Affiliation: Ecole Polytechnique
- Gold(I)-catalyzed formation of dihydroquinolines and indoles from N-aminophenyl propargyl malonatesColombe Gronnier
Laboratoire de Synthese Organique, UMR 7652 CNRS Ecole Polytechnique, Ecole Polytechnique, 91128 Palaiseau, France
Chem Commun (Camb) 47:218-20. 2011..The use of [XPhosAu(NCMe)]SbF(6) in nitromethane at 100 °C allows the rapid and efficient formation of variously substituted dihydroquinolines, which can be subsequently converted into indoles by a rare photochemical rearrangement...