Itaru OsakaSummaryAffiliation: Hiroshima University Country: Japan Publications
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Publications
Synthesis, characterization, and transistor and solar cell applications of a naphthobisthiadiazole-based semiconducting polymerItaru Osaka
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1 4 1 Kagamiyama, Higashi Hiroshima, Hiroshima 739 8527, Japan
J Am Chem Soc 134:3498-507. 2012..These results demonstrate great promise for using NTz as a bulding unit for high-performance semiconducting polymers for both transistors and solar cells...
High-mobility semiconducting naphthodithiophene copolymersItaru Osaka
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1 4 1 Kagamiyama, Higashi Hiroshima, Hiroshima 739 8527, Japan
J Am Chem Soc 132:5000-1. 2010..We believe that these findings will give new insight into the design of new organic semiconducting materials and that the present polymers are promising materials for printable electronics...
Impact of isomeric structures on transistor performances in naphthodithiophene semiconducting polymersItaru Osaka
Department of Chemistry, Graduate School of Engineering, Hiroshima University, 1 4 1 Kagamiyama, Higashi Hiroshima, Hiroshima 739 8527, Japan
J Am Chem Soc 133:6852-60. 2011..We thus propose that both the molecular shapes and the electronic structures are important factors to be considered when designing high performance semiconducting polymers...
Thienoacene-based organic semiconductorsKazuo Takimiya
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima, Japan
Adv Mater 23:4347-70. 2011..The discussion provides insight into new molecular design strategies for the development of superior organic semiconductors...
Linear- and angular-shaped naphthodithiophenes: selective synthesis, properties, and application to organic field-effect transistorsShoji Shinamura
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima 739 8527, Japan
J Am Chem Soc 133:5024-35. 2011..These results indicate that the present NDT cores, in particular the linear-shaped, centrosymmetric naphtho[2,3-b:6,7-b']dithiophene, are promising building blocks for the development of organic semiconducting materials...
Borylation on Benzo[1,2-b:4,5-b']- and Naphtho[1,2-b:5,6-b']dichalcogenophenes: Different Chalcogene Atom Effects on Borylation Reaction Depending on Fused Ring StructureMasahiro Nakano
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima 739 8527, Japan, and Emergent Molecular Function Research Team, RIKEN Advanced Science Institute, Wako, Saitama 351 0198, Japan
Org Lett 14:5448-51. 2012..e., benzo[1,2-b:4,5-b']- and naphtho[1,2-b:5,6-b']dichalcogenophenes, were examined, and it was observed that the reaction efficiency largely depends on the fused ring structure and chalcogenophene ring...
Diphenyl Derivatives of Dinaphtho[2,3-b:2',3'-f]thieno[3,2-b]thiophene: Organic Semiconductors for Thermally Stable Thin-Film TransistorsMyeong Jin Kang
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima, Hiroshima 739 8527 Japan
ACS Appl Mater Interfaces 5:2331-6. 2013..For its excellent thermal stability with good FET characteristics, 2,9-DPh-DNTT can be a useful organic semiconductor in various applications that require processes at high temperatures...
Orthogonally functionalized naphthodithiophenes: selective protection and borylationShoji Shinamura
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima 739 8527, Japan
Org Lett 14:4718-21. 2012..The same protocol is applicable to other isomeric naphthodithiophenes (NDTs), which affords a set of key building blocks for the development of elaborated functional π-materials...
Isomerically pure anthra[2,3-b:6,7-b']-difuran (anti-ADF), -dithiophene (anti-ADT), and -diselenophene (anti-ADS): selective synthesis, electronic structures, and application to organic field-effect transistorsMasahiro Nakano
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima 739 8527, Japan
J Org Chem 77:8099-111. 2012..We also tested the diphenyl derivatives of anti-ADF, -ADT, and -ADS as the active material for OFET devices, which showed high mobility of up to 1.3 cm(2) V(-1) s(-1)...
[2,2']Bi[naphtho[2,3-b]furanyl]: a versatile organic semiconductor with a furan-furan junctionKazuki Niimi
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima 739 8527, Japan
Chem Commun (Camb) 48:5892-4. 2012..In the devices, the material acted as a p-type semiconductor, showing moderately high mobility in OFETs, good photo conversion efficiency in OPVs, and blue-green emission in OLETs...
Angular-shaped naphthodifurans, naphtho[1,2-b;5,6-b']- and naphtho[2,1-b;6,5-b']-difuran: are they isoelectronic with chrysene?Masahiro Nakano
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima 739 8527, Japan
Chem Commun (Camb) 48:5671-3. 2012..The difference in electronic structure in the ground state can be explained by distinct electronic perturbation from the outermost aromatic rings...
General synthesis of dinaphtho[2,3-b:2',3'-f]thieno[3,2-b]thiophene (DNTT) derivativesKazuki Niimi
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima 739 8527 Japan
Org Lett 13:3430-3. 2011..Thus, newly developed derivatives of DNTT showed very high field effect mobility in the vapor-processed field-effect transistors up to 8 cm(2) V(-1) s(-1)...
Dianthra[2,3-b:2',3'-f]thieno[3,2-b]thiophene (DATT): synthesis, characterization, and FET characteristics of new π-extended heteroarene with eight fused aromatic ringsKazuki Niimi
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima 739 8527, Japan
J Am Chem Soc 133:8732-9. 2011....
Largely π-extended thienoacenes with internal thieno[3,2-b]thiophene substructures: synthesis, characterization, and organic field-effect transistor applicationsTatsuya Yamamoto
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima 739 8527, Japan
Org Lett 14:4914-7. 2012....
Synthesis and characterization of benzo[1,2-b:3,4-b':5,6-b'']trithiophene (BTT) oligomersTomoya Kashiki
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi Hiroshima 739 8527, Japan
J Org Chem 76:4061-70. 2011....
