Pierangelo MetrangoloSummaryAffiliation: Politecnico di Milano Country: Italy Publications
| Collaborators
|
Detail Information
Publications
Metal-bound halogen atoms in crystal engineeringPierangelo Metrangolo
Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131 Milano, Italy
Chem Commun (Camb) 49:1783-5. 2013..which highlights the very rich supramolecular behaviour of halogen atoms. Their findings appear even more timely when viewed in light of the recently proposed IUPAC definition of the halogen bond...
Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channelsJavier Martí-Rujas
Center for Nano Science and Istituto Italiano di Tecnologia, via Pascoli 70 3, 20133 Milano, Italy
Chem Commun (Camb) 48:8207-9. 2012..The framework is able to host various guest molecules with a diverse set of steric demands and substitution patterns, and survives single-crystal-to-single-crystal guest exchanges from liquid and gas phases...
Chemistry. Halogen versus hydrogenP Metrangolo
Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Milan, 20131, Italy
Science 321:918-9. 2008
Nonporous organic solids capable of dynamically resolving mixtures of diiodoperfluoroalkanesPierangelo Metrangolo
Laboratory of Nanostructured Fluorinated Materials, Department of Chemistry, Materials, and Chemical Engineering Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131 Milan, Italy
Science 323:1461-4. 2009..Heating liberates the DIPFAs and regenerates the original salt lattice, highlighting the practical potential for the system in separation applications...
2-Iodo-imidazolium receptor binds oxoanions via charge-assisted halogen bondingMassimo Cametti
NFMLab Department of Chemistry, Materials and Chemical Engineering Giulio Natta, Politecnico di Milano, Via Mancinelli 7, I 20131, Milan, Italy
Org Biomol Chem 10:1329-33. 2012..Phosphate, in particular, binds to 1 with an association constant of ca. 10(3) M(-1), which is particularly high for a single X-bond. A remarkably short C-I···O(-) contact is observed in the structure of the salt 1·H(2)PO(4)(-)...
Halogen bonding: a general route in anion recognition and coordinationGabriella Cavallo
NFMLab DCMIC G Natta Politecnico di Milano, 7, Via Mancinelli, I 20131 Milan, Italy
Chem Soc Rev 39:3772-83. 2010..The interaction allows for several other anions to self-assemble with halocarbons and mention is also given to the halogen bonding-based coordination of halides, polycyano- and polyoxometallates (72 references)...
Dimensional encapsulation of I(-)...I(2)...I(-) in an organic salt crystal matrixAntonio Abate
NFMLab and D C M I C Giulio Natta, Politecnico di Milano, Via L Mancinelli 7, 20131 Milan, Italy
Chem Commun (Camb) 46:2724-6. 2010..I-I...I(-), which matches in length to the chosen dication...
The halogen-bonded adduct 1,4-bis(pyri-din-4-yl)buta-1,3-diyne-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexa-deca-fluoro-1,8-diiodo-octane (1/1)Gabriella Cavallo
NFMLab, Department of Chemistry, Materials and Chemical Engineering, G Natta, Politecnico di Milano, Via Mancinelli, 7, I 20131 Milano, Italy
Acta Crystallogr Sect E Struct Rep Online 69:o328-9. 2013..The topology of the network is a nice example of the paradigm of the expansion of ditopic starting modules; the XB leads to the construction of infinite supramolecular chains along [2-11] formed by alternating XB donors and acceptors...
Halogen-bonding-triggered supramolecular gel formationLorenzo Meazza
NFMLab DCMIC Giulio Natta, Politecnico di Milano, Via L Mancinelli 7 IT 20131, Italy
Nat Chem 5:42-7. 2013..Using this concept, we have prepared a halogen bond donor bis(urea) gelator that forms co-gels with halogen bond acceptors...
The fluorous effect in biomolecular applicationsMassimo Cametti
NFMLab DCMIC Giulio Natta, Politecnico di Milano, Via Mancinelli 7, I 20131 Milan, Italy
Chem Soc Rev 41:31-42. 2012....
