Research Topics
Species | Stefania AbbruzzettiSummaryAffiliation: University of Parma Country: Italy Publications
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Detail Information
Publications
Oxygen and nitric oxide rebinding kinetics in nonsymbiotic hemoglobin AHb1 from Arabidopsis thalianaStefania Abbruzzetti
Dipartimento di Fisica, Universita degli Studi di Parma, Parma, Italy
IUBMB Life 63:1094-100. 2011..However, the accessibility to this site seems to be strongly ligand-dependent, being lower for O2 and higher for NO...
Different roles of protein dynamics and ligand migration in non-symbiotic hemoglobins AHb1 and AHb2 from Arabidopsis thalianaStefano Bruno
Dipartimento di Biochimica e Biologia Molecolare, Universita degli Studi di Parma, Italy
Gene 398:224-33. 2007..This finding strongly supports the idea that they have distinct physiological functions...
Ligand migration in nonsymbiotic hemoglobin AHb1 from Arabidopsis thalianaStefania Abbruzzetti
Dipartimento di Fisica, Universita degli Studi di Parma, NEST CNR INFM, Parma, Italy
J Phys Chem B 111:12582-90. 2007..This finding may be of relevance to the physiological NO dioxygenase activity of this protein, which requires sequential binding of two substrates, NO and O2, to the heme...
Structural plasticity and functional implications of internal cavities in distal mutants of type 1 non-symbiotic hemoglobin AHb1 from Arabidopsis thalianaSerena Faggiano
Dipartimento di Biochimica e Biologia Molecolare, Universita degli Studi di Parma, Parma, Italy
J Phys Chem B 113:16028-38. 2009..Overall, data are consistent with the putative NO-dioxygenase activity attributed to AHb1...
The reactivity with CO of AHb1 and AHb2 from Arabidopsis thaliana is controlled by the distal HisE7 and internal hydrophobic cavitiesStefano Bruno
Dipartimento di Biochimica e Biologia Molecolare, Universita degli Studi di Parma, Parma, Italy
J Am Chem Soc 129:2880-9. 2007..Overall, these kinetic and structural data are consistent with the putative NO-dioxygenase activity previously attributed to AHb1, whereas the role of AHb2 remains elusive...
Histidine E7 dynamics modulates ligand exchange between distal pocket and solvent in AHb1 from Arabidopsis thalianaFrancesca Spyrakis
Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Universita degli Studi di Parma, Italy
J Phys Chem B 115:4138-46. 2011..Overall, these findings provide evidence supporting the functional implications of the conformational rearrangement found for the distal His in AHb1, which mimics the gating role proposed for the same residue in myoglobin...
Characterization of ligand migration mechanisms inside hemoglobins from the analysis of geminate rebinding kineticsStefania Abbruzzetti
Dipartimento di Fisica Università degli Studi di Parma, Parma, Italy
Methods Enzymol 437:329-45. 2008....
Ligand migration through the internal hydrophobic cavities in human neuroglobinStefania Abbruzzetti
Dipartimento di Fisica, National Enterprise for nanoScience and nanoTechnology CNR INFM, Universita degli Studi di Parma, 43100 Parma, Italy
Proc Natl Acad Sci U S A 106:18984-9. 2009..Overall, data are consistent with the presence of a discrete system of docking sites, possibly acting as reservoirs for the putative cosubstrates and for other reactive species involved in the physiologically relevant reaction...
Oxygen binding to Arabidopsis thaliana AHb2 nonsymbiotic hemoglobin: evidence for a role in oxygen transportFrancesca Spyrakis
Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Universita degli Studi di Parma, Italy
IUBMB Life 63:355-62. 2011..Overall, our results are consistent with a role for AHb2 as an oxygen carrier, as recently proposed on the basis of experiments on AHb2-overexpressing mutants of A. thaliana...
Ligand migration and hexacoordination in type 1 non-symbiotic rice hemoglobinNitin Kumar Bisht
Dipartimento di Fisica, Universita degli Studi di Parma, Parma, Italy
Biochim Biophys Acta 1814:1042-53. 2011..This article is part of a Special Issue entitled: Protein Dynamics: Experimental and Computational Approaches...
Time-resolved methods in Biophysics. 2. Monitoring haem proteins at work with nanosecond laser flash photolysisStefania Abbruzzetti
Dipartimento di Fisica, , Parma, Italy
Photochem Photobiol Sci 5:1109-20. 2006..The comparison between time courses recorded on haemoglobins in solution and encapsulated in silica gels allows for the highlighting of different interplays between protein dynamics and ligand migration...
Ligation tunes protein reactivity in an ancient haemoglobin: kinetic evidence for an allosteric mechanism in Methanosarcina acetivorans protoglobinStefania Abbruzzetti
Dipartimento di Fisica, Universita degli Studi di Parma, Parma, Italy
PLoS ONE 7:e33614. 2012..The equilibrium is shifted towards the species with low binding (and high dissociation) rates for the unliganded molecules. A quantitative model is proposed to describe the observed carbonylation kinetics...
Low affinity PEGylated hemoglobin from Trematomus bernacchii, a model for hemoglobin-based blood substitutesDaniela Coppola
Department of Biochemistry and Molecular Biology, University of Parma, Parma, Italy
BMC Biochem 12:66. 2011..These recent findings call for the biotechnological development of stable, low-affinity PEGylated hemoglobins with low NO dioxygenase reactivity...
Determination of microscopic rate constants for CO binding and migration in myoglobin encapsulated in silica gelsSilvia Sottini
Dipartimento di Fisica, , Parco Area delle Scienze 7/A, , Parco Area delle Scienze 23/A, 43100 Parma, Italy
J Phys Chem B 109:19523-8. 2005..Microscopic rates and activation barriers were estimated using a four-state model...
Geminate rebinding in R-state hemoglobin: kinetic and computational evidence for multiple hydrophobic pocketsSilvia Sottini
Dipartimento di Fisica, , Parco Area delle Scienze 7/A, 43100 Parma, Italy
J Am Chem Soc 127:17427-32. 2005..Furthermore, the connection between the two xenon sites is relatively open, explaining why the decreased mobility of the protein with viscosity only slightly perturbs the energetics of ligand migration between the two sites...
Ligand reactivity and allosteric regulation of hemoglobin-based oxygen carriersLuca Ronda
Department of Biochemistry and Molecular Biology, University of Parma, Parma, Italy
Biochim Biophys Acta 1784:1365-77. 2008....
Acid-induced unfolding of myoglobin triggered by a laser pH jump methodStefania Abbruzzetti
Dipartimento di Fisica, , Parco Area delle Scienze 7/A, 43100 Parma, Italy
Photochem Photobiol Sci 5:621-8. 2006..The complete time course of the unfolding kinetics, spanning a range from milliseconds to several seconds, could be accurately reproduced by monitoring absorbance changes in the visible spectrum at 633 nm...
Molten globule formation in apomyoglobin monitored by the fluorescent probe Nile RedEugenia Polverini
Dipartimento di Fisica, , Viale G. P. Usberti 7/A, 43100 Parma, Italy
Biochemistry 45:5111-21. 2006..Under these conditions, NR is positioned in a different orientation, reaching a more hydrophobic environment in agreement with the spectroscopic data...
Kinetics of histidine dissociation from the heme Fe(III) in N-fragment (residues 1-56) of cytochrome cStefania Abbruzzetti
Dipartimento di Fisica, , Parco Area delle Scienze 7/A 43100 Parma, Italy
Protein J 23:519-27. 2004..This underlines the role played by the missing segment (residues 57-104) peptide chain in discriminating deligation of the "nonnative" His from the sixth coordination position of the metal...
Heterogeneous kinetics of the carbon monoxide association and dissociation reaction to nitrophorin 4 and 7 coincide with structural heterogeneity of the gate-loopStefania Abbruzzetti
Dipartimento di Fisica, Universita degli Studi di Parma, viale delle Scienze 7A, I 43124, Parma, Italy
J Am Chem Soc 134:9986-98. 2012....
Photoswitching of E222Q GFP mutants: "concerted" mechanism of chromophore isomerization and protonationStefania Abbruzzetti
Dipartimento di Fisica, Universita di Parma, Viale G P Usberti 7a, 43100, Parma, Italy
Photochem Photobiol Sci 9:1307-19. 2010..Such a "concerted" mechanism is, in our opinion, at the basis of efficient photochromic behavior and might be activated by the E222Q mutation...
Kinetics of acid-induced spectral changes in the GFPmut2 chromophoreStefania Abbruzzetti
Dipartimento di Fisica, , Parco Area delle Scienze 7/A, 43100 Parma, Italy
J Am Chem Soc 127:626-35. 2005..A kinetic model suggests that, in addition to protecting the chromophore from the solvent, His148 may act as the primary acceptor for the protons on the way to the chromophore...
A photochromic bacterial photoreceptor with potential for super-resolution microscopyAba Losi
Dipartimento di Fisica, Universita di Parma, viale delle Scienze 7A, 43124 Parma, Italy
Photochem Photobiol Sci 12:231-5. 2013..We demonstrate Fluorescence PhotoActivation Localization Microscopy (FPALM) studies of live Escherichia coli cells, expressing YtvA molecules...
