Pierangelo Metrangolo

Summary

Affiliation: Politecnico di Milano
Country: Italy

Publications

  1. doi request reprint Metal-bound halogen atoms in crystal engineering
    Pierangelo Metrangolo
    Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131 Milano, Italy
    Chem Commun (Camb) 49:1783-5. 2013
  2. ncbi request reprint Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels
    Javier Martí-Rujas
    Center for Nano Science and Istituto Italiano di Tecnologia, via Pascoli 70 3, 20133 Milano, Italy
    Chem Commun (Camb) 48:8207-9. 2012
  3. doi request reprint Chemistry. Halogen versus hydrogen
    P Metrangolo
    Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Milan, 20131, Italy
    Science 321:918-9. 2008
  4. ncbi request reprint Nonporous organic solids capable of dynamically resolving mixtures of diiodoperfluoroalkanes
    Pierangelo Metrangolo
    Laboratory of Nanostructured Fluorinated Materials, Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131 Milan, Italy
    Science 323:1461-4. 2009
  5. doi request reprint Halogen bonding and pharmaceutical cocrystals: the case of a widely used preservative
    Michele Baldrighi
    NFMLab, Department of Chemistry, Politecnico di Milano, Via L Mancinelli 7, 20131 Milan, Italy
    Mol Pharm 10:1760-72. 2013
  6. pmc The Halogen Bond
    Gabriella Cavallo
    Laboratory of Nanostructured Fluorinated Materials NFMLab, Department of Chemistry, Materials and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, I 20131 Milano, Italy
    Chem Rev 116:2478-601. 2016
  7. doi request reprint 2-Iodo-imidazolium receptor binds oxoanions via charge-assisted halogen bonding
    Massimo Cametti
    NFMLab Department of Chemistry, Materials and Chemical Engineering Giulio Natta, Politecnico di Milano, Via Mancinelli 7, I 20131, Milan, Italy
    Org Biomol Chem 10:1329-33. 2012
  8. doi request reprint Dynamic Characterization of Crystalline Supramolecular Rotors Assembled through Halogen Bonding
    Luca Catalano
    Laboratory of Nanostructured Fluorinated Materials NFMLab, Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131 Milano, Italy
    J Am Chem Soc 137:15386-9. 2015
  9. doi request reprint Halogen bond: a long overlooked interaction
    Gabriella Cavallo
    Laboratory of Nanostructured Fluorinated Materials NFMLab, Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131, Milano, Italy
    Top Curr Chem 358:1-17. 2015
  10. doi request reprint Azobenzene-based difunctional halogen-bond donor: towards the engineering of photoresponsive co-crystals
    Marco Saccone
    NFMLab DCMIC Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, IT 20131 Milano, Italy
    Acta Crystallogr B Struct Sci Cryst Eng Mater 70:149-56. 2014

Collaborators

  • Olli Ikkala
  • Fabio Ganazzoli
  • Ludovico Valli
  • Gabriele Giancane
  • Giuseppina Raffaini
  • Miguel A Garcia-Garibay
  • Jonathan W Steed
  • Massimo Cametti
  • Gabriella Cavallo
  • Giancarlo Terraneo
  • Giuseppe Resnati
  • Tullio Pilati
  • Luca Catalano
  • Roberto Milani
  • Arianna Bertolani
  • Arri Priimagi
  • Ilaria Tirotta
  • Marco Saccone
  • Michele Baldrighi
  • Lorenzo Meazza
  • Javier Martí-Rujas
  • Antonio Abate
  • Lisa Pirrie
  • Loic Stefan
  • Nikolay Houbenov
  • Johannes S Haataja
  • Salvador Pérez-Estrada
  • Maria Grazia Bruzzone
  • Chiara Cordiglieri
  • Lara Gazzera
  • Giuseppe Baselli
  • Francesca Baldelli Bombelli
  • Fulvio Baggi
  • Ileana Zucca
  • Alfonso Mastropietro
  • Michele R Chierotti
  • Katharina Fucke
  • Jonathan A Foster
  • Roberto Gobetto
  • Giovanni Marras
  • Maurizio Ursini
  • Hannes Neukirch
  • Melchiorre F Parisi
  • Archan Dey
  • Luca Colombo
  • Jian Lu
  • Maurizio Sansotera
  • Manuel Brischetto
  • Stefano Radice
  • Kari Rissanen
  • Manu Lahtinen

Detail Information

Publications22

  1. doi request reprint Metal-bound halogen atoms in crystal engineering
    Pierangelo Metrangolo
    Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131 Milano, Italy
    Chem Commun (Camb) 49:1783-5. 2013
    ..which highlights the very rich supramolecular behaviour of halogen atoms. Their findings appear even more timely when viewed in light of the recently proposed IUPAC definition of the halogen bond...
  2. ncbi request reprint Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels
    Javier Martí-Rujas
    Center for Nano Science and Istituto Italiano di Tecnologia, via Pascoli 70 3, 20133 Milano, Italy
    Chem Commun (Camb) 48:8207-9. 2012
    ..The framework is able to host various guest molecules with a diverse set of steric demands and substitution patterns, and survives single-crystal-to-single-crystal guest exchanges from liquid and gas phases...
  3. doi request reprint Chemistry. Halogen versus hydrogen
    P Metrangolo
    Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Milan, 20131, Italy
    Science 321:918-9. 2008
  4. ncbi request reprint Nonporous organic solids capable of dynamically resolving mixtures of diiodoperfluoroalkanes
    Pierangelo Metrangolo
    Laboratory of Nanostructured Fluorinated Materials, Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131 Milan, Italy
    Science 323:1461-4. 2009
    ..Heating liberates the DIPFAs and regenerates the original salt lattice, highlighting the practical potential for the system in separation applications...
  5. doi request reprint Halogen bonding and pharmaceutical cocrystals: the case of a widely used preservative
    Michele Baldrighi
    NFMLab, Department of Chemistry, Politecnico di Milano, Via L Mancinelli 7, 20131 Milan, Italy
    Mol Pharm 10:1760-72. 2013
    ..The cocrystal involving the GRAS excipient CaCl2 has superior powder flow characteristics compared to the pure IPBC, representing a promising solution to the handling issues related to the manufacturing of products containing IPBC...
  6. pmc The Halogen Bond
    Gabriella Cavallo
    Laboratory of Nanostructured Fluorinated Materials NFMLab, Department of Chemistry, Materials and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, I 20131 Milano, Italy
    Chem Rev 116:2478-601. 2016
    ..The specific advantages brought up by a design based on the use of the halogen bond will be demonstrated in quite different fields spanning from material sciences to biomolecular recognition and drug design. ..
  7. doi request reprint 2-Iodo-imidazolium receptor binds oxoanions via charge-assisted halogen bonding
    Massimo Cametti
    NFMLab Department of Chemistry, Materials and Chemical Engineering Giulio Natta, Politecnico di Milano, Via Mancinelli 7, I 20131, Milan, Italy
    Org Biomol Chem 10:1329-33. 2012
    ..Phosphate, in particular, binds to 1 with an association constant of ca. 10(3) M(-1), which is particularly high for a single X-bond. A remarkably short C-I···O(-) contact is observed in the structure of the salt 1·H(2)PO(4)(-)...
  8. doi request reprint Dynamic Characterization of Crystalline Supramolecular Rotors Assembled through Halogen Bonding
    Luca Catalano
    Laboratory of Nanostructured Fluorinated Materials NFMLab, Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131 Milano, Italy
    J Am Chem Soc 137:15386-9. 2015
    ..Line shape analysis of quadrupolar echo (2)H NMR measurements in selected examples indicated rotational trajectories consistent with the 3-fold or 6-fold symmetric potential of the rotator. ..
  9. doi request reprint Halogen bond: a long overlooked interaction
    Gabriella Cavallo
    Laboratory of Nanostructured Fluorinated Materials NFMLab, Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131, Milano, Italy
    Top Curr Chem 358:1-17. 2015
    ....
  10. doi request reprint Azobenzene-based difunctional halogen-bond donor: towards the engineering of photoresponsive co-crystals
    Marco Saccone
    NFMLab DCMIC Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, IT 20131 Milano, Italy
    Acta Crystallogr B Struct Sci Cryst Eng Mater 70:149-56. 2014
    ....
  11. pmc Tetra-phenyl-phospho-nium iodide-1,3,5-tri-fluoro-2,4,6-tri-iodo-benzene-methanol (3/4/1)
    Gabriella Cavallo
    NFMLab, Department of Chemistry, Materials and Chemical Engineering, Giulio Natta, Politecnico di Milano, Via Mancinelli, 7, I 20131 Milano, Italy
    Acta Crystallogr Sect E Struct Rep Online 69:o865-6. 2013
    ..The crystal studied was refined as a perfect inversion twin. ..
  12. pmc (Tris{2-[2-(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)eth-oxy]eth-yl}amine)-potassium iodide
    Gabriella Cavallo
    NFMLab, Department of Chemistry, Materials and Chemical Engineering, G Natta, Politecnico di Milano, Via Mancinelli, 7, I 20131 Milano, Italy
    Acta Crystallogr Sect E Struct Rep Online 69:m284-5. 2013
    ..28 (14) and 75.20 (19)°] to the other two rings. The coordination sphere of the K(+) cation is composed of the six O atoms, the N atom and an F atom in the ortho position of one of the rings...
  13. pmc [5,11,17,23-Tetra-tert-butyl-25,27-(3,6-dioxaoctan-1,8-di-oxy)-26,28-bis-(pyridin-2-ylmeth-oxy)calix[4]arene]sodium iodide-1,2,4,5-tetra-fluoro-3,6-diiodo-benzene-methanol (2/3/4)
    Gabriella Cavallo
    NFMLab, Department of Chemistry, Materials and Chemical Engineering, G Natta, Politecnico di Milano, Via Mancinelli, 7, I 20131 Milano, Italy
    Acta Crystallogr Sect E Struct Rep Online 69:m236-7. 2013
    ....
  14. pmc 1,3-Bis(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)-2,2-bis-[(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)meth-yl]propane
    Gabriella Cavallo
    NFMLab, Department of Chemistry, Materials and Chemical Engineering, G Natta, Politecnico di Milano, Via Mancinelli, 7, I 20131 Milano, Italy
    Acta Crystallogr Sect E Struct Rep Online 69:o579-80. 2013
    ..In addition, π-π stacking inter-actions between tetra-fluoro-iodo-phenyl (TFIP) groups and five short F⋯F inter-actions are present...
  15. ncbi request reprint Halogen bonding: a general route in anion recognition and coordination
    Gabriella Cavallo
    NFMLab DCMIC G Natta Politecnico di Milano, 7, Via Mancinelli, I 20131 Milan, Italy
    Chem Soc Rev 39:3772-83. 2010
    ..The interaction allows for several other anions to self-assemble with halocarbons and mention is also given to the halogen bonding-based coordination of halides, polycyano- and polyoxometallates (72 references)...
  16. ncbi request reprint Dimensional encapsulation of I(-)...I(2)...I(-) in an organic salt crystal matrix
    Antonio Abate
    NFMLab and D C M I C Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131 Milan, Italy
    Chem Commun (Camb) 46:2724-6. 2010
    ..I-I...I(-), which matches in length to the chosen dication...
  17. pmc The halogen-bonded adduct 1,4-bis(pyri-din-4-yl)buta-1,3-diyne-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexa-deca-fluoro-1,8-diiodo-octane (1/1)
    Gabriella Cavallo
    NFMLab, Department of Chemistry, Materials and Chemical Engineering, G Natta, Politecnico di Milano, Via Mancinelli, 7, I 20131 Milano, Italy
    Acta Crystallogr Sect E Struct Rep Online 69:o328-9. 2013
    ..The topology of the network is a nice example of the paradigm of the expansion of ditopic starting modules; the XB leads to the construction of infinite supramolecular chains along [2-11] formed by alternating XB donors and acceptors...
  18. doi request reprint Halogen-bonding-triggered supramolecular gel formation
    Lorenzo Meazza
    NFMLab DCMIC Giulio Natta, Politecnico di Milano, Via L Mancinelli 7 IT 20131, Italy
    Nat Chem 5:42-7. 2013
    ..Using this concept, we have prepared a halogen bond donor bis(urea) gelator that forms co-gels with halogen bond acceptors...
  19. doi request reprint Atomistic simulation of hydrophobin HFBII conformation in aqueous and fluorous media and at the water/vacuum interface
    Giuseppina Raffaini
    Dipartimento di Chimica, Materiali ed Ingegneria Chimica Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131 Milano, Italy Unità Politecnico, INSTM, Piazza Leonardo da Vinci 32, 20133 Milano, Italy Electronic address
    J Mol Graph Model 63:8-14. 2016
    ....
  20. pmc Supramolecular amplification of amyloid self-assembly by iodination
    Arianna Bertolani
    Laboratory of Nanostructured Fluorinated Materials NFMLab, Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Via Mancinelli 7, Milano I 20131, Italy
    Nat Commun 6:7574. 2015
    ..This is remarkable for such a modest perturbation in structure. Iodination of aromatic amino acids may thus develop as a general strategy for the design of new hydrogels from unprotected peptides and without using organic solvents. ..
  21. doi request reprint A superfluorinated molecular probe for highly sensitive in vivo(19)F-MRI
    Ilaria Tirotta
    Laboratory of Nanostructured Fluorinated Materials NFMLab, Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Fondazione Centro Europeo Nanomedicina, and Department of Electronics, Information, and Bioengineering, Politecnico di Milano, Milan, Italy
    J Am Chem Soc 136:8524-7. 2014
    ..The molecule, which bears 36 equivalent (19)F atoms and shows a single intense resonance peak, is easily synthesized via a simple one-step reaction and is formulated in water with high stability using trivial reagents and methods. ..
  22. doi request reprint The fluorous effect in biomolecular applications
    Massimo Cametti
    NFMLab DCMIC Giulio Natta, Politecnico di Milano, Via Mancinelli 7, I 20131 Milan, Italy
    Chem Soc Rev 41:31-42. 2012
    ....