Research Topics
| M Amelia SantosSummaryCountry: Portugal Publications
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Publications
Design, synthesis and molecular modeling study of iminodiacetyl monohydroxamic acid derivatives as MMP inhibitorsM Amelia Santos
Centro de Quimica Estrutural, Instituto Superior Tecnico, Rua Rovisco Pais 1, 1049 001 Lisboa, Portugal
Bioorg Med Chem 14:7539-50. 2006..The sulfonamide based IDA derivatives studied (compounds B1-B3) showed to be potent (nM range) against deep S1' pocket MMPs enzymes (i.e., MMP-2)...
Iminodiacetyl-hydroxamate derivatives as metalloproteinase inhibitors: equilibrium complexation studies with Cu(II), Zn(II) and Ni(II)Silvia Chaves
Centro de Quimica Estrutural, Complexo I, Instituto Superior Tecnico, Av Rovisco Pais, 1049 001, Lisboa, Portugal
J Inorg Biochem 97:345-53. 2003..Moreover, at higher pH, H(2)L(1) is able to form a pentanuclear tetrameric copper complex with an interesting 12-metallacrown-4 structure...
N-Arylamine derivatives of 3-hydroxy-4-pyridinones: solution studies and bioevaluation in view of Al-detoxification rolesM Amelia Santos
Centro de Quimica Estrutural, Complexo I, Instituto Superior Tecnico, Av Rovisco Pais, 1049 001 Lisboa, Portugal
Anal Bioanal Chem 381:413-9. 2005....
Bis(3-hydroxy-4-pyridinone)-EDTA derivative as a potential therapeutic Al-chelating agent. Synthesis, solution studies and biological assaysM Amelia Santos
Centro de Quimica Estrutural, Complexo I, Instituto Superior Tecnico, Av Rovisco Pais, 1, 1049 001 Lisboa, Portugal
J Inorg Biochem 99:1845-52. 2005..Biodistribution studies, performed with 67Ga-overload mice, showed rapid clearance of the radiotracer from the body, thus indicating that the new ligand should be a quite effective agent for the in vivo aluminium removal...
Bifunctional 3-hydroxy-4-pyridinone derivatives as potential pharmaceuticals: synthesis, complexation with Fe(III), Al(III) and Ga(III) and in vivo evaluation with 67GaM Amelia Santos
Centro de Quimica Estrutural, Complexo I, Instituto Superior Tecnico, 1049 001 Lisboa, Portugal
J Biol Inorg Chem 10:564-80. 2005..Concerning the (67)Ga complexes, the benzyl-propylamine (H(2)L(3)) shows considerable bone retention, thus suggesting its potential application as imaging agent...
Methotrexate gamma-hydroxamate derivatives as potential dual target antitumor drugsM Amelia Santos
Centro de Quimica Estrutural, Instituto Superior Tecnico, 1049 001 Lisboa, Portugal
Bioorg Med Chem 15:1266-74. 2007..Therefore, based on the present results, these bi-functional drugs may be good candidates to target specific tumors in animal models due to potential combined effects on two pathways crucial for tumor development...
Carbonic anhydrase inhibitors: inhibition of cytosolic/tumor-associated isoforms I, II, and IX with iminodiacetic carboxylates/hydroxamates also incorporating benzenesulfonamide moietiesM Amelia Santos
Centro de Quimica Estrutural, Instituto Superior Tecnico, Rua Rovisco Pais 1, 1049 001 Lisbon, Portugal
Bioorg Med Chem Lett 17:1538-43. 2007....
A new approach for potential combined chelation therapy using mono- and bis-hydroxypyridinonesM Amelia Santos
Centro de Quimica Estrutural, Instituto Superior Tecnico, Lisboa, Portugal
Hemoglobin 32:147-56. 2008..This may be rationalized by adjuvant and eventual synergistic effects, due to complementary accessibility of each chelator to different cellular compartments...
Novel folate-hydroxamate based antimetabolites: synthesis and biological evaluationMarta P Carrasco
Centro de Quimica Estrutural, Instituto Superior Tecnico, 1049 001 Lisboa, Portugal
Med Chem 7:265-74. 2011..The MTX-based compound could be of interest for testing against metastasizing tumors in an animal model. The studied derivatives represent promising molecular templates for further development of dual activity anti-cancer drugs...
Novel 1-hydroxypiperazine-2,6-diones as new leads in the inhibition of metalloproteinasesSérgio M Marques
Centro de Química Estrutural, Instituto Superior Tecnico, Av Rovisco Pais 1, 1049 001 Lisboa, Portugal
J Med Chem 54:8289-98. 2011..The final structure obtained will allow straightforward drug design approaches in view of further optimization and development of new MMP inhibitors bearing the HPD moiety...
New tris(hydroxypyridinones) as iron and aluminium sequestering agents: synthesis, complexation and in vivo studiesSilvia Chaves
Centro de Quimica Estrutural, Instituto Superior Tecnico, Av Rovisco Pais 1, 1049 001 Lisboa, Portugal
Chemistry 16:10535-45. 2010....
N-Carboxyalkyl derivatives of 3-hydroxy-4-pyridinones: synthesis, complexation with Fe(III), Al(III) and Ga(III) and in vivo evaluationM Amelia Santos
Centro de Quimica Estrutural, Complexo I, Instituto Superior Tecnico, Av Rovisco Pais, Lisbon, Portugal
J Inorg Biochem 92:43-54. 2002..All the ligands were found to enhance the excretion of the gallium. Noteworthy is the observed Ga bone fixation, mostly with the ethyl derivative, thus suggesting the potential use of the complex as a bone seeking agent...
Dual inhibitors of matrix metalloproteinases and carbonic anhydrases: iminodiacetyl-based hydroxamate-benzenesulfonamide conjugatesSérgio M Marques
Centro de Quimica Estrutural, Instituto Superior Tecnico, Av Rovisco Pais 1, 1049 001 Lisboa, Portugal
J Med Chem 51:7968-79. 2008..Furthermore, a docking study for MMPs was reported for the most promising compound in order to investigate its binding interactions with the different MMPs...
Pteridine-sulfonamide conjugates as dual inhibitors of carbonic anhydrases and dihydrofolate reductase with potential antitumor activitySérgio M Marques
Instituto Superior Tecnico, Centro de Quimica Estrutural, Av Rovisco Pais 1, 1049 001 Lisboa, Portugal
Bioorg Med Chem 18:5081-9. 2010..Nevertheless, this fact points out the need of improving the cell intake properties of these new compounds, since the general inhibitory profiles revealed their potential as anticancer agents...
New hydroxypyrimidinone-containing sulfonamides as carbonic anhydrase inhibitors also acting as MMP inhibitorsM Alexandra Esteves
LNEG, Unidade de Pilhas de Combustível e Hidrogénio, Estrada do Paco do Lumiar, Lisboa, Portugal
Bioorg Med Chem Lett 20:3623-7. 2010....
Combined chelation based on glycosyl-mono- and bis-hydroxypyridinones for aluminium mobilization: solution and biodistribution studiesSilvia Chaves
Centro de Quimica Estrutural, Instituto Superior Tecnico, 1049 001 Lisboa, Portugal
J Inorg Biochem 103:1521-9. 2009..This may be rationalized by coadjuvation and eventual synergistic effects, due to complementary accessibility of the chelators to different cellular compartments...
New hydroxypyridinone-functionalized sepharoses as sorbing agents for hard metal ionsRaquel Grazina
Centro Química Estrutural, Instituto Superior Técnico UTL, Av Rovisco Pais, 1049 001 Lisboa, Portugal
J Hazard Mater 186:1902-8. 2011..These functionalized supports also showed capacity to be regenerated and reused. Thus, there are good perspectives for potential environmental and medical applications of these new metal sorbents...
A gallium complex with a new tripodal tris-hydroxypyridinone for potential nuclear diagnostic imaging: solution and in vivo studies of 67Ga-labeled speciesSilvia Chaves
Centro de Quimica Estrutural, Instituto Superior Técnico UTL, 1049 001 Lisboa, Portugal
J Inorg Biochem 105:31-8. 2011..These results indicate good perspectives for potential application of extrafunctionalized analogues in radiodiagnostic techniques...
Complexes of hydroxy(thio)pyrone and hydroxy(thio)pyridinone with Zn(II) and Mo(VI). Thermodynamic stability and insulin-mimetic activitySilvia Chaves
Centro de Quimica Estrutural, Instituto Superior Tecnico, Av Rovisco Pais 1, 1049 001 Lisboa, Portugal
Metallomics 2:220-7. 2010..Hence, these preliminary studies indicate that the Zn(thiomaltol)? complex can be considered a potential drug candidate for treatment of diabetes mellitus, upon in vivo evaluations...
Bifunctional phenolic-choline conjugates as anti-oxidants and acetylcholinesterase inhibitorsJaroslav Sebestik
Centro de Quimica Estrutural, Instituto Superior Tecnico, Av Rovisco Pais 1, 1049 001 Lisboa, Portugal
J Enzyme Inhib Med Chem 26:485-97. 2011....
