Research Topics
| Takashi SakaiSummaryAffiliation: Eisai Co Country: Japan Publications
| Collaborators
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Detail Information
Publications
Pladienolides, new substances from culture of Streptomyces platensis Mer-11107. I. Taxonomy, fermentation, isolation and screeningTakashi Sakai
Tsukuba Research Laboratories, Eisai Co, Ltd, 5 1 3, Tokodai, Tsukuba, Ibaraki 300 2635, Japan
J Antibiot (Tokyo) 57:173-9. 2004..They also demonstrated growth-inhibitory activity against U251 human glioma cells in vitro. Pladienolides are highly potent inhibitors of both hypoxia signals and cancer cell proliferation, and thus may be useful as antitumor agents...
Stereochemistry of pladienolide BNaoki Asai
Tsukuba Research Laboratories, Eisai Co, Ltd, Tokodai, Tsukuba, Ibaraki, Japan
J Antibiot (Tokyo) 60:364-9. 2007..The absolute configurations at ten chiral centers were determined on the basis of spectral data of pladienolide B and its chemical transformation products...
Pladienolides, new substances from culture of Streptomyces platensis Mer-11107. II. Physico-chemical properties and structure elucidationTakashi Sakai
Tsukuba Research Laboratories, Eisai Co, Ltd, 5 1 3, Tokodai, Tsukuba, Ibaraki 300 2635, Japan
J Antibiot (Tokyo) 57:180-7. 2004..Pladienolides are unusual 12-membered macrolides having a long side chain at the carbon that bears a lactone oxygen...
Pladienolides, new substances from culture of Streptomyces platensis Mer-11107. III. In vitro and in vivo antitumor activitiesYoshiharu Mizui
Tsukuba Research Laboratories, Eisai Co, Ltd, 5 1 3 Tokodai, Tsukuba, Ibaraki 300 2635, Japan
J Antibiot (Tokyo) 57:188-96. 2004..For the reason of their novel mechanism of action and excellent in vivo efficacy, pladienolides appear to have major potential for use in cancer treatment...
5-[4-(1-Hydroxyethyl)phenyl]-10,15,20-triphenylporphyrin as a probe of the transition-state conformation in hydrolase-catalyzed enantioselective transesterificationsTadashi Ema
Department of Applied Chemistry, Faculty of Engineering, Okayama University, Tsushima, Okayama 700 8530, Japan
J Org Chem 67:2144-51. 2002....
Highly enantioselective and efficient synthesis of methyl (R)-o-chloromandelate with recombinant E. coli: toward practical and green access to clopidogrelTadashi Ema
Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Okayama 700 8530, Japan
Org Biomol Chem 5:1175-6. 2007..0 M) with recombinant E. coli overproducing a versatile carbonyl reductase...
Potential role for astroglial D-amino acid oxidase in extracellular D-serine metabolism and cytotoxicityHwan Ki Park
Department of Gene Regulatorics, The Institute for Enzyme Research, The University of Tokushima, Tokushima 770-8503, Japan
J Biochem (Tokyo) 139:295-304. 2006..These results support the proposal that astroglial DAO plays an important role in metabolizing a neuromodulator, D-serine...
Role of dihydropyrimidine dehydrogenase inhibitory fluoropyrimidine against non-small cell lung cancer--in correlation with the tumoral expression of thymidylate synthase and dihydropyrimidine dehydrogenaseKentarou Inoue
Depatment of Thoracic Surgery, Mie University School of Medicine, 2-174 Edobashi, Tsu, Mie 514-8507, Japan
Lung Cancer 49:47-54. 2005..DPD inhibitory fluoropyrimidine and examination of the tumoral expression of DPD might be a promising chemotherapeutic strategy in NSCLC...
Lipase-catalyzed resolution of (2R*,3S*)- and (2R*,3R*)-3-methyl-3-phenyl-2-aziridinemethanol at low temperatures and determination of the absolute configurations of the four stereoisomersTakashi Sakai
Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3 1 1 Tsushima naka, Okayama 700 8530, Japan
J Org Chem 70:1369-75. 2005..The absolute configuration of (2S,3S)-3 was determined by X-ray analysis of the corresponding N-(S)-2-(6-methoxy-2-naphthyl)propanoyl derivative (S,S,S)-13...
Chk2 is a tumor suppressor that regulates apoptosis in both an ataxia telangiectasia mutated (ATM)-dependent and an ATM-independent mannerAtsushi Hirao
Department of Medical Biophysics, Ontario Cancer Institute, University of Toronto, Ontario M5G 2C1, Canada
Mol Cell Biol 22:6521-32. 2002..ATR may thus selectively contribute to p53-mediated apoptosis. These data indicate that distinct pathways regulate the activation of p53 leading to cell cycle arrest or apoptosis...
Chiral selector with multiple hydrogen-bonding sites in a macrocyclic cavityTadashi Ema
Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Okayama, Japan
Org Lett 10:2365-8. 2008..Various organic solvents could be used as the mobile phase to optimize the resolution efficiency of CSPs, and in some cases, even MeCN, MeOH, and CO(2) could be used for the complete resolution of enantiomers...
