721 608 44854 G A Razuvaev Institute of Organometallic Chemistry, RAS, Tropinina str 49, 603950 Nizhny Novgorod, Russia
    Chemistry 20:13497-500. 2014
    ..The compounds presented are the first dithionite and sulfinate complexes of the f-elements...
  20. ncbi request reprint Novel lanthanide-based polymeric chains and corresponding ultrafast dynamics in solution
    Dominique T Thielemann
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstr 15, 76131 Karlsruhe, Germany
    Inorg Chem 50:11990-2000. 2011
    ..Below 0.5 K, hysteresis loops of the magnetization are observed, which show weak single chain magnet (SCM) behavior...
  21. doi request reprint Bis(phosphinimino)methanide Borohydride Complexes of the Rare-Earth Elements as Initiators for the Ring-Opening Polymerization of ε-Caprolactone: Combined Experimental and Computational Investigations
    Jelena Jenter
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstr 15, 76128 Karlsruhe Germany, Fax 49 721 608 4845
    Chemistry 16:4629-38. 2010
    ..This particularity has been attributed to the metallic fragment based on the natural bond order analysis. ..
  22. doi request reprint Salen-based coordination polymers of manganese and the rare-Earth elements: synthesis and catalytic aerobic epoxidation of olefins
    Asamanjoy Bhunia
    Institut fur Anorganische Chemie, Karlsruhe Institute of Technology KIT, Engesserstrasse 15, D 76131 Karlsruhe Germany, Fax 49 721 608 44854
    Chemistry 19:1986-95. 2013
    ..The catalyst could be reused without significant loss of activity...
  23. doi request reprint Di- and trinuclear gold complexes of diphenylphosphinoethyl-functionalised imidazolium salts and their N-heterocyclic carbenes: synthesis and photophysical properties
    Sebastian Bestgen
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology KIT, Engesserstraße 15, 76131 Karlsruhe Germany, Fax 49 721 6084 4854
    Chemistry 21:601-14. 2015
    ..The synthesised gold complexes show a variety of photophysical properties, including bright white photoluminescence at ambient temperature. ..
  24. doi request reprint Realgar as a building block for lanthanide clusters: encapsulation of a copper cluster by a lanthanide cluster
    Nicholas Arleth
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstrasse 15, Geb 30 45, 76131 Karlsruhe, Germany
    J Am Chem Soc 136:14023-6. 2014
    ..Alternatively, the endohedral cluster can thus be described as [Cu4@{(Cp‴Sm(thf))4S6}], in which a Cu4 tetrahedron is encapsulated by the samarium sulfido cluster {(Cp‴Sm(thf))4S6}. ..
  25. doi request reprint Slow magnetic relaxation in tris(diphosphanylamido) and tetra(phosphanoamido) dysprosium complexes
    Franziska Völcker
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Karlsruhe, Germany
    Dalton Trans 42:11471-5. 2013
    ..Magnetic properties of these two compounds are similar with both showing slow magnetic relaxation. ..
  26. doi request reprint Organometallic calcium and strontium borohydrides as initiators for the polymerization of ε-caprolactone and L-lactide: combined experimental and computational investigations
    Magdalena Kuzdrowska
    Institut für Anorganische Chemie and Helmholtz Research School Energy Related Catalysis, Karlsruher Institut fur Technologie KIT, Engesserstr 15, Geb 30 45, 76131 Karlsruhe, Germany
    Dalton Trans 42:9352-60. 2013
    ..Gibbs free energy profiles were determined for the three calcium complexes highlighting slightly more active calcium complexes as compared to strontium analogues, in agreement with experimental findings...
  27. doi request reprint 6-(Tetrazol-5-yl)-2,2'-bipyridine: a highly selective ligand for the separation of lanthanides(III) and actinides(III)
    Jochen Kratsch
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie, Engesserstrasse 15, 76131 Karlsruhe, Germany
    Inorg Chem 53:8949-58. 2014
    ....
  28. doi request reprint Single-chain self-folding of synthetic polymers induced by metal-ligand complexation
    Johannes Willenbacher
    Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology KIT, Engesserstr 18, 76128, Karlsruhe, Germany Institut für Biologische Grenzflächen, Karlsruhe Institute of Technology KIT, Hermann von Helmholtz Platz 1, 76344, Eggenstein Leopoldshafen, Germany
    Macromol Rapid Commun 35:45-51. 2014
    ..The results derived via (1) H and (31) P{(1) H} NMR experiments, SEC, and DLS unambiguously evidence the efficient formation of SCMCs via metal ligand complexation. ..
  29. doi request reprint High-coordinate gold(I) complexes with dithiocarboxylate ligands
    Christoph Kaub
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstrasse 15, 76131 Karlsruhe, Germany
    Inorg Chem 53:4491-9. 2014
    ..57)Fe-Mössbauer spectroscopy was performed for compounds 2-4. The spectra show isomer shifts and quadrupole splittings that are typical for diamagnetic ferrocenes. ..
  30. doi request reprint New amino acid ligated yttrium hydroxy clusters
    Dominique T Thielemann
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstr 15, Geb 30 45, 76131, Karlsruhe, Germany
    Dalton Trans 39:6661-6. 2010
    ..PGSE NMR diffusion measurements as function of concentration have been carried out on one model cluster, proving these molecules to be prone to aggregation in chloroform solutions...
  31. ncbi request reprint Rare-Earth-metal methylidene complexes
    Jochen Kratsch
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology KIT, Engesserstrasse 15, 76131 Karlsruhe Germany
    Angew Chem Int Ed Engl 53:376-83. 2014
    ..In this field rare-earth-metal alkylidene, especially methylidene, compounds are an emerging class of compounds with a high synthetic potential for organometallic chemistry and maybe in the future also for organic chemistry. ..
  32. doi request reprint Au-based bimetallic nanoparticles for the intramolecular aminoalkene hydroamination
    Sanjay K Singh
    Institut fur Anorganische Chemie, Karlsruher Institut für Technologie KIT Engesserstr 15, 76131 Karlsruhe, Germany
    Dalton Trans 42:10404-8. 2013
    ....
  33. doi request reprint [Ln(BH(4))(2)(THF)(2)] (Ln = Eu, Yb)-A Highly Luminescent Material. Synthesis, Properties, Reactivity, and NMR Studies
    Sebastian Marks
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstraße 15, 76131 Karlsruhe, Germany
    J Am Chem Soc 134:16983-6. 2012
    ..They show significantly lower or no luminescence. Using the diamagnetic compound [{(Me(3)SiNPPh(2))(2)CH}Yb(BH(4))(THF)(2)], we performed a 2D (31)P/(171)Yb HMQC experiment...
  34. ncbi request reprint Synthesis, reactivity and applications of zinc-zinc bonded complexes
    Tianshu Li
    Institut fur Anorganische Chemie, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany
    Chem Soc Rev 41:3759-71. 2012
    ..Very recently, the potential capability of [Zn(2)(η(5)-Cp*)(2)] to serve as a suitable catalyst in hydroamination reactions was demonstrated. Finally, the recent work on Cd-Cd bonded coordination compounds is reviewed...
  35. doi request reprint Chiral benzamidinate ligands in rare-Earth-metal coordination chemistry
    Paul Benndorf
    Institut fur Anorganische Chemie, Karlsruher Institut fur Technologie KIT, Engesserstrasse 15, 76131 Karlsruhe Germany, Fax 49 721 608 44854
    Chemistry 18:14454-63. 2012
    ..A clear dependence of the rate of reaction and enantioselectivity on the ionic radius was observed, which showed higher reaction rates but poorer enantioselectivities for the yttrium compound...