Li Cheng Song
Affiliation: Nankai University
Song L, Zhu A, Guo Y. Synthesis, characterization, and H/D exchange of Î¼-hydride-containing [FeFe]-hydrogenase subsite models formed by protonation reactions of (Î¼-TDT)Fe2(CO)4(PMe3)2 (TDT = SCH2SCH2S) with protic acids. Dalton Trans. 2016;45:5021-9 pubmed publisher
..To our knowledge, 8 is the first crystallographically characterized Î¼-deuterium-containing butterfly [2Fe2S] complex produced by H/D exchange reaction. ..
Song L, Feng L, Guo Y. Hydrophilic quaternary ammonium-group-containing [FeFe]H2ase models prepared by quaternization of the pyridyl N atoms in pyridylazadiphosphine- and pyridylmethylazadiphosphine-bridged diiron complexes with various electrophiles. Dalton Trans. 2019;48:1443-1453 pubmed publisher
..In addition, the electrocatalytic study demonstrated that both 1 and 3 can serve as electrocatalysts for H2 production from acetic acid with higher icat/ip and TONs in MeCN/H2O than in MeCN. ..
Song L, Cao M, Wang Y. Novel reactions of homodinuclear Ni2 complexes [Ni(RNPyS4)]2 with Fe3(CO)12 to give heterotrinuclear NiFe2 and mononuclear Fe complexes relevant to [NiFe]- and [Fe]-hydrogenases. Dalton Trans. 2015;44:6797-808 pubmed publisher
..In addition, the electrochemical properties of and as well as the electrocatalytic H2 production catalyzed by and were investigated by CV techniques. ..
Song L, Wang Y, Xing X, Ding S, Zhang L, Wang X, et al
. Hydrophilic Quaternary Ammonium-Group-Containing [FeFe]-Hydrogenase Models: Synthesis, Structures, and Electrocatalytic Hydrogen Production. Chemistry. 2016;22:16304-16314 pubmed publisher
Song L, Yang X, Cao M, Gao X, Liu B, Zhu L, et al
. Dithiolato-bridged nickel-iron complexes as models for the active site of [NiFe]-hydrogenases. Chem Commun (Camb). 2017;53:3818-3821 pubmed publisher
..Herein, we report the synthesis, structures, and some properties of the NiFe-based dicarbonyl, terminal hydride, and Î¼-hydroxo models for the active site of [NiFe]-hydrogenases. ..