Mirco Natali

Summary

Affiliation: University of Ferrara
Country: Italy

Publications

  1. ncbi Efficient photocatalytic hydrogen generation from water by a cationic cobalt(II) porphyrin
    Mirco Natali
    Dipartimento di Scienze Chimiche e Farmaceutiche, Universita degli Studi di Ferrara, Via Fossato di Mortara 17 19, 44121 Ferrara, Italy
    Chem Commun (Camb) 50:1842-4. 2014
  2. doi Porphyrin-cobaloxime dyads for photoinduced hydrogen production: investigation of the primary photochemical process
    Mirco Natali
    Dipartimento di Scienze Chimiche e Farmaceutiche, Universita degli Studi di Ferrara, Via Fossato di Mortara 17 19, 44121 Ferrara, Italy
    Photochem Photobiol Sci 12:1749-53. 2013
  3. doi Photocatalytic hydrogen evolution with a self-assembling reductant-sensitizer-catalyst system
    Mirco Natali
    Department of Chemical and Pharmaceutical Sciences, University of Ferrara, Via Fossato di Mortara 17 19, 44121 Ferrara, Italy
    Chemistry 19:9261-71. 2013
  4. doi Is [Co4(H2O)2(α-PW9O34)2](10-) a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments
    Mirco Natali
    Dipartimento di Chimica, Universita di Ferrara, and Centro Interuniversitario per la Conversione Chimica dell Energia Solare, sez di Ferrara, Via L Borsari 46, 44121 Ferrara, Italy
    Chem Commun (Camb) 48:8808-10. 2012
  5. ncbi Photoinduced electron transfer across molecular bridges: electron- and hole-transfer superexchange pathways
    Mirco Natali
    Dipartimento di Scienze Chimiche e Farmacautiche, Universita di Ferrara, and Centro Interuniversitario per la Conversione Chimica dell Energia Solare SolarChem, sez di Ferrara, Via Fossato di Mortara 17 19, 44121 Ferrara, Italy
    Chem Soc Rev 43:4005-18. 2014
  6. doi Photoinduced water oxidation by a tetraruthenium polyoxometalate catalyst: ion-pairing and primary processes with Ru(bpy)3(2+) photosensitizer
    Mirco Natali
    Dipartimento di Chimica and Centro Interuniversitario per la Conversione Chimica dell Energia Solare SOLARCHEM, Sezione di Ferrara, Via Borsari 46, 44121 Ferrara, Italy
    Inorg Chem 51:7324-31. 2012

Detail Information

Publications6

  1. ncbi Efficient photocatalytic hydrogen generation from water by a cationic cobalt(II) porphyrin
    Mirco Natali
    Dipartimento di Scienze Chimiche e Farmaceutiche, Universita degli Studi di Ferrara, Via Fossato di Mortara 17 19, 44121 Ferrara, Italy
    Chem Commun (Camb) 50:1842-4. 2014
    ..Spectroscopic investigation of the system by stationary and time-resolved techniques enables a complete characterization of the photoinduced dynamics...
  2. doi Porphyrin-cobaloxime dyads for photoinduced hydrogen production: investigation of the primary photochemical process
    Mirco Natali
    Dipartimento di Scienze Chimiche e Farmaceutiche, Universita degli Studi di Ferrara, Via Fossato di Mortara 17 19, 44121 Ferrara, Italy
    Photochem Photobiol Sci 12:1749-53. 2013
    ..Three porphyrin-cobaloxime dyads, suitable for application in photoinduced hydrogen generation with sacrificial donors, are characterized by ultrafast spectroscopy in order to clarify the primary photochemical events. ..
  3. doi Photocatalytic hydrogen evolution with a self-assembling reductant-sensitizer-catalyst system
    Mirco Natali
    Department of Chemical and Pharmaceutical Sciences, University of Ferrara, Via Fossato di Mortara 17 19, 44121 Ferrara, Italy
    Chemistry 19:9261-71. 2013
    ..At high sacrificial donor concentration, the maximum turnover number (TON=352 or 117, relative to the sensitizer or the catalyst, respectively) is eventually limited by hydrogenation of both sensitizer (chlorin formation) and catalyst...
  4. doi Is [Co4(H2O)2(α-PW9O34)2](10-) a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments
    Mirco Natali
    Dipartimento di Chimica, Universita di Ferrara, and Centro Interuniversitario per la Conversione Chimica dell Energia Solare, sez di Ferrara, Via L Borsari 46, 44121 Ferrara, Italy
    Chem Commun (Camb) 48:8808-10. 2012
    ..Water oxidation catalysts: evolution of [Co(4)(H(2)O)(2)(α-PW(9)O(34))(2)](10-) to catalytically active species is assessed by laser flash photolysis in sacrificial photocatalytic cycles with Ru(bpy)(3)(2+) as a photosensitizer...
  5. ncbi Photoinduced electron transfer across molecular bridges: electron- and hole-transfer superexchange pathways
    Mirco Natali
    Dipartimento di Scienze Chimiche e Farmacautiche, Universita di Ferrara, and Centro Interuniversitario per la Conversione Chimica dell Energia Solare SolarChem, sez di Ferrara, Via Fossato di Mortara 17 19, 44121 Ferrara, Italy
    Chem Soc Rev 43:4005-18. 2014
    ..Finally, conceptual analogies between bridge effects in photoinduced electron transfer and optical intervalence transfer are outlined. Selected experimental examples, instrumental to illustration of the principles, are discussed. ..
  6. doi Photoinduced water oxidation by a tetraruthenium polyoxometalate catalyst: ion-pairing and primary processes with Ru(bpy)3(2+) photosensitizer
    Mirco Natali
    Dipartimento di Chimica and Centro Interuniversitario per la Conversione Chimica dell Energia Solare SOLARCHEM, Sezione di Ferrara, Via Borsari 46, 44121 Ferrara, Italy
    Inorg Chem 51:7324-31. 2012
    ..45 turnovers in Ru(bpy)(3)(3+) reduction. With the assumption that one molecule of oxygen released after four hole-scavenging events, this translates into a very high average turnover frequency (280 s(-1)) for oxygen production...