M A SuhmSummaryCountry: Germany Publications
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Publications
Proton tunneling estimates for malonaldehyde vibrations from supersonic jet and matrix quenching experimentsT N Wassermann
Institut fur Physikalische Chemie, Universitat Gottingen, Germany
Phys Chem Chem Phys 8:2344-8. 2006....
[In Process Citation]Susanne Hesse
, , Tammannstr 6,
Phys Chem Chem Phys 11:11157-70. 2009..The latter is not energetically accessible in open chain esters because it would bring the molecular C[double bond, length as m-dash]O and C-O-C dipole moments into an unfavorable near-parallel orientation, thus their higher volatility...
Concerted proton motion in hydrogen-bonded trimers: a spontaneous Raman scattering perspectivePhilipp Zielke
Institut fur Physikalische Chemie, Universitat Gottingen, Tammannstr 6, 37077, Gottingen, Germany
Phys Chem Chem Phys 8:2826-30. 2006....
Comment on "Theoretical investigations into the enantiomeric and racemic forms of α-(trifluoromethyl)lactic acid" by R. Tonner, V. A. Soloshonok and P. Schwerdtfeger, Phys. Chem. Chem. Phys., 2011, 13, 811-817M A Suhm
Institut fur Physikalische Chemie, Universitat Gottingen, Tammannstr 6, 37077 Gottingen, Germany
Phys Chem Chem Phys 13:4159-60; discussion 4161-2. 2011..It is argued that differences between homo- and heterochiral dimers of the title compound in the gas phase cannot be responsible for the different sublimation behaviour of racemic and enantiomerically pure crystals near room temperature...
Hydrogen bonding lights up overtones in pyrazolesT N Wassermann
Institut fur Physikalische Chemie, Universitat Gottingen, Tammannstrasse 6, 37077 Gottingen, Germany
J Chem Phys 127:234309. 2007..Spectra of substituted pyrazoles confirm the robustness of the coupling, which remains dark in strained dimers, but lights up in linearly hydrogen-bonded trimers...
Intra- vs. intermolecular hydrogen bonding: dimers of alpha-hydroxyesters with methanolNicole Borho
, , Tammannstr. 6, 37077, , Germany
Phys Chem Chem Phys 8:4449-60. 2006....
Chirality-induced switch in hydrogen-bond topology: tetrameric methyl lactate clusters in the gas phaseThomas B Adler
, , Tammannstrasse 6, , Germany
Angew Chem Int Ed Engl 45:3440-5. 2006
A peptide co-solvent under scrutiny: self-aggregation of 2,2,2-trifluoroethanolTina Scharge
Institut fur Physikalische Chemie, Universitat Gottingen, Tammannstr 6, 37077, Gottingen, Germany
Phys Chem Chem Phys 9:4472-90. 2007..Simple force fields can be refined to capture some molecular recognition features of TFE dimer, but their limitations are emphasized...
Raman spectroscopic evidence for the most stable water/ethanol dimer and for the negative mixing energy in cold water/ethanol trimersMarija Nedić
Institut fur Physikalische Chemie, Universitat Gottingen, Tammannstrasse 6, Gottingen, Germany
Phys Chem Chem Phys 10:5953-6. 2008....
Infrared spectroscopy of pyrrole-2-carboxaldehyde and its dimer: a planar beta-sheet peptide model?Corey A Rice
Institut fur Physikalische Chemie, Universitat Gottingen, Tammannstrasse 6, D 37077 Gottingen, Germany
J Chem Phys 126:134313. 2007..The effect of matrix isolation is modeled by condensing layers of Ar atoms on the isolated monomer and dimer. The dimer structure is discussed in the context of the peptide beta-sheet motif...
Self-organization of lactates in the gas phaseNicole Borho
, , Tammannstr. 6, D-37077, , Germany
Org Biomol Chem 1:4351-8. 2003..Chemical modification of the ester-group (methyl-, ethyl- and isopropyl-lactate) and argon admixture to the helium expansion contribute importantly to an understanding of the cluster spectra and topology...
Spectroscopic characterization of N(2)O aggregates: from clusters to the particulate stateM K Kunzmann
, , Tammannstr 6, , Germany
Spectrochim Acta A Mol Biomol Spectrosc 59:2855-65. 2003..A pronounced temperature dependence of a combination band maximum in the collisional cooling cell spectra is found. This correlation is exploited to estimate cluster temperatures in supersonic jet spectra...
A combined Raman- and infrared jet study of mixed methanol-water and ethanol-water clustersMarija Nedić
Institut fur Physikalische Chemie, Universitat Gottingen, Tammannstr 6, 37077 Gottingen, Germany
Phys Chem Chem Phys 13:14050-63. 2011..The effects of weak C-H···O hydrogen bonds are quantified in the case of mixed ethanol-water dimers...
Dimers of cyclic carbonates: chirality recognition in battery solvents and energy storageFranz Kollipost
Institut fur Physikalische Chemie, Universitat Gottingen, Tammannstr 6, 37077 Gottingen, Germany
Phys Chem Chem Phys 13:14176-82. 2011..This suggests the usefulness of chirality control in elucidating ionic transport mechanisms in battery solvents and asymmetric catalysis in such solvents...
Temperature-dependent intensity anomalies in amino acid esters: weak hydrogen bonds in protected glycine, alanine and valineKatharina E Otto
Institut fur Physikalische Chemie, Universitat Gottingen, Tammannstr 6, D 37077 Gottingen, Germany
Phys Chem Chem Phys 13:14119-30. 2011..It also rules out cooperative hydrogen bond topologies and points at deficiencies in standard harmonic treatments with the linear dipole approximation...
Elementary peptide motifs in the gas phase: FTIR aggregation study of formamide, acetamide, N-methylformamide, and N-methylacetamideMerwe Albrecht
Institut fur Physikalische Chemie, Universitat Gottingen, Tammannstrasse 6, 37077 Gottingen, Germany
J Phys Chem A 112:7530-42. 2008..Accurate benchmark quantities for multidimensional vibrational treatments of these peptide models are derived, and the influence of methyl groups on the N-H stretching dynamics is discussed...
Quantitative chirality synchronization in trifluoroethanol dimersTina Scharge
, , Tammannstr. 6, , Germany
Phys Chem Chem Phys 8:4664-7. 2006....
Experimental and theoretical study of the microsolvation of sodium atoms in methanol clusters: differences and similarities to sodium-water and sodium-ammoniaIngo Dauster
Institut fur Physikalische Chemie, Tammannstr 6, Georg August Universitat, Gottingen, Germany
Phys Chem Chem Phys 10:83-95. 2008..For Na(NH(3))(n), a largely delocalized and internal electron is excited to autoionizing electronic states, a process that is no longer local and consequently may depend on cluster size up to very large n...
Chirality recognition between neutral molecules in the gas phaseAnne Zehnacker
CNRS, Laboratoire de Photophysique Moleculaire, UPR3361, Univ Paris Sud, 91405 Orsay, France
Angew Chem Int Ed Engl 47:6970-92. 2008..Analogies between the microscopic mechanisms and macroscopic phenomena and between intra- and intermolecular cases are drawn...
