Todd B Marder

Summary

Country: Germany

Publications

  1. Zhang Z, Edkins R, Haehnel M, Wehner M, Eichhorn A, Mailänder L, et al. Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles. Chem Sci. 2015;6:5922-5927 pubmed publisher
    ..52 and -1.69 eV vs. Fc/Fc+, respectively. ..
  2. Zhang Z, Edkins R, Nitsch J, Fucke K, Steffen A, Longobardi L, et al. Optical and electronic properties of air-stable organoboron compounds with strongly electron-accepting bis(fluoromesityl)boryl groups. Chem Sci. 2015;6:308-321 pubmed publisher
  3. Scharnagl F, Bose S, Marder T. Acylboranes: synthetic strategies and applications. Org Biomol Chem. 2017;15:1738-1752 pubmed publisher
    ..Applications of acylboranes in chemoselective amide-bond forming reactions, converting them into functionalised boron derivatives are also discussed. ..
  4. Ji L, Griesbeck S, Marder T. Recent developments in and perspectives on three-coordinate boron materials: a bright future. Chem Sci. 2017;8:846-863 pubmed publisher
    ..Significant developments have been made in all of these areas in recent years and new applications are rapidly emerging for this class of boron compounds. ..
  5. Pietsch S, Paul U, Cade I, Ingleson M, Radius U, Marder T. Room temperature ring expansion of N-heterocyclic carbenes and B-B bond cleavage of diboron(4) compounds. Chemistry. 2015;21:9018-21 pubmed publisher
  6. Bose S, Deißenberger A, Eichhorn A, Steel P, Lin Z, Marder T. Zinc-Catalyzed Dual C-X and C-H Borylation of Aryl Halides. Angew Chem Int Ed Engl. 2015;54:11843-7 pubmed publisher
    ..This method thus represents a novel use of a group XII catalyst for C-H borylation. This transformation does not proceed via a free aryne intermediate, but a radical process seems to be involved. ..
  7. Würtemberger Pietsch S, Radius U, Marder T. 25 years of N-heterocyclic carbenes: activation of both main-group element-element bonds and NHCs themselves. Dalton Trans. 2016;45:5880-95 pubmed publisher
    ..Furthermore, a few related NHC rearrangements were observed some decades ago. In this Perspective, we summarise the history of NHC ring expansion reactions from the 1960s till the present. ..
  8. Batsanov A, Cabeza J, Crestani M, Fructos M, García Álvarez P, Gille M, et al. Fully Borylated Methane and Ethane by Ruthenium-Mediated Cleavage and Coupling of CO. Angew Chem Int Ed Engl. 2016;55:4707-10 pubmed publisher
    ..The use of (13)CO-enriched ruthenium carbonyl has demonstrated that the boron-bound carbon atoms of all of these reaction products arise from CO ligands. ..
  9. Paul U, Sieck C, Haehnel M, Hammond K, Marder T, Radius U. Cyclic (Alkyl)(Amino)Carbene Complexes of Rhodium and Nickel and Their Steric and Electronic Parameters. Chemistry. 2016;22:11005-14 pubmed publisher

More Information

Publications15

  1. Zhang Z, Wang Z, Haehnel M, Eichhorn A, Edkins R, Steffen A, et al. Synthesis and fluxional behaviour of novel chloroborole dimers. Chem Commun (Camb). 2016;52:9707-10 pubmed publisher
    ..DFT calculations suggest an unusual dimerisation mechanism and provide insight into the dynamics of the dimers. ..
  2. Würtemberger Pietsch S, Schneider H, Marder T, Radius U. Adduct Formation, B-H Activation and Ring Expansion at Room Temperature from Reactions of HBcat with NHCs. Chemistry. 2016;22:13032-6 pubmed publisher
  3. Griesbeck S, Zhang Z, Gutmann M, Lühmann T, Edkins R, Clermont G, et al. Water-Soluble Triarylborane Chromophores for One- and Two-Photon Excited Fluorescence Imaging of Mitochondria in Cells. Chemistry. 2016;22:14701-6 pubmed publisher
    ..Thus, chromophore 3 has excellent potential for one- and two-photon-excited fluorescence imaging of mitochondrial function in cells. ..
  4. Sieck C, Tay M, Thibault M, Edkins R, Costuas K, Halet J, et al. Reductive Coupling of Diynes at Rhodium Gives Fluorescent Rhodacyclopentadienes or Phosphorescent Rhodium 2,2'-Biphenyl Complexes. Chemistry. 2016;22:10523-32 pubmed publisher
    ..Control of the isomer distribution is achieved by modification of the bis- (diyne) linker length, providing a fundamentally new route to access photoactive metal biphenyl compounds. ..
  5. Ji L, Haehnel M, Krummenacher I, Biegger P, Geyer F, Tverskoy O, et al. The Radical Anion and Dianion of Tetraazapentacene. Angew Chem Int Ed Engl. 2016;55:10498-501 pubmed publisher
    ..Solutions of the radical anion 1(.-) were stable in air for several hours and characterized by EPR spectroscopy. Dianion 1(2-) is highly fluorescent and photostable. ..
  6. Eichhorn A, Kuehn L, Marder T, Radius U. Facile insertion of a cyclic alkyl(amino) carbene carbon into the B-B bond of diboron(4) reagents. Chem Commun (Camb). 2017;53:11694-11696 pubmed publisher